PY¥thon Insecticide Cattle Ear Tag

Hazard statements (CLP)

H225, H302, H315, H317, H319, H332, H335, H351, H373, H412, H413

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

Health Environmental Physi Acute Toxicity: Category 4 (Oral) Acute Toxicity: Unknown, See Section 12 None Known Skin Irritation: No Chronic Toxicity: Category 4 Skin Sensitization: No Eye: No

Signal word

WARNING DANGER

Hazard pictograms

Exclamation — acute toxicity, Environmentally hazardous substance

Precautionary statements

WARNING P101 lf medical advice is needed, have product container or label at hand H302 Harmful if swallowed P102 Keep out of reach of children H413 May cause long lasting harmful P103 Read label before use effects to aquatic life P264 Wash thoroughly with soap and water afler handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment P301+P312 IF SWALLOWED: Do not induce vomiting unless told te do so by a poison control center or physician. Do not give anything by mouth to an unconscious person. Call a physician if you feel unwell. P330 Rinse mouth P501 Dispose of contents by securely wrapping and discarding in trash. Non-refillable container. Do not reuse. Discard in trash or offer for recycling. COMPOSITION/INFORMATION ON INGREDIENTS Concentration (wiw) CAS Number % gikg Handling Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Do not contaminate food, feedstutls or water. This product is extremely toxic to fish and aquatic invertebrates. Do not contaminate water by disposal of used tags. Remove tags before animal slaughter. DANGER P101 If medical advice is needed. have product container or label at hand. H225 Highly flammable P102 Keep out of reach of children. liquid and vapour P103 Read label before use. H315 Causes sk1n P202 Do not handle until all safety precautions have been read and understood. irritation P210 Keep away from heaVsparks/open flames/hot surfaces. No smoking. H317 May cause an P233 Keep container tightly dosed. allergic skin P240 Ground/bond container and receiving equipment reaction P241 Use explosion-proof electricaVventilating/lighting equipment. H319 Causes serious eye P242 Use only non-sparking tools. irritation P243 Take precautionary measures against static discharge. H332 Harmful if inhaled P260 Do not breathe mist. spray, vapours. H335 May cause P264 Wash thoroughly after handling. respiratory imtation P270 Do not eat. drink or smoke when using this product. H351 Suspected of P271 Use only outdoors or in a well-ventilated area. causing cancer P272 Contaminated work clothing must not be allowed out of the workplace. H373 May cause damage P273 Avoid release to the environment. to organs through P280 Wear protective gloves and eye protection. prolonged or P302+P352 IF ON SKIN: Wash with plenty of water. repeated exposure P303+P361 +P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with H412 Harmful to aquatic water/shower. life with long lasting P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing effects P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P332+P337+P313 If skin irritation/rash or eye irritation occurs or persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash It before reuse. P370+P378 In case of fire: Use alcohol resistant foam, carbon dioxide or dry chemical to extinguish. P403+P233 Store in well-ventilated place. Keep container tightly dosed. P403+P235 Store in well-ventilated place. Keep cool. P405 Store locked up P501 Dispose of contents/containers to hazardous or special waste collection point, in accordance With applicable federal, state and local reaulations. Non-refillable container. Do not reuse.

Hazardous Ingredients

Zeta-cypermethrin, 5-enantiomer (FMC 56701) 10.0% 100 52315-07-8 S-cyano (3-phenoxypheny!) methyl (+) cisfrans 3-(2,2-dichloroetheny!)-2,2 Dimethylcyclopropane-carboxylate* *cis/trans ratio: max. 55% (4) cis and min. 45% (+) trans, inert related Compounds less than 2%. Piperonyl Butoxide 20.0% 200 51-03-6 (butylcarbityl) (6-propylpiperonyl) ether and related compounds FIRST AID | Eye Contact: Eye contact may cause mild irritation. If contacted, hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, afler first 5 minutes, then continue rinsing eye. If irritation persists, seek medical attention. Skin Contact: Wash skin immediately and thoroughly with soap and water for 15-20 minutes after contact. Ingestion: May be harmful if swallowed. If part of tag is swallowed, have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Cail physician. inhalation: No apparent hazard with normal use. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth to mouth, if possible. Other This product contains zetacypermethrin, a pyrethroid insecticide, and piperonyl butoxide, a mixed-function oxidase inhibitor. Information: Note to physician: Treatment is controlled removal of exposure followed by symptomatic and supportive care. FIRE FIGHTING MEASURES = Flash Paint (method): Not Applicable Autoignition Temperature: Not Determined LEL: Not Applicable UEL: Not Applicable Flammability Classification: | Not Applicable Extinguishing Media: Foam, CO, or dry chernical. Soft stream water fog only if necessary. Contain all runoff. Hazardous Combustion Products: On burning may decompose to form carbon monoxide, carbon dioxide, hydragen cyanide, chlorine and hydrogen chloride. Unusual Fire or Explosion Hazards: Not applicable. This product is not explosive. Fire-F ighting Instructions/Equipment: (For a large quantity of product) Isolate fire area, Evacuate downwind. Wear full protective clothing and self- contained breathing apparatus. Do not breathe or contact smoke, gases or vapors generated. Runoff must be contained due to fish toxicity, ACCIDENTAL RELEASE MEASURES Use recommended personal protective equipment (see Section 8). Small spill Solid product. Not applicable. Large Spill Solid product [ SECTION 7: Not Applicable. HANDLING AND STORAGE

Storage

Requirements: Store in original container in a dry, cool place away from direct sunlight. Do not store near heat or open flame. Opened bags containing ear tags should be re-sealed for storage. Y-TEX• Corporation SAFETY DATA SHEET Product Name: PYthool!llnsecticide Cattle Ear Tag 2 of 2 Er9Jsh I EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS: Component U.S. OSHA PEL ACGIHTLV Eye/Face Protection: None required. Skin Protection-Gloves: Wear long-sleeved shirt, long pants, socks, shoes and rubber or non-permeable protective gloves when applying tags. Respiratory Protection: None required. Engineering Controls: None required. Administrative Controls: Use this product only as specified on th1s label.

Further information

See Section 7 I SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance/Physical State: Solid, molded plastic ear tag, pinkish purple (mauve) color Odor: Essentially odorless Odor Threshold (ppm): Not applicable pH: Not applicable Melting Point: Approx. 150'C (302' F) Boiling Point: Not applicable Flash Point: Not applicable Evaporation Rate: Not applicable Flammability (solid, gas) Solid, Nonflammable LEL: Not applicable UEL: Not applicable Vapor Pressure (mm Hg)· 1.9 x 1 o-t mm Hg for zetacypermethrin a.i. Vapor Density (Air= 1): 1.219 g/cm3, @ 25•c for zetacypermethrin a.i. Relative Density: 1.21 g/ml (9.5 gltag) Specific Gravity (HzO = 1): Not applicable Solubility in Water: Essentially Insoluble Coefficient or Water/Oil solubility: Not applicable Autoignition Temperature: Not applicable Decom sition Tern rature. Not a licable V.O.C.: Not a licable Chemical Stability: Stable Hazardous Polymerization: Will not occur Conditions to Avoid: Do not store near heat or flame. Opened bags containing ear tags should be re"sealed for storage. Chemicals to Avoid: None known. Hazardous Decomposition Products: On burning may decompose to form carbon monoxide, carbon dioxide, hydrogen cyanide, chlorine and hydrogen chloride. I SECTION 11: Revision Date: 2/12/19 Australia APVMA Reg. No.: 48148 Dominican Republic: 6937 USA EPA Reg. No.: 39039-4 Brazil lie Min. Agri. No.: 7.640 New Zealand ACVM No.: A9151 USA EPA Establishment No.: 39039-WY -01 Colombia Reg ICA No.: 6100-MV Puerto Rico Reg. No.: 19-1514-3 The ortonnaiJon conlaoned herein os based on data available to us .00 11 aa:uate and rebiDie to the beSI d ou- knowledge and belief Howe-. y. TEX Corporebon makes no represenl81ionl IS 1o ots ~eteness or ecancy lnformaUon '' ~ed on mnclotoon tlllt persons reoeovong such .ntormetoon !Mil make their own c!eterminanon as to its SLilablioty for their JUPOSeS prior to use In no ewnt woll y. TEX Corporatoon be responsoble for clamages ol any nature whai!IOe'Jer resulting from the use of or reloance upon the information a>ntained hereon I SECTION PRODUCT COMPANY IDENTIFICATION 1: and Product Name: Tag Marking Pen (0612000) Date Prepared February 28, 2013 Tag Marking Ink (0607000) Revision Date: October 30, 2018 Y • TEX Corporation For Health Safety Emergency Only, Call CHEM-TEL, Inc. (24 hours): 1-800..255-3924 US 1825 Big Horn Ave. 813-248-0585 International Cody, WY 82414 Calls 800-443-6401 , 307-587-5515 (Y-TEX) 7 30am- 4 30pm MDT, Monday-Friday) Environmental Phvsical Acute Toxicity: Aquatic Chronic 3 Flammable Liquids & Vapours Respiratory: Category 2 Skin Sensitization: Carcin

TOXICOLOGICAL INFORMATION

Acute Effects: Low single dose toxicity: Eyes: Eye contact may cause mild Irritation. Avoid eye contact with tags or used gloves. If contacted, flush with plenty of water. If irritation pers1sts. seek medical attention. Skin: Acute dermal LDso>5000 mglkg (male & female albino rats). Skin irritant No (albino rabbits); Skin sensitizer No (guinea pigs). Wash thoroughly with soap and water after handling. Ingestion: Acute oral LDso>1 000 mg/kg (rats. estimated for whole tag). May be harmful if swallowed. Have person sip a g[~ss _or :-vater if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an Move person to fresh air. Not Determined Carcinogenicity: None known Not Determined Target Organ Effects: Not Determined Sensitization to Product. Skin - No (guinea pigs) Irritancy of Product: Skin - No (albino rabbits) resentl known. Do not apply directly to water. Do not contaminate water by disposal or used tags. Pesticide Disposal. Remove tags before animal slaughter. Securely wrap used tags in a plastic bag or several layers of newspaper and discard in trash. Do not reuse tag container. Discard in trash. at: Non-refillable container. Do not reuse ba . Discard b in trash, or offer for re di if available. TRANSPORT INFORMATION Not regulated for transport UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zetacypermethrin mixture), Class 9, PG Ill, limited Quantity, Marine Pollutant I SECTION 15: REGULATORY INFORMATION This chemical is a pestid de product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if swallowed. Wear to "Sleeved shirt ton

Hazard statements

Svmbols: Flammables Exclamation- Acute Toxicitv, Health Hazard