1,1-methylenebis

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Carc.2-H351

Other physicochemical hazards

STOT SE.3-H335 Human health: Acute Tox.4-H332, Skin Irrit.2-H315, Eye Irrit.2-H319, Resp Sens.1-H334, Skin Sens.1- STOT RE.2-H373 H317, Carc.2-H351, STOT SE.3-H335, STOT RE.2-H373

Environmental hazards

Acute Tox.4-H332 26447- 01- Reaction mass of 4,4- Skin Irrit.2-H315 2119457015- methylenediphenyl diisocynte

2.2 Label elements

4040-5 45 Eye Irrit.2-H319 & o-(p-isocyanatobenzyl) Label In Accordance With (EC) No.

Signal word

Danger Carc.2-H351 STOT SE.3-H335

Hazard statements

H332 - Harmful if inhaled STOT RE.2-H373 H315 - Causes skin irritation 4. FIRST AID MEASURES H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation 4.1 Description of first aid measures H334 - May cause an allergy or asthma symptoms or breathing difficulties if inhaled General information H351 - Suspected of causing cancer Take off immediately all contaminated clothing. including shoes. Obtain medical attention H335 - May cause respiratory irritation Inhalation H373 - May cause damage to organs through prolonged or repeated exposure Move patient from contaminated area to fresh air. If not breathing, give artificial respiration. Obtain immediate

Contains

Reaction mss of 4,4-methylenediphenyl diisocynte & o-(p-isocyanatobenzyl) medical attention. Treatment is symptomatic. phenyl isocyanate Skin contact: Isocyanates, may cause an allergic reaction Wash immediately and thoroughly with soap and water. Obtain medical attention if irritation occurs Eye contact:

Precautionary statements

P260+284 Do not breathe dust/vapour/spray, in case of inadequate ventilation Wash open eyes immediately and thoroughly for at least 15 minutes. Obtain immediate medical attention. wear respiratory protection Ingestion P280 Wear protective gloves/clothing/eye protection/face protection Do NOT induce vomiting. Give nothing to eat or drink. Wash mouth out with water Consult a physician. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a comfortable 4.2 Most important symptoms and effects, both acute and delayed position Irritation P302+352IF ON SKIN: Wash with plenty of soap and water 4.3 Indication of any immediate medical attention and special treatment needed P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes, remove In case of inhalation of decomposition products in a fire, symptoms may be delayed, surveillance for 48h. contact lenses if present and easy to do so, continue rinsing Treatment should be symptomatic. P310 Immediately call a poison center/doctor

2.3 Other hazards

None Known 5. FIRE FIGHTING MEASURES

Results of PBT and vPvB assessment

This information is not required 5.1. Extinguishing media