BUG WASH

Hazard statements (CLP)

H320, H335, H351, H362, H372

Code

Statements

H320

Causes eye irritation

2.2 Label elements

,

Signal word

Danger j

Hazard statements

j H320 Causes eye irritation. 4 H335 May cause respiratory irritation. 4 H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. 7 ‘ H372 Causes damage to organs (blood, eyes, kidneys, liver) through prolonged or repeated exposure If swailowed, 3

Prevention

» P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood, P260." Do not breathe fume, mist, vapours, spray. P263 Avoid contact during pregnancy and while nursing. P264 Wash hands and skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. t

Product definition

BUG WASH - Ver, 1 SDS No.:? 1823 Date of preparation May 10, 2017 ‘ Date of Last Revision: Page 01 of 09 3 5 P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, eye protection. ‘ BUG WASH - Ver. 1 SDS No:: 1823 Date of preparation May 10, 2017 Date of Last Revision: Page 02 of 09 rm” clothing, shoes and leather goods before reuse or dispose of safely. en Eye Contact Mau Avoid direct contact, Wear chemical protective gloves if necessary. Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes, while holding the eyelid(s) open. If eye irritation persists, get medical advice or attention. Ingestion Rinse mouth with water. Never give anything by mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. If vomiting occurs naturally, lie on your side in the recovery position, Rinse mouth with water again. If breathing has stopped, trained personnel should immediately begin rescue breathing. If thé heart has stopped, trained personnel should start cardiopulmonary resuscitation (CPR) or automated external defibrillation (AED). Avoid mouth-to-mouth contact by using a barrier device. Immediately call a Poison Centre or doctor. Specific treatment is required. Most Important Symptoms and Effects, Acute and Delayed . No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Can cause headache, nausea, vomiting, dizziness, drowsiness and confusion. A severe exposure can cause stomach pain, muscle pain, difficult breathing and coma. Vision can be impaired and permanent blindness can result. There may be other permanent effects on the nervous system e.g. tremor, seizures. ; Immediate Medical Attention and Special Treatment a Target Organs Eyes, liver, nervous system. 3 a Special Instructions Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in symptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CNS, eyes and gastrointestinal tract. Because of the initial CNS‘s effects of headache, vertigo, lethargy and confusion, there may be an impression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are-common complaints. Treatment with ipecac or lavage is indicated in any patient presenting within two hours of ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severity than serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration with appropriate hospitals is recommended. BUG WASH - Ver, 1 SDS No.;* 1823 Date of preparation May 10, 2017 Date of Last Revision: Page 03 of 09 downwind locations. Use the personal protective equipment recommended in Section 8 of this safety data sleet. Increase ventilation to area or move leaking container to a well-ventilated and secure area. Eliminate all ignition sources, Use grounded, explosion-proof equipment. May accumulate in hazardous amounts in low-lying areas especially inside confined spaces, if ventilation is not sufficient. Distant ignition and flashback are possible. Environmental Precautions Do not allow into any sewer, on the ground or into any waterway. Methods and Materials for Containment and Cleaning Up Stop leak if without risk. Move containers from spill area, Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment, Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section waste disposal. Precautions for Safe ng Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or rmist, Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source, Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges, To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty 1 for emergency contact information and section 13 for 5 containers retain product residue and can be hazardous. Do not reuse container, Conditions for Safe Storage 4 Store in accordance with local regulations, Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment.to avoid environmental contamination. Control Parameters 4 ACGIH TLV® ; BUG WASH - Ver, 1 | SDS No.: f 1823 Date of preparation May 10, 2017 Date of Last Revision: Page 04 of 09 Wear chemical protective clothing e.g. gloves, aprons, boots. Nitrile rubber. Respiratory Protection Not normally required If product is used as directed. For non-routine or emergency situations: wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. O Basic Physical and Chemical Properties Appearance Available in these colours: Clear, Yellow, Gold, Red, Blue, Green, Amber, Pink, Orange, Purple, White, Brown. 7 Odour Pungent Odour Threshold Not available pH 7.5 - 11,0 (100% solution) t Melting Point/Freezing Point Not available (melting); Not available (freezing) | Initial Boiling Point/Range Not available Flash Point Not available Evaporation Rate Not available Flammability (solid, gas) Not applicable Upper/Lower Flammability or Not available (upper); Not available (lower) Explosive Limit Vapour Pressure Not available Vapotir Density (air= 1) Not available Relative Density (water = 1) 0,992 - 0.996 at 20 °C Solubility Soluble in water; Soluble in all proportions in alcohols (e.g. ethanol). Partition Coefficient, Not available n-Octanoi/Water (Log Kow) Auto-ignition Temperature Not available Decomposition Temperature Not available Viscosity Not available (kinematic); Not available (dynamic) j BUG WASH - Ver. 1 SDS No: 1823 Date of preparation May 10, 2017 Date of Last Revision: Page —s- 05 of: 09 Hazardous Decomposition Products Very toxic carbon monoxide, carbon dioxide; very toxic, flammable formaldehyde. Likely Routes of Exposure Ingestion; eye contact; skin contact; inhalation. Acute Toxicity Chemical Name LDLo + Oral LD50 (oral) LD50 (dermal) Methanol 143 mg/kg Human - Male 143 mg/kg Human - Male | 15800 mg/kg (rabbit) 2-Butoxyethanol 320 mg/kg (rabbit) 220 mg/kg (rabbit) 141,903 mg/L (4hr) (Rat) Vapour ATE Mixture 1 5628 mg/kg Oral (Rat) ' 4301.97 mg/kg Oral (Rat) ATE Mixture 63875,92 mg/kg Dermal (Rabbit) ATE Mixture Skin Corrosion/Irritation Human experience shows very mild irritation. Serious Eye Damagellrritation Human experience and animal tests show mild irritation. STOT (Specific Target Organ Toxicity) - Single Exposure Infialation May be harmful based on animal tests. Depression of the central nervous system. Symptoms may include headache, nausea, dizziness, drowsiness and confusion. A severe exposure can cause unconsciousness, (2-Butoxyethanol) at high concentrations May be harmful based on human experience. Nose and throat irritation. (2-Butoxyethanol). (Methanol) at high concentrations. t Skin Absorption . j May be harmful based on animal tests. j Ingestion Toxic, can cause death depression of the central nervous system, impaired vision and blindness. In some cases, there may be delayed effects on the nervous system. Symptoms may include headache, nausea, vomiting, dizziness, drowsiness and confusion, A severe exposure may cause stomach pain, muscle pain, difficult breathing and coma, Vision can be impaired and permanent blindness can result. There may be other permanent effects on the nervous system e.g. tremor, seizures. If large amounts are swallowed. Aspiration Hazard Not known to be an aspiration hazard. STOT (Specific Target Organ Toxicity) - Repeated Exposure If swallowed: liver function tests may show abnormal results, May cause Following skin contact: dermatitis. Symptoms may include dry, red, cracked skin (dermatitis), (2-Butoxyethanol) May cause If inhaled: at high concentrations blood tests may show abnormal results. (2-Butoxyethanol) May cause If inhaled and/or following skin contact: at high concentrations harmful effects on the kidneys. (2-Butoxyethanol) Respiratory and/or Skin Sensitization dae Not known to be a respiratory sensitizer. Not known to be a skin sensitizer. owe Carcinogenicity Chemical Name IARC ACGIH® NTP OSHA x Methanol Not Listed Not designated Not Listed Not Listed, Product Identifier: BUG WASH - Ver. 1 SDS No.: 1823 Date of Preparation: May 10, 2017 Date of Last Revision: Page 06 of 09 ERs y 2-Butaxyethanol Group 3 A3 INot Listed Not Listed: May cause cancer based on animal studies. Reproductive Toxicity Development of Offspring Animal studies show effects on the offspring. If innaled known to cause decreased weight, birth defects, Teratogenic(external, soft tissue and skeletal defects) embryotoxic (late resorptions). Sexual Function and Fertility Not known to cause effects on sexual function or fertility. Effects on or via Lactation Can transfer to mother's milk. May cause harm to breastfed babies. Germ Cell Mutagenicity Conclusions cannot be drawn from the limited studies available. Interactive Effects No information was located. This section is not required by OSHA HCS 2012, This section is not required by WHMIS. Ecotoxicity Agute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea Blonts Aquatic ErC50 Algae Methanol 15400 mg/L. 10000 mg/L (Lepomis (Daphnia magna macrochirus (water flea); 48-hour) (bluegill); 96-hour) 2-Butoxyethanol 220 mg/L 1815 mg/L (Daphnia (Oncorhynchus magna (water flea); mykiss (rainbow 24 hr) trout); 96-hour; fresh water) Chronic Aquatic Toxicity Chernical Name NOEC Fish EC50 Fish NOEC Crustacea EC50 Crustacea Methanol 7900 mg/L (Lepomis macrochirus Ar (bluegill); 200-hrs) 2-Butoxyethanol Not available Persistence and Degradability Degrades rapidly based on quantitative tests. Bioaccumulative Potential This product and its degradation products are not expected to bioaccumulate. Mobility in Soil No information was located, Other Adverse Effects There is no information available. Product identifier: BUG WASH - Ver. 1 SDS No.: 1823 Date of Preparation: May 10, 2017 Date of,Last Revision: Page _ 07 of 09

Response

P304 + P340 IF INHALED: Remove person to fresh alr and keep comfortable for breathing. P312 Call a POISON CENTRE or doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do, Continue rinsing. P312_ Call a POISON CENTRE or doctor if you feel unwell. P337-+ P313 If eye irritation persists: Get medical advice or attention.

Storage

Store in a well ventilated place. Keep cool. Keep container tightly closed. Store locked up.

Disposal

Dispose of contents/container in accordance with applicable regional, national and local laws and regulations.

2.3 Other hazards

. None known. Mixture: Chemical Name CAS No. % Other Identifiers |Other Names Methanol 67-56-1 1-5 2-Butoxyethanol 111-76-2 0.1-1 Notes , Use of Generic SDS: If the concentration or actual concentration range of an ingredient of a particular hazardous product in the series is — different from the concentration or actual concentration range disclosed for the rest of the series, either the concentration or the actual concentration range must be indicated beside that ingredient under item 3 E (Composition/Information on ingredients) of the SDS. Furthermore, if any other specific information element(s) (such as flash point, numerical measure of toxicity, etc.) for a particular hazardous product in the series differs from that of the other products in the series (without affecting the classification), the information element relevant to that hazardous product must be disclosed on the SDS with an indication to which hazardous product each relates, Source: Health Canada - Technical Guidance on the Requirements of the Hazardous Products Act and the Hazardous Products Regulations

Medical Conditions Generally Aggravated by Exposure

Respiratory conditions. , Ext guis ng Media Suitable Extinguishing Media Not combustible. Use extinguishing agent suitable for surrounding fire. Unsuitable Extinguishing Media Not applicable. Specific Hazards Arising from the Product Does not burn, In a fire, the following hazardous materials may be generated: toxic chemicals; very toxic carbon monoxide, carbon . dioxidé; very toxic, flammable formaldehyde. Special Protective Equipment and Precautions for Fire-fighters Review Section 6 (Accidental Release Measures) for important information on responding to leaks/spills. See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective materials. rotective Equipment, and Emergency Procedures Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel, Evacuate

Further information

Physical State Liquid Molecular Weight Not available Other-Physical Property 1 Available in these Colours: Red, Blue Reactivity None Known. Chemical Stability Normally stable. Possibility of Hazardous Reactions None known. Conditions to Avoid Heat. Open flames, sparks, static discharge, heat and other ignition sources. Prolonged storage. Evaporation of solution. Light. Incompatible Materials Slightly reactive or incompatible with the following materials: oxidizing agents (e.g. peroxides), strong acids (e.g. hydrochloric acid), strong bases (e.g. sodium hydroxide). Not corrosive to metals.