MEDALLION TL

Hazard statements (CLP)

H411

Code

Statements

H411

Toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Additional Product Safety Information Classification of the substance or mixture This section does not form part of the product label under the Plant Protection Products Regulations 1995.)

2.2 Label elements

use has ‘extensions of use’ approval or is otherwise permitted under the Plant Protection Product Regulations.

Hazard pictograms

Safety Data Sheet SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product definition

Product name MEDALLION TL Design Code A17856B

Hazard statements

H411 Toxic to aquatic life with long lasting effects. 1.2 Relevant identified uses of the substance or mixture and uses advised against EUH401 To avoid risks to human health and the environment comply with the 1.3 Details of the supplier of the safety data sheet Company instructions for use. Company Syngenta UK Ltd Precautionary P391 Collect spillage. CPC4, Capital Park, Statements P501 Dispose of contents/container to a licensed hazardous-waste disposal Fulbourn, Cambridge contractor or collection site except for empty clean containers which can CB21 5XE be disposed of as non-hazardous waste. Telephone +44 (0) 1223 883400 Telefax +44 (0) 1223 882195

Supplemental label elements

Use EUH208 Fungicide

Contains

1,2-benzisothiazol-3-one. May produce an allergic reaction

2.1 Classification of the substance or mixture

(This section does not form part of the product label under the Plant Protection Products Regulations 1995.) Classification (REGULATION (EC) No 1272/2008) Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects. The product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular 2.2 Label elements use has ‘extensions of use’ approval or is otherwise permitted under the Plant Protection Product Regulations. Labelling: Regulation (EC) No. 1272/2008 The information on this label is based on the best available information including data from test results. Hazard pictograms Safety Data Sheet SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product name MEDALLION TL Design Code A17856B Hazard Statements H411 Toxic to aquatic life with long lasting effects. 1.2 Relevant identified uses of the substance or mixture and uses advised against Supplemental Hazard Use EUH208 Fungicide Contains 1,2-benzisothiazol-3-one. May produce an allergic reaction. Statements EUH401 To avoid risks to human health and the environment comply with the 1.3 Details of the supplier of the safety data sheet Company instructions for use. Company Syngenta UK Ltd Precautionary P391 Collect spillage. CPC4, Capital Park, Statements P501 Dispose of contents/container to a licensed hazardous-waste disposal Fulbourn, Cambridge contractor or collection site except for empty clean containers which can CB21 5XE be disposed of as non-hazardous waste. Telephone +44 (0) 1223 883400 Telefax +44 (0) 1223 882195 2.3 Other hazards Website www.syngenta.co.uk This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 1.4 Emergency telephone number Emergency telephone number +44 (0) 1484 538444 4 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS SECTION 5. FIRE-FIGHTING MEASURES 3.2 Mixtures 5.1 Extinguishing media Chemical Name CAS-No. EC No. Classification Concentration (%) Suitable extinguishing media : Registration number (REGULATION (EC) No Extinguishing media - small fires 1272/2008 Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. fludioxonil 131341-86-1 Aquatic Acute1; H400 >= 10 - < 20 Extinguishing media - large fires Aquatic Chronic1; H410 Alcohol-resistant foam or Water spray poly(oxy-1,2- ethanediyl), 99734-09-5 Aquatic Chronic3; H412 >= 1 - < 2.5 Unsuitable extinguishingmedia: Do not use a solid water stream as it may scatter and spread fire. -[2,4,6- tris(1- phenylethyl) phenyl]- -hydroxy- 5.2 Specific hazards arising from the substance or mixture bronopol (INN) 52-51-7 Acute Tox. 4; H302 < 0.1 Specific hazards during firefighting: As the product contains combustible organic components, fire will 200-143-0 Acute Tox. 4; H312 produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to Skin Irrit. 2; H315 decomposition products may be a hazard to health. Eye Dam. 1; H318 STOT SE 3; H335 5.3 Advice for firefighters Aquatic Acute 1; H400 Special protective equipment for firefighters: Wear full protective clothing and self-contained breathing apparatus. 1,2-benzisothiazol-3(2H)-one 2634-33-5 Acute Tox. 4; H302 < 0.05 220-120-9 Skin Irrit. 2; H315 Eye Dam. 1; H318 SECTION 6. ACCIDENTAL RELEASE MEASURES Skin Sens. 1; H317 6.1 Personal precautions, protective equipment and emergency procedures Aquatic Acute 1; H400 Personal precautions : Refer to protective measures listed in sections 7 and 8. For explanation of abbreviations see section 16. 6.2 Environmental precautions Environmental precautions : Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. SECTION 4. FIRST AID MEASURES 4.1 Description of first aid measures 6.3 Methods and materials for containment and cleaning up General advice : Have the product container, label or Safety Data Sheet with you when calling the emergency Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. number, a poison control center or physician, or going for treatment. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national If inhaled : Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. regulations (see section 13). Keep patient warm and at rest. Call a physician or poison control centre immediately. In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of 6.4 Reference to other sections water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. Refer to disposal considerations listed in section 13., Refer to protective measures listed in sections 7 and 8.