FLOORGUARD HYBRID PU

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) Vapour pressure ACUTE TOXICITY Information not relevant - GHS: Globally Harmonized System of classification and labeling of chemicals EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering Not available Vapour density C(M)IT/MIT (3:1) - IATA DGR: International Air Transport Association Dangerous Goods Regulation medical advice/attention. places in which people eat. Not available

2.1 Classification of the substance or mixture

Relative density LC50 (Inhalation) of the mixture: LC50 - for Fish - IC50: Immobilization Concentration 50% 1,08-1,26 > 0,19 mg/l/96h Not classified (no significant component) g/ml SECTION 15. Regulatory information SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. 7.2. Conditions for safe storage, including any incompatibilities Solubility LD50 (Oral) of the mixture: EC50 - for Crustacea - IMDG: International Maritime Code for dangerous goods INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly Not available > 0,16 mg/l/48h Not classified (no significant component) The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Partition coefficient: n-octanol/water LD50 (Dermal) of the mixture: EC50 - for Algae / Aquatic Plants - IMO: International Maritime Organization The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Not available > 0,018 mg/l/72h Not classified (no significant component) authorised by a doctor. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Auto-ignition temperature - INDEX NUMBER: Identifier in Annex VI of CLP However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Not available 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away 12.2. Persistence and degradability sheet with appropriate information, compliant to (EU) Regulation 2015/830. Decomposition temperature - LC50: Lethal Concentration 50% sheet with appropriate information, compliant to (EU) Regulation 2015/830. Not available breathing, administer artificial respiration. Take suitable precautions for rescue workers. from any incompatible materials, see section 10 for details. Viscosity - LD50: Lethal dose 50% Seveso Category - Directive 2012/18/EC: BIT 90-110 KU None Hazard classification and indication: Explosive properties Information not available - OEL: Occupational Exposure Level Hazard classification and indication: LD50 (Oral) -- Not available > 2,175 mg/kg 1,2-benziosothiazolin-3-one 4.2. Most important symptoms and effects, both acute and delayed 7.3. Specific end use(s) Oxidising properties

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 LD50 (Dermal) Not available > 1,221 mg/kg 1,2-benziosothiazolin-3-one - PEC: Predicted environmental Concentration Specific information on symptoms and effects caused by the product are unknown. Information not available None LC50 (Inhalation) 0,5 mg/l

Further information

12.3. Bioaccumulative potential

2.2 Label elements

PEL: Predicted exposure level 4.3. Indication of any immediate medical attention and special treatment needed - PNEC: Predicted no effect concentration Substances in Candidate List (Art. 59 REACH) C(M)IT/MIT (3:1) SECTION 8. Exposure controls/personal protection Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. VOC (Directive 2010/75/EC) : Information not available - REACH: EC Regulation 1907/2006 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. LD50 (Oral) > 300 mg/kg On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. - RID: Regulation concerning the international transport of dangerous goods by train Information not available LD50 (Dermal) > 2000 mg/kg

Hazard pictograms

Information not available - TLV: Threshold Limit Value -- 8.1. Control parameters Substances subject to authorisarion (Annex XIV REACH) 12.4. Mobility in soil SKIN CORROSION / IRRITATION - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. None SECTION 5. Firefighting measures

Signal word

TWA STEL: Short-term exposure limit -- SECTION 10. Stability and reactivity Information not available Does not meet the classification criteria for this hazard class Information not available - TWA: Time-weighted average exposure limit 5.1. Extinguishing media Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:

Hazard statements

VOC: Volatile organic Compounds 10.1. Reactivity 8.2. Exposure controls None Safety data sheet available on request. SERIOUS EYE DAMAGE / IRRITATION

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation EUH210

Results of PBT and vPvB assessment

SUITABLE EXTINGUISHING EQUIPMENT - WGK: Water hazard classes (German). EUH208

Contains

C(M)IT/MIT (3:1) There are no particular risks of reaction with other substances in normal conditions of use. Substances subject to the Rotterdam Convention: The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Does not meet the classification criteria for this hazard class BIT None UNSUITABLE EXTINGUISHING EQUIPMENT well aired through effective local aspiration. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. May produce an allergic reaction. 10.2. Chemical stability None in particular. When choosing personal protective equipment, ask your chemical substance supplier for advice. RESPIRATORY OR SKIN SENSITISATION GENERAL BIBLIOGRAPHY Substances subject to the Stockholm Convention: Information not available 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament P102 Keep out of reach of children. 10.3. Possibility of hazardous reactions Healthcare controls HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. C(M)IT/MIT (3:1) 4. Regulation (EU) 2015/830 of the European Parliament P273 Avoid release to the environment. Information not available Do not breathe combustion products. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on BIT 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament P301+P312 IF SWALLOWED: Call a POISON CENTER / doctor / . . . / if you feel unwell. SECTION 13. Disposal considerations No hazardous reactions are foreseeable in normal conditions of use and storage. the duration and type of use. 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 5.3. Advice for firefighters SKIN PROTECTION GERM CELL MUTAGENICITY 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 10.4. Conditions to avoid 13.1. Waste treatment methods Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament

Other hazards

Personal protective equipment must be CE marked, showing that it complies with applicable standards. 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 5.2. Special hazards arising from the substance or mixture The product is stable in normal conditions of use and storage. None HAND PROTECTION

Precautionary statements

May produce an allergic reaction. 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament Protect hands with category III work gloves (see standard EN 374).

2.3 Other hazards

GENERAL INFORMATION with soap and water after removing protective clothing. Does not meet the classification criteria for this hazard class 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament None in particular. However the usual precautions used for chemical products should be respected. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for EYE PROTECTION 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Wear airtight protective goggles (see standard EN 166). CARCINOGENICITY 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. CONTAMINATED PACKAGING contaminated water used for extinction and the remains of the fire according to applicable regulations. RESPIRATORY PROTECTION 12. Regulation (EU) 2016/1179 (IX Atp. CLP) EPY 9.6.2 - SDS 1004.9