Ammonium Chloride Granular (G, C Grades)

Classification (GHS-US)

Acute toxicity (oral) Category 4 H302 Serious eye damage/eye irritation Category 2A H319

Hazard statements

see section 16 GHS-US/CAN labeling H302 - Harmful if swallowed H319 - Causes serious eye irritation

Signal word

Warning

Precautionary statements

P264 -Wash thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P330 - Rinse mouth P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. No additional information available No data available | (CAS No) 12125-02-9 99.5-100 | Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Comb. Dust 12/03/2019 EN (English US) Page 1 SECTION 4: First-aid measures after inhalation Remove to fresh air immediately. If not breathing, give artificial respiration, preferably mouth-to mouth. If breathing is difficult, give oxygen. Call a physician. First-aid measures after skin contact Immediately wash the affected area with plenty of soap and water for a minimum of 15 minutes. Remove any contaminated clothing. Get immediate medical attention. Redness and sores may develop if contaminated area was not attended to immediately or improper washing was not thorough. First-aid measures after eye contact Flush eyes immediately with copious amounts of water for at least 15 minutes. Keep eyelids apart while irrigating the eyes. Get medical attention immediately. First-aid measures after ingestion Do not induce vomiting. Give large quantities of water or milk. Call a physician. Never give anything by mouth to an unconscious person. Symptoms/injuries Inhalation of upper respiratory tract resulting in coughing, excessive spitting and choking sensation. Reactions in humans have usually been limited to mild irritation or inflammation of the nose and throat. Symptoms/injuries after skin contact Ammonium chloride may cause skin irritation, or dermatitis on skin exposed for prolonged periods. Symptoms/injuries after eye contact Ammonium Chloride, including vapor, can cause irritation and inflammation of the eyes. Permanent damage to the eye can occur if substance is not immediately flushed from the eye. Symptoms/injuries after ingestion May be harmful if swallowed. Suitable extinguishing media Water, water fog, carbon dioxide (CO2), dry chemical. Unsuitable extinguishing media None. Fire hazard a fire. Explosion hazard None known. 6.1.1. For non-emergency personnel No additional information available 6.1.2. For emergency responders No additional information available Avoid release to the environment. For containment Stop the flow of material, if this is without risk. Methods for cleaning up Sweep up and recycle into process if contamination does not present a problem. Use appropriate protective equipment if dust is generated or contact with eyes or skin is expected. Flush residues and liquid to holding area for neutralization before discharge. Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Avoid dust generation. Avoid contact with skin and eyes. Do not allow product to enter sewage system or water bodies. 3A ROR Canc to te Re Storage conditions Keep container tightly sealed and in the original container. 42/03/2019 EN (English US) 216 “USA - ACGIH ACGIH TWA (mg/m?) 10 mg/m? (fume) USA - ACGIH ACGIH STEL (mg/m?) 20 mg/m? (fume) Canada (Quebec) VECD (mg/m?) 20 mg/m? (fume) Canada (Quebec) VEMP (mg/m*) 10 mg/m? (fume) Alberta OEL STEL (mg/m?) 20 mg/m? (fume) Alberta OEL TWA (mg/m?) 10 mg/m? (fume) British Columbia OEL STEL (mg/m?) 20 mg/m? (fume) British Columbia OEL TWA (mg/m?) 10 mg/m? (fume) Manitoba OEL STEL (mg/m?) 20 mg/m? (fume) Manitoba OEL TWA (mg/m?) 10 mg/m? (fume) New Brunswick OEL STEL (mg/m?) 20 mg/m? (fume) New Brunswick OEL TWA (mg/m?) 10 mg/m? (fume) New Foundland & Labrador | OEL STEL (mg/m?) 20 mg/m? (fume) New Foundland & Labrador OEL TWA (mg/m?) 10 mg/m? (fume) Nova Scotia OEL STEL (mg/m*) 20 mg/m? (fume) Nova Scotia OEL TWA (mg/m?) 10 mg/m? (fume) Nunavut OEL STEL (mg/m?) 20 mg/m? (fume) Nunavut OEL TWA (mg/m?) 10 mg/m? (fume) Northwest Territories OEL STEL (mg/m) 20 mg/m? (fume) Northwest Territories OEL TWA (mg/m?) 10 mg/m? (fume) Ontario OEL STEL (mg/m*) 20 mg/m? (fume) Ontario OEL TWA (mg/m?) 10 mg/m? (fume) Prince Edward Island OEL STEL (mg/m?) 20 mg/m? (fume) Prince Edward Island OEL TWA (mg/m?) 10 mg/m? (fume) Saskatchewan OEL STEL (mg/m?) 20 mg/m? (fume) Saskatchewan OEL TWA (mg/m?) 10 mg/m? (fume) Yukon OEL STEL (mg/m?) 20 mg/m? (fume) Yukon OEL TWA (mg/m?) 10 mg/m? (fume) Appropriate engineering controls Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Hand protection Wear impervious gloves to minimize skin contact. Eye protection Where chemical safety goggles or equivalent. Skin and body protection Wear suitable protective clothing. Respiratory protection |f airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection. PREETI ES EET Physical state Solid Appearance Granular nuggets, prills or rods. Color No data available Odor Odorless. Odor threshold No data available pH 4.0-6.0 Relative evaporation rate (butylacetate=1) No data available Melting point 642 °F (339°C) Freezing point No data available Boiling point > 212 °F (decomposes at 968°F/520°C) Flash point No data available Self ignition temperature No data available 12/03/2019 EN (English US) 3/6 Decomposition temperature No data available Flammability (solid, gas) No data available Vapor pressure No data available Relative vapor density at 20 °C No data available Relative density No data available Solubility Water: 100 % Log Pow No data available Log Kow No data available Viscosity, kinematic No data available Viscosity, dynamic No data available Explosive properties No data available Oxidizing properties No data available Explosive limits No data available SECTION 10: Stability and reactivity a ipatible materials Aluminum, zinc, tin and their alloys. Acute toxicity (oral) Oral: Harmful if swallowed. Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified | ATE CA (oral) | 500 mg/kg body weight - LD50 oral rat - 7 1 Skin corrosion/irritation Not classified pH: 4.0 - 6.0 Serious eye damage/irritation Causes serious eye irritation. pH: 4.0 - 6.0 Respiratory or skin sensitization Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity — single exposure =: Not classified Specific target organ toxicity — repeated Not classified exposure Aspiration hazard Not classified 12/03/2019 EN (English US) 4/6 Ecology - general Very toxic to aquatic life with long lasting effects. Aquatic acute Not classified Aquatic chronic Not classified LC50 fish 1 209 mg/l (Exposure time 96 h - Species Cyprinus carpio [static]) obili Wee Ses Deb No additional information available Ozone Not classified Product/Packaging disposal recommendations =: Dispose of contents/container in accordance with local/regional/national/international regulations. TDC Not regulated for transport Listed on the Canadian DSL (Domestic Sustances List) Listed _ Ammonium chlorid 25-02-9) U.S. - Massachusetts - Right To Know List U.S. - Minnesota - Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 12/03/2019 EN (English US) 5/6