TMT 15

2.1. Indeling van de stof of het mengsel

C; R34 R43 R52/53 R-phrases 34 Causes burns. 43 May cause sensitisation by skin contact. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization low acid solution of: Hazardous ingredients CAS No EC No Name [% weight]

Classificaties

55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3- < 2,5 T R23/24/25; C R34; R43; N R50-53 one [EC no. 247-500-7] and 2-methyl- 2Hisothiazol-3-one [EC no. 220-239-6] (3:1) 4. FIRST AID MEASURES General information Remove contaminated soaked clothing immediately and dispose it safely. In case of inhalation In case of inhalation of mist seek medical advice. In case of skin contact In case of contact with skin wash off immediately with soap and water. Page 1/6 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 05.09.2008 Revision 28.05.2008 (GB) Version 1.0 BerkeCID HYDREX 7310 Consult a doctor if skin irritation persists. In case of eye contact In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. In case of ingestion Do not induce vomiting. Call for a doctor immediately. Rinse out mouth and give plenty of water to drink. Give plenty of water to drink in small sips. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Product does not burn, fire-extinguishing activities according to surrounding. Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases Fire gas of organic material has to be classed invariably as respiratory poison. In case of fire formation of dangerous gases possible. Special protective equipment for fire-fighters Use breathing apparatus with independent air supply. Do not inhale explosion and/or combustion gases.

Extra informatie

Collect contaminated firefighting water separately, must not be discharged into the drains. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Remove persons to safety. Use personal protective clothing. Use breathing apparatus if exposed to vapours/dust/aerosol. Environmental precautions Do not seep away runed out product into ground or body of water. Do not discharge into surface waters/groundwater. Methods for cleaning up Disposal according to regulations. Take up with absorbent material (e.g. general-purpose binder). 7. HANDLING AND STORAGE Advice on safe handling Avoid formation of aerosols. Open and handle container with care! Take the usual precautions when handling with chemicals. Advice on protection against fire and explosion No special measures necessary. Requirements for storage rooms and vessels Keep in closed original container. Prevent penetration into the ground. Only use containers that are approved specifically for the substance/product. Page 2/6 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 05.09.2008 Revision 28.05.2008 (GB) Version 1.0 BerkeCID HYDREX 7310 Advice on storage compatibility Do not store together with animal feedstuffs. Do not store together with food. Further information on storage conditions Keep container tightly closed, store at cool and aired place, open and handle carefully. Protect from heat and direct solar radiation. Protect from heat/overheating. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory protection Breathing apparatus in the event of aerosol or mist formation. Short term: filter apparatus, Filter A/P2 Hand protection The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Gloves (acid-resistant) PVC gloves Eye protection tightly fitting goggles Skin protection protective chlothing General protective measures Do not inhale vapours. Do not inhale aerosols Avoid contact with eyes. Hygiene measures Do not eat or drink when working. Remove soiled or soaked clothing immediately. Keep away from food and drink. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour liquid clear characteristic Important health, safety and environmental information Value Temperature at Method Remark pH value in delivery ca. 3 state boiling point not determined Flash point not applicable Lower explosion limit not applicable Upper explosion limit not applicable Page 3/6 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 05.09.2008 Revision 28.05.2008 (GB) Version 1.0 BerkeCID HYDREX 7310 Value Temperature at Method Remark Vapour pressure not determined Density > 1 g/cm3 Solubility in water 20 °C miscible Explosive properties none 10. STABILITY AND REACTIVITY Materials to avoid Reactions with oxidising agents. Reactions with reducing agents. Reactions with alkalies. Hazardous decomposition products No hazardous decomposition products known. 11. TOXICOLOGICAL INFORMATION Acute toxicity/Irritability/Sensitization Value/Validation Species Method Remark LD 50 acute oral > 2000 mg/kg rat LD 50 acute > 2000 mg/kg rabbit dermal Irritability skin irritant Skin sensitization sensitizing Experiences made from practice Experiences at humans: may cause hypersensitivity reactions on skin in case of persons suffering from hypersensitivity. Because of structure symptoms sensitization possible. Skin: causes strong corrosions. Additional information Further hazardous properties can not be excepted Observe the general safety regulations when handling chemicals. 12. ECOLOGICAL INFORMATION Ecotoxicological effects Value Species Method Validation Fish LC50 0,253 mg/l (96 h) Oncorhynchus mykiss Daphnia EC50 1,3 mg/l (48 h) Daphnia magna Page 4/6 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 05.09.2008 Revision 28.05.2008 (GB) Version 1.0 BerkeCID HYDREX 7310 General regulation Do not allow uncontrolled leakage of product into the environment. 13. DISPOSAL CONSIDERATIONS Waste code No. Name of waste 16 05 08* discarded organic chemicals consisting of or containing dangerous substances Wastes marked with an asterisk are considered to be hazardous waste pursuant to Directive 91/689/EEC on hazardous waste. Recommendations for the product Remove in accordance with local offical regulations. Recommendations for packaging Remove in accordance with local official regulations. Recommended cleansing agent water General information Give to a certified disposal contractor. Do not empty into drains.