What Are The 5 Principles of Chemical Safety?
By Zarif Ahmed
| 19 Dec 2025
What Are The 5 Principles of Chemical Safety?
What Are The 5 Principles of Chemical Safety?

Chemical exposure is a significant health and safety concern in workplaces throughout New Zealand. While specific annual illness rates for the current year are still being compiled by WorkSafe New Zealand, historical data suggests that thousands of workers are exposed to hazardous substances across industries like agriculture, manufacturing, and construction.

Effective safety management is critical for protecting the health of workers, the environment, and our local communities. By following five main principles of chemical safety, businesses can build a thorough framework to prevent workplace injuries.

The goal of these regulations is to ensure that dangers are spotted and controlled before any harm occurs. This article covers these five principles and how they can protect workers and reduce chemical risks.

Hazard Identification

Protection starts with recognition because workers cannot stay safe from a threat if it has not been identified. Employers have a legal duty to identify all hazardous substances in their workplace.

The first step is finding exactly which chemicals in a facility are dangerous by gathering details about their properties and how they behave. It is important for facilities to keep an accurate hazardous substances inventory of all chemicals used or stored on-site.

These substances must have current Safety Data Sheets (SDS) available from the supplier. Teams should know how to find SDSs and read them carefully to understand specific handling and storage rules.

Special attention is needed for chemicals used in large amounts or those that are highly volatile. These substances evaporate quickly, filling the air with potentially dangerous vapors that are easy for workers to inhale.

Risk Assessment

Knowing a hazard exists is not the same as knowing the risk. A chemical risk assessment checks how likely harm is to happen and how severe that harm could be.

This process looks at how workers might interact with chemicals and how often that interaction happens. It also considers the effectiveness of safety measures that are already in place, such as ventilation systems.

While WorkSafe provides local guidance, businesses often look to NIOSH steps: finding the hazard, checking the dose-response, and assessing exposure. These steps help show if exposure levels are too high for a safe working environment.

If a chemical is not properly stored, it can cause many accidents such as fires and explosions. Because of this, reviewing storage—including the compatibility of different chemicals—is a key part of the assessment.

Control Measures (Hierarchy of Controls)

Removing the danger at the source works better than just relying on safety gear. The "Hierarchy of Controls" ranks safety methods by how well they protect the worker.

The five levels of control are as follows:

  • Elimination: This removes the hazard entirely, such as stopping the use of a dangerous chemical.
  • Substitution: This swaps a dangerous chemical for a safer one, like using water-based paint instead of solvent-based alternatives.
  • Engineering Controls: These are physical changes, like local exhaust ventilation, that block hazards from the worker.
  • Administrative Controls: These are rules to limit exposure time, such as rotating jobs or implementing safe work procedures.
  • Personal Protective Equipment (PPE): This is the last defense, using gear like gloves or respirators when other controls cannot fully manage the risk.

Elimination and substitution work best because they remove risks without relying on human behavior.

Communication and Training

Workers cannot avoid hazards if they do not understand them. Good communication ensures everyone knows the dangers and how to stay safe.

New Zealand regulations require PCBUs to provide information, training, and instruction for workers handling hazardous substances. NZ has adopted the Globally Harmonized System (GHS) to ensure chemical classifications and labels are consistent with international standards.

Labels must use specific pictures (pictograms), warning words, and hazard statements. Training needs to teach workers how to detect chemicals in the air and the correct procedures to follow during an emergency.

Clear communication is vital for worker health, as many occupational illnesses go unreported until years later. Ensuring that every team member knows the risks is a fundamental part of workplace safety.

Monitoring and Review

The saying "what gets measured gets managed" is true for chemical safety. Regular checks make sure that your controls still work as conditions change.

Exposure monitoring measures chemicals in the air to ensure they stay within safe limits. In New Zealand, these are compared against Workplace Exposure Standards (WES) and Biological Exposure Indices (BEI).

Workplace monitoring also includes checking surfaces for contamination to prevent skin contact. Beyond sampling, safety programs should review accident reports and "near-miss" incidents to find patterns.

Safety programs should be reviewed at least once a year. Regular reviews ensure that the safety system stays effective even if you introduce new chemicals or change your work processes.

Final Thoughts

Safety is not just a checklist; it is an active commitment to protecting lives in the workplace. The goal of these five principles is to spot dangers and stop them before they cause harm to your team.

Progress works better than waiting for perfection. It starts with an honest assessment of your biggest risks and taking immediate steps to control them.

By maintaining a clear inventory and keeping communication open, safety becomes a daily habit. Every step taken to follow this system makes the workplace safer for everyone involved.

Frequently Asked Questions

What are the 5 key principles for chemical safety?

The core principles are Hazard Identification, Risk Assessment, Control Measures, Communication, and Monitoring. Together, they build a full protection system.

How does the hierarchy of controls work?

It ranks safety steps by effectiveness. It starts with elimination, then substitution, engineering controls, administrative controls, and finally PPE.

Why is regular monitoring important?

Monitoring proves that controls work as intended. It catches problems before harm occurs, which is vital as conditions change.

What role do Safety Data Sheets (SDS) play?

SDS documents give details about what is in a chemical and its health risks. They also explain handling rules and protective gear.

How often should risk assessments be updated?

Assessments should be reviewed at least annually. Updates are needed right away if new chemicals arrive or processes change.

Zarif Ahmed

Zarif Ahmed LinkedIn

An engineer and safety writer by profession, focusing on chemical management, regulatory development, and the patterns that shape workplace practice over time.