Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
10 - 30 %
General Information
Revision date
2013-12-19
Product name
ZZ-Fire Protection Foam 2K NE
CAS No.
9016-87-9
1.2.1 Relevant identified uses
Di-/poly-isocyanate component to produce polyurethanes
Emergency telephone
Giftnotruf Berlin, Telephone: +49 (0) 30-30686790
Icons in SDS
Company Information
company name
ZAPP-ZIMMERMANN GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
Lars.Volkmer@kzim.de
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Classification According to Directive 67/548/EEC or 1999/45/EC: identification
CLP CLASSIFICATION
Skin Irrit. 2; H315 Causes skin irritation. Eye Irrit. 2; H319 Causes serious eye irritation. Resp. Sens. 1; H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sens. 1; H317 May cause an allergic skin reaction. Carc. 2; H351 Suspected of causing cancer. STOT SE 3; H335 May cause respiratory irritation. STOT RE 2; H373 May cause damage to organs through prolonged or repeated exposure.
EU Classification
Directive 67/548/EEC or 1999/45/EC Carc. Cat. 3; R40 Limited evidence of a carcinogenic effect. Xn; R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Xi; R36/37/38 Irritating to eyes, respiratory system and skin. Sens.; R42/43 May cause sensitization by inhalation and skin contact.
2.2 Label elements
CLP) (67/548/EEC or 1999/45/EC) Xn harmful
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use. P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water/soap. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P501 Dispose of contents/container to hazardous or special waste collection point.
R-phrase(s)
R 36/37/38 Irritating to eyes, respiratory system and skin. R 40 Limited evidence of a carcinogenic effect. R 42/43 May cause sensitization by inhalation and skin contact. R 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
S-phrase(s)
S 22 Do not breathe dust. S 24 Avoid contact with skin. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 46 If swallowed, seek medical advice immediately and show this container or label. Special labelling EUH204 Contains isocyanates. May produce an allergic reaction.
Contains
Diphenylmethane disocyanate (isomers, homologues)
2.3 Other hazards
Persons with over-sensitive breath ways (e.g. asthma, chronic bronchitis) are not allowed to use the product due to safety regulations. Vapours and aerosols are the main dangers to the respiratory tract. Respiratory symptoms may still occur several hours after overexposure. SECTION SECTION 3: 3: Composition