Waterige ammoniak

Gevarenpictogrammen

R-PHRASES/ % (w/w) ELINCS NO NOT AS Sodium Hydroxide 215-185-5 1310-73-2 c R35 5- 10 Refer to Section 16 for descriptions of relevant risk phrases and Notas. I 4. I FIRST AID MEASURES INHALATION: Get immediate medical attention. Remove to fresh air, treat symptomatically. Artificial respiration and/or oxygen may be necessary. SKIN CONTACT: Get immediate medica! attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. lmmediately flush with plenty of water lor at least 15 minutes. Fora large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use. EYE CONTACT: Get immediate medica! attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. lmmediately flush eye with water lor at least 15 minutes while holding eyelids open. INGESTION: Get immediate medica! attention. DO NOT IN DUCE VOMITING. lf conscious, washout mouthand give water to drink. NOTE TO PHYSICIAN : Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reaelions of the patient, the physician's judgement should be used to control symptoms and clinical condition. Measures against circulatory shock, respiratory depression and convulsions may be needed. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 2/11 NNALCO NALCO® 72215 PRODUCT I 5. I FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA: Nol expected to burn. Use extinguishing media appropriate lor surrounding lire. I EMERGENCY TELEPHONE NUMBER(S) See sectien 16, lor Emergency Telephone Numbers. FIRE AND EXPLOSION HAZARD : May evolve oxides of phosphorus (POx) under lire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of lire, wear a full face positive-pressure self contained breathing apparatus and proteelive suil. Is. I ACCIDENT AL RELEASE MEASURES PERSONAL PRECAUTIONS : Restriet access to area as appropriate until clean-up operations are complete. Use personaf proteelive equipment recommended inSection 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilale spil! area if possible. Ensure clean-up is conducted by trained personnel only. Do nol touch spilled materiaL Have emergency equipment (lor lires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHOOS FOR CLEANING UP : SMALL SPILLS: Soak up spil! with absorbent materiaL Place residues in a suitable, covered, properly labeled container. Wash alleeled area. LARGE SPILLS: Contain liquid using absorbent material, by digging tranches or by diking. Reelalm into recovery or salvage drumsortank truck lor proper disposaL Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler lor disposal of contaminated reeavered materiaL Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENT AL PRECAUTIONS: Do nol contaminate surface water. Prevent product trom entering drains. Do nol allow material to contaminate ground water system. In !he even! of a spil!, prevent material trom entering sewers or waterways. lf drains, streams, soil or sewers become contaminated, notify local authority. I 7. I HANDLING AND STORAGE HANDLING: Do nol gel in eyes, on skin, on clothing. Do nol take internally. Use with adequate ventilation. Do nol breathe vapors/gases/dust. Use personaf proteelive equipment recommended in Section 8 (Exposure Controls/Personal Protection). Keep the containers closed when nol in use. Have emergency equipment (lor lires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Do nol mix with acids. SlORAGE CONDITIONS : Proteet product from freezing. Store in suitable labeled containers. Store the containers tightly closed. Store separately trom acids. Keep container in a well-ventilated place. SUITABLE CONSTRUCTION MATERIAL: HOPE (high density polyethylene), Stainless Steel 304, Compatibility with Plastic Materialscan vary; we therefore recommend !hal compatibility is lesled prior to use. SPECIFIC USE(S) : BOILER WATER TREATMENT NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 3/11 NNALCO PRODUCT For specific dosages and customized applications please contact your representative. I 8. I EXPOSURE CONTROLS/PERSONAL PROTEGTION OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines havenotbeen established lor this product. Available exposure limits lor the substance(s) are shown below. Country/Souree Substance(s) Category: ppm mgfm3 AUSTRIA Sodium Hydroxide (lnhalable fraction.) MAK 2 MAKCEIL 4 BELGIUM Sodlum Hydroxide TWA 2 BULGARIA Sodium Hydroxide (Aerosol.) TWA 2 DENMARK Sodium Hydroxide LOFT 2 FINLAND Sodium Hydroxide HETKELL 2 FRANGE Sodium Hydroxide VME 2 IRELAND Sodium Hydroxide STEL 2 ITALY Sodium Hydroxide CeiHng 2 NORWAY Sodium Hydroxide GEIL 2 SPAIN Sodium Hydroxide VLA-EG 2 SWEDEN Sodium Hydroxide (lnhalable dust) NGV 1 TGV 2 SWITZERLAND Sodium Hydroxide (lnhalable dust) TWA 2 STEL 2 UNilED KINGDOM Sodium Hydroxide STEL 2 PO LAND Sodium Hydroxide MAG-NDS 0.5 MAG-NDSG 1 h HUNGARY Sodium Hydroxide AK 2 GK 2 LATVIA Sodium Hydroxide TWA 0.5 GZEGH REPUBLIG SexHum Hydroxide PEL 1 NP K-P 2 GROATIA Sodium Hydroxide KG VI 2 ROMANIA Sodium Hydroxide as NaOH TWA 1 STEL 3 RUSSIAN Sodium Hydroxide as NaOH {Aerosol.) GEIL 0.5 FEDERATION SERBIA Sodium Hydroxide MAG 2 Sodium Hydroxide as NaOH MAG 0.5 SLOVAKIA Sodium Hydroxide TWA 2 NALCO EUROPE B.V. Postbus 627 • 2300 AP leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 4/11 I EMERGENCY TELEPHONE NUMBER(S) ~ALCO® 72215 See section 16, for Emergency Telephone Numbers. NNALCO NALCO® 72215 PRODUCT I SLOVENIA Soclium Hydroxide (lnhalable fraction.) *A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes. MONITORING MEASURES : A small volume of air is drawn through an absorbani or barrier totrap the substance(s) which can then be desorbed or removed and analyzed as relereneed below: Substa nee( s) Method Analysis Absorbani Sodium Hydroxide US NIOSH: 7401 Tilration PTFE filter ENGINEERING MEASURES : General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions near the source. Laberatory samples should be handled in a fumehood. Provide mechanica! ventilation of confined spaces. PERSONAL PROTEGTION GENERAL ADVICE: EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers. TWA 2 STELMULT The u se and choice of personaf proteetion equipment is related to the hazard of the product, the workplace and the way the product is handled. In genera!, we recommend as a minimum preeautien that safety glasses with side-shields and werkdothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTEGTION: Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemieals being handled. Consider the u se of filter type: A-B-E-K-P The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. In even! of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. lf respiratory proteetion is required, institute a complete respiratory proteetion program including selection, fit testing, training, maintenance and inspection. HAND PROTEGTION : When handling this product, the use of chemica! gauntlets is recommended. The choice ofwork glove depends on work conditions and what chemieals are handled, but we have positive experience under light handling conditions using gloves made trom PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 37 4. SKIN PROTEGTION : When handling this product, the use of a chemica! resistant suil and rubber boots is recommended. The applicable European standard can be found in EN ISO 20345. EYE PROTEGTION : Wear a face shield with chemica! splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS: Use good work and personaf hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. lf dothing is contaminated, remove dothing and thoroughly wash the affected area. Launder contaminated dothing before reuse. Always wash thoroughly alter handling chemicals. When handling this product never eat, drink or smoke. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. nalco.com and request access 5/11 NNALCO

Product-ID

NALCO® 72215 Is. I PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Colorless ODOR None FLASH POINT: None SPECIFIC GRAVITY 1.09-1.12 SOLUBILITY IN WATER Complete pH (100 %) > 13 FREEZING POINT -3 "C Note: These physical properties are typical values tor this product and are subject to change. 110. STABILITY AND REACTIVITY I STABILITY: Stabie under normal conditions. EMERGENCY TELEPHONE NUMBER(S) I See section 16, for Emergency Telephone Numbers. HAZARDOUS POLYMERIZATION: Hazardous polymerization wil! not occur. CONDITIONS TO AVOID: Freezing temperatures. MATERIALS TO AVOID: Acids, Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generale heat, spiatlering or boiling and toxic vapors., Oxidizing agents, Metals HAZARDOUS DECOMPOSITION PRODUCTS : Gives off hydrogen by reaction with metals. Under lire conditions: Oxides of phosphorus 111. I TOXICOLOGICAL INFORMATION No taxicity studies have been conducted on this product. SENSITIZATION: This product is not expected to be a sensitizer. CARCINOGENICITY: None of the substances in this product are lisled as carcinogens by the International Agency tor Research on Cancer (!ARC), the National Toxicology Program (NTP) or the American Conference of Governmentallndustrial Hygienists (ACGIH). For additional intermation on the hazard of the preparation, please consult section 2 and 12. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 6/11 NNALCO NALCO® 72215 PRODUCT I 112. I ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : No toxicity studies have been conducted on this product. MOBILITY: The environmental fate was estimated using a levellil fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EP A. The model assumes a steady state condition between the total input and output. The levellil model does nol require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of !he models. lf released into the environment this material is expected to distribute to the air, water and soit/sediment in the approximate respective percentages; Air Water Soit/Sediment <5% 30-50% 50-70% The portion in water is expected to be soluble or dispersible. PERSISTENCY AND DEGRADATION: Greater than 95% of this product consists of i norgenie substances for which a biodegradation value is nol applicable. BIOACCUMULATION POTENTlAL This preparatien or material is nol expected to bioaccumulate. 113. I DISPOSAL CONSIDERATIONS lf this preparatien becomes a waste, the final user must define and assign the appropriate Europeen Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, natienat and local regulations. Dispose of wasles in an approved incinerator or waste treatment/disposal site, in aceordenee with all applicable regulations. Do nol dispose of wasles in local sewer or with normal garbage. This product wil! generale an ash if burned. lt can be burned directly in appropriate equipment. Any chemica! waste is a potentiel environmental pollulani and is NOT suitebie for disposal via ground, municipal sewers, drains, natura! streams or rivers. Empty drums should betaken for recycling, recovery, or disposal through a suitably qualified or licensed con tractor. EUROPE WASTE CODE : 16 03 03*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS- lnorganic wasles containing dangerous sub stances. lf this product is used in any further processes, the final user must redefine and assign the most appropriate Europeen Waste Catalogue Code. NATIONAL REGULATIONS AUSTRIA: Waste Code :52404 NATIONAL REGULATIONS CZECH REPUBLIC NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additienat copies of an MSDS visit www.nalco.com and request access 7/11 EMERGENCY TELEPHONE NUMBER(S) I See section 16, lor Emergency Telephone Numbers. NNALCO NALCO® 72215 PRODUCT Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No. 477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wasles (No. 381/2001 Coll.), as amended 114. I TRANSPORT INFORMATION The information in this sectionis lor relerenee only and should nottake the place of a shipping paper (bill of lading) I EMERGENCY TELEPHONE NUMBER(S) See section 16, tor Emergency Telephone Numbers. specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Narnes lor this product are as follows. LAND TRANSPORT Proper Shipping Name : SODIUM HYDROXIDE SOLUTION Technica! Name(s) : UN/ID No: UN 1824 Hazard Class - Primary : 8 Packing Group : 11 ADRIRID H.l.n.: 80

2.1. Indeling van de stof of het mengsel

CODE C5 AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : SODIUM HYDROXIDE SOLUTION Technica! Name(s) : UN/ID No: UN 1824 Hazard Class - Primary : 8 Packing Group : 11 IATA Cargo Packing lnstructions: 813 IATA Cargo Aircraft Limit: 30 L (Max net quantity per package) IATA Passenger Packing lnstructions: Y809/809 IATA Passenger Aircraft Limit : 0.5 L/1 L MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name : SODIUM HYDROXIDE SOLUTION Technica! Name(s) : UN/ID No: UN 1824 Hazard Class - Primary : 8 Packing Group : 11 OTHER APPLICABLE IN FORMATION CEFIC TREMGARD REFERENCE : 80S1824 EMERGENCY ACTION CODE : 2R 115. I REGULATORY INFORMATION AND LABELLING GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparatiens Directive 1999/45/EC. HAZARD SYMBOLS NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 8/11 NNALCO NALCO® 72215 PRODUCT ~ .i.~ CORROSIVE Contains: .. Sodium Hydroxide RISK PHRASES R35 - Causes severe burns. SAFETY PHRASES S24/25 - Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medica! advice. S28- After contact with skin, wash immediately with plenty of water. S36/37/39- Wear suitable proteelive clothing, gloves and eye/face protection. S45- In case of accident ar if you feel unwell, seek medica! advice immediately (show !he label where possible). NATIONAL REGULATIONS CZECH REPUBLIC This preparatien is classified as per Act on Chemica! Substances and Chemica! Preparatiens (No. 356/2003 Coll.) This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll. Occupational exposure limits for !he Czech Republic in sectien 8 are given as per Government's Reguiatien No. 178/2001 Coll. laying down conditions of health proteetion of employees at work NATIONAL REGULATIONS FRANCE Table of occupational diseases, Artiele L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s): 65 Classified lndustrial Sites (ICPE): Not-applicable. NATIONAL REGULATIONS GERMANY WGK 1 (Annex 4) NATIONAL REGULATIONS HOLLAND ABM RESULT I ~f~ RESULT I Substance(s) I % (w/w) NATIONAL REGULATIONS, USA FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and CosmeticAct: When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 BoilerWater Additives INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 9/11 I EMERGENCY TELEPHONE NUMBER(S) I See section 16, for Emergency Telephone Numbers. NNALCO NALCO® 72215 PRODUCT The substance(s) in this preparatien are included in or exempted trom the EINECS or ELINCS inventories Safety Data Sheet according to Reguiatien (EC) No 190712006. Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restrietion of CHemieals (REACH) regulation. lt is our intention to pre-register all chemica! substances that we manufacture or import into European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment. Should you require any further information on Nalco's REACH programmeplease contact us at reach@nalco.com or visit our website. UNITED STATES: This product has notbeen evaluated lor TSCA and may contain substances not found on the TSCA 8(b) lnventory List. This product may be used under the TSCA 5(h)(3) Research Exemption if all requirements are met. JAPAN All substances in this product comply with the Law Regulating the Manufacture and lmportation Of Chemica! Substances and are listed on the Existin and New Chemica! Substances list ENGS . OTHER INFORMATION LIST OF RELEVANT R-PHRASES AND NOT AS IN SECTION 3 R35 - Causes severe burns. - REVISED INFORMATION: section(s): This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any ether uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative lor any further infonnation. EMERGENCY TELEPHONE NUMBER(S) Trans-Europaan +32-(0)3-575-5555 Belgium I Luxembourg +32-(0 3-575-0330 Buigaria +32-(0 3-575-5555 Croatia +385 (0)91-1-25-75-23 Czech Republic +420-602-669421 Denmark +47 -22-33-69-99 Finland +358-(0)9-471 977 France I French Switzerland +33-(0)6-11-07 -32-81 Germany I Austria I German Switzerland +49-(0)6232-130128 Hungary +36-30-9-506-447 ltaly lltalian Switzerland +39-333-21 0-794 7 Latvia +32-(0)3-575-5555 The Netherlands +32-(0)3-575-0330 Norway +4 7-22-33-69-99 Poland +48-(0)601-66-2626 (SGS) I +48 (0) 14 637 40 81 (SPOT) Portugal +351-91-911-1399 Roman ia +40-744 -34-14-53 NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 10111 I EMERGENCY TELEPHONE NUMBER(S) I See section 16, for Emergency Telephone Numbers. NNALCO NALCO® 72215 PRODUCT I Russia I Selarus Saudi Arabia Serbia +32-(0)3-575-5555 Slovak Republic +421-(0)905-585-938 Slovenia +386-41-634-916 Spain +34-977-551577 Sweden +47 -22-33-69-99 UAE +44-(0)7071-223-738 UK and Republic of Iraland +44-(0)7071-223-738 Nalfleet International +32-(0)3-575-5555 POISON CONTROL CENTER TELEPHONE NUMBERS Belqium +32-70-245245 Czech Republic +420 224 91 92 93 Hungary_ +36-80-201-199 ETTSZ, 1096 Budapest, Nagyvárad tér 2 France +33:(0)145-42-59-59 ORFILA Slovak Republic +421 (0)2 54774166 Prepared By : SHE Department Date issued : 23.11.2009 Version Number: 2.6 Numbers quoled in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 11 /11 EMERGENCY TELEPHONE NUMBER(S) I See section 16, lor Emergency Telephone Numbers. +7-812-449-0474