ZZ-Fire Protection Foam 2K NE

ZAPP-ZIMMERMANN GmbH

Revision date : 2013-12-19

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

10 - 30 %

General Information

Revision date

2013-12-19

Product name

ZZ-Fire Protection Foam 2K NE

CAS No.

9016-87-9

1.2.1 Relevant identified uses

Di-/poly-isocyanate component to produce polyurethanes

Emergency telephone

Giftnotruf Berlin, Telephone: +49 (0) 30-30686790

Icons in SDS

GHS07 GHS08

Company Information

company name

ZAPP-ZIMMERMANN GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

Lars.Volkmer@kzim.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification According to Directive 67/548/EEC or 1999/45/EC: identification

CLP CLASSIFICATION

Skin Irrit. 2; H315 Causes skin irritation. Eye Irrit. 2; H319 Causes serious eye irritation. Resp. Sens. 1; H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sens. 1; H317 May cause an allergic skin reaction. Carc. 2; H351 Suspected of causing cancer. STOT SE 3; H335 May cause respiratory irritation. STOT RE 2; H373 May cause damage to organs through prolonged or repeated exposure.

EU Classification

Directive 67/548/EEC or 1999/45/EC Carc. Cat. 3; R40 Limited evidence of a carcinogenic effect. Xn; R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Xi; R36/37/38 Irritating to eyes, respiratory system and skin. Sens.; R42/43 May cause sensitization by inhalation and skin contact.

2.2 Label elements

CLP) (67/548/EEC or 1999/45/EC) Xn harmful

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P201 Obtain special instructions before use. P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water/soap. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P501 Dispose of contents/container to hazardous or special waste collection point.

R-phrase(s)

R 36/37/38 Irritating to eyes, respiratory system and skin. R 40 Limited evidence of a carcinogenic effect. R 42/43 May cause sensitization by inhalation and skin contact. R 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

S-phrase(s)

S 22 Do not breathe dust. S 24 Avoid contact with skin. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 46 If swallowed, seek medical advice immediately and show this container or label. Special labelling EUH204 Contains isocyanates. May produce an allergic reaction.

Contains

Diphenylmethane disocyanate (isomers, homologues)

2.3 Other hazards

Persons with over-sensitive breath ways (e.g. asthma, chronic bronchitis) are not allowed to use the product due to safety regulations. Vapours and aerosols are the main dangers to the respiratory tract. Respiratory symptoms may still occur several hours after overexposure. SECTION SECTION 3: 3: Composition

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