Silicone Spray 500m l

SECTION 2: Hazards identification

1272/2008 (REGULATION (EC) No

2.2 Label elements

REGULATION (EC) No EUH208

Signal word

Danger

Hazard statements

H2 Extrem ely flam m able aerosol. H29 Pressurised container: M ay burst if heated. H315 Causes skin irritation. H412 Harm ful to aquatic life with long lasting effects. Precautionary statem ents

Prevention

P210 Kep away from heat, hot surfaces, sparks, open flam es and other ignition sources. No sm oking. P211 Do not spray on a n open flam e or other ignition source. P251 Do not pierce or burn, even after use. P264 W ash skin thoroughly after handling. P273 Avoid release to the

Storage

P410 + P412 Protect from sunlight. Do not expose to tem - peratures exceding 50 °C / 122 °F. Additional 7.1 Precautions for safe handling Technical m easures Se Engineering m easures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation Use with local exhaust ventilation. Advice on safe handling Do not get on skin or clothing. Avoid inhalation of vapour or m ist. Do not swallow. Avoid contact with eyes. ash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of workplace exposure as- sessm ent Kep away from heat, hot surfaces, sparks, open f lam es and other ignition sources. No sm oking. Take precautionary m easures against static discharges. Take care to prevent spills, waste and m inim ize release the including any incom patibilities Requirem ents for Kep in a cool, well -ventilated place. Store in accordance with areas and containers the particular national regulations. Do not pierce or burn, even after use. Kep cool. Protect from sunlight. Advice on com m Do not store with the following product types: Self -reactive substances and m ixtures Organic peroxides Oxidizing agents Flam m able solids Pyrophoric liquids Pyrophoric solids Self -hea ting substances and m ixtures Substances and m ixtures, which in contact with water, em it flam m able gases Explosives Gases Recom m ended storage tem < 40 °C perature 7.3 Specific end use(s) Specific use(s) No data available protection SECTION 8: Exposure controls/personal 8.1 Control param eters Ocupational Exposure Lim its Com ponents CAS -No. Value type (Form Control param eters Basis of exposure Butane 106 -97 -8 OELV in 1,000 ppm IE OEL (STEL) Hydrocarbons, C6 Not As- OELV - 8 hrs 500 pm IE OEL C7, n -alkanes, signed (TW A) 1,800 m g/m 3 isoalkanes, cyclics, <5% n -hexane OELV in 1,000 ppm IE OEL (STEL) 3,600 m g/m 3 Hydrocarbons, C6, 64742 -49 -0 OELV - 8 hrs 500 pm IE OEL isoalkanes, <5% n (TW A) 1,800 m g/m 3 hexane OELV in 1,000 ppm IE OEL (STEL) 3,600 m g/m 3 Hydrocarbons, C7, 64742 -49 -0 OELV - 8 hrs g/m 3 IE OEL n-alkanes, isoal- (TW A) (inhalable kanes, cyclics fraction Hydrocarbons, C9 Not As- OELV - 8 hrs g/m 3 IE OEL C10, n -alkanes, signed (TW A) (inhalable isoalkanes, cyclics, fraction <2% arom atics Cyclohexane 110 -82 -7 TW A 200 pm 2006/15/EC 700 m g/m 3

Contains

R) -p-m entha -1,8 -diene . M ay produce an allergic reaction. ent to kep aterial from spreading. dyked If can be pum ped, store recovered m aterial in apropriate container. Clean up rem aining m aterials from spill with suitable absor- bent. Local or national regulations m ay a ply to releases and dis- posal of this m aterial, as well those aterials and item s em ployed in the cleanup of releases. You will need to deter- ine which regulations are applicable. Sections 13 and 15 of this SDS provide inform ation regarding certain loca l or national requirem ents. 6.4 Reference to other sections Se sections: 7, 8, 11, 12 and 13. Handling and

2.3 Other hazards

This substance/m ixture contains no com ponents considered to be either persistent, bioaccum ula- tive and toxic

PBT Substances

or very persistent bioaccum ulative

vPvB Substances

at levels of 0.1% higher. Ecological inform ation The substance/m ixture does not contain com ponents considered to have endocrine disrupting properties according to REACH Article 57(f) or Com m ission Delegated regu- lation (EU) 2017/2100 or Com m ission Regulation 2018/605 at levels of 0.1% higher. To xicological inform ation The substance/m ixture does not contain com ponents considered to have endocrine disrupting properties according to REACH Article 57(f) or Com m ission Delegated regulation (EU) 2017/2100 or Com m ission Regulation 2018/605 at level s of 0.1% or higher. ingredients SECTION 3: Com position/inform ation on 3.2 M ixtures Com ponents Chem ical nam e CAS -No.

2.1 Classification of the substance or mixture

Concentration EC -No. w/w Index -No. Registration num ber Hydrocarbons, C6 -C7, n -alkanes, Not Assigned Flam Liq. . 2; H225 >= 2.5 - < 10 isoalkanes, cyclics, <5% n Skin Irrit. 2; H315 hexane 01 -211947514 -35 STOT SE 3; H36 Asp. Tox. 1; H304 Aquatic Chronic 2; H41 Hydrocarbons, C6, isoalkanes, 64742 -49 -0 Flam Liq. . 2; H225 >= 2.5 - < 10 <5% n -hexane Skin Irrit. 2; H315 01 -2119484651 -34 STOT SE 3; H36 Asp. Tox. 1; H304 Aquatic Chronic 2; H41 Hydrocarbons, C7, n -alkanes, 64742 -49 -0 Flam Liq. . 2; H225 >= 2.5 - < 10 isoalkanes, cyclics Skin Irrit. 2; H315 01 -211947515 -33 STOT SE 3; H36 Asp. Tox. 1; H304 Aquatic Chronic 2; H41 Hydrocarbons, C9 -C10, n Not Assigned Flam Liq. . 3; H226 >= 1 - < 2.5 alkanes, isoalkanes, cyclics, <2% STOT SE 3; H36 arom atics 01 -2119471843 -32 Asp. Tox. 1; H304 Aquatic Chronic 3; H412 EUH06 Cyclohexane 110 -82 -7 Flam Liq. . 2; H225 >= 1 - < 2.5 203 -806 Skin Irrit. 2; H315 601 -017 -00 -1 STOT SE 3; H36 01 -2119463273 -41 Asp. Tox. 1; H304 Aquatic Acute 1; H40 Aquatic Chronic 1; H410 M-Factor (Acute aquatic toxicity n-Hexane 110 -54 -3 Flam Liq. . 2; H225 >= 1 - < 2.5 203 -77 Skin Irrit. 2; H315 601 -037 -00 -0 Repr. 2; H361f 01 -2119480412 -44 STOT SE 3; H36 STOT RE 1; H372 (Nervous system Asp. Tox. 1; H304 Aquatic Chronic 2; H41 Propan -2-ol 67 -63 -0 Flam Liq. . 2; H225 >= 1 - < 10 200 -61 Eye Irit. 2; H319 603 -17 -00 -0 STOT SE 3; H36 01 -2119457558 -25 (R) -p-m entha -1,8 -diene 5989 -27 -5 Flam Liq. . 3; H226 0.1 - < 0.25 227 -813 Skin Irrit. 2; H315 601 -096 -00 -2 Skin Sens. 1B ; H317 01 -2119529223 -47 Asp. Tox. 1; H304 Aquatic Acute 1; H40 Aquatic Chronic 3; H412 M-Factor (Acute aquatic toxicity For explanation of abbreviations see SECTION 4: First aid m easures 4.1 Description of first aid m easures General advice In the case of accident or if you fel unwell, sek m edical ad- vice im m ediately. hen sym ptom s persist in all or cases of doubt sek m edical advice. Protection of first -aiders First Aid responders should pay attention to self -protection, and use the recom m ended personal protective equipm ent when the potential for exposure exists (se section 8). If inhaled If inhaled, rem ove to fresh air. Get m edical attention if sym ptom s occur. In case of skin contact In case of contact, im m ediately flush skin with plenty water for at least 15 m inutes while rem oving contam inated clothing and shoes. Get m edical attention. ash clothing before reuse. Thoroughly clean shoes before reuse. In case of eye contact Flush eyes with water as a precaution. Get m edical attention if irritation develops and persists. If swallowed If swallowed, DO NOT induce vom iting. Get m edical attention if sym ptom s occur. Rinse m outh thoroughly with water. ost im portant sym ptom s and efects, both acute and delayed Risks Causes skin irritation. ay produce an allergic reaction. 4.3 Indication of any im ediate m edical atention and special treatm ent neded Treatm ent Treat sym ptom atically and supportively. Firefighting m easures 5.1 Extinguishing m edia Suitable extinguishing m edia ater spray Alcohol -resistant foam Carbon dioxide (CO2) Dry chem ical Unsuitable extinguishing High volum e water jet edia 5.2 Special arising from the substance or m ixture Specific during fire- Flash back possible over considerable distance. fighting Vapours m ay form explosive ixtures with air. Exposure to com bustion products m ay be a health. If the tem perature rises there is danger of vessels bursting due to the high vapor pressure. Haza rdous com bustion prod- Carbon oxides ucts Silicon oxides 5.3 Advice for firefighters Special protective equipm ent In the event of fire, wear self -contained breathing apparatus. for firefighters Use personal protective equipm ent. Specific extinguishing m eth- Use extinguishing m easures are that appropriate to local cir- ods cum stances and the surounding

Environmental hazards

Use water spray to col unopened containers. Rem ove undam aged containers from fire area if it is safe to do so. Evacua te area. Acidental release m easures 6.1 Personal Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containm ent or oil barriers). Retain and dispose of contam inated wash water. Local authorities should be advised if significant spillages cannot be contained. ethods and m aterial for containm ent and cleaning up ethods for cleaning up Non -sparking tools should be used. Soak up with inert absorbent m aterial. Suppress (knock down) gases/vapours/m ists with a water spray jet. For large spills, provide d yking or other appropriate Do not spray on an open flam ignition e or other source. Hygiene m easures If exposure to chem ical is likely during typical use, provide eye flushing system s and safety showers close to the working place. hen using do not eat, drink or sm oke. ash contam i- nated clothing before re -use. 7.2 Conditions for safe

Precautionary statements

protective equipm ent and em ergency procedures Personal Rem ove all sources of ignition. Use personal protective equipm ent. Follow safe handling advice (se section 7) and personal pro- tective equipm ent recom endations m (se 6.2 Environm ental Environm ental Avoid release to the

Further information

Indicative OELV - 8 hrs 200 pm IE OEL (TW A) 700 m g/m 3 n-Hexane 110 -54 -3 TW A 20 ppm 2006/15/EC 72 m g/m 3 Indicative OELV - 8 hrs 20 ppm IE OEL (TW A) 72 m g/m 3 Substances which have the capacity to penetrate intact skin when they com e in contact with it, and be absorbed into the body Propan -2-ol 67 -63 -0 OELV - 8 hrs 200 pm IE OEL (TW A) Substances which have the capacity to penetrate intact skin when they com e in contact with it, and be absorbed into the body OELV - 15 m in 400 pm IE OEL (STEL) Substances which have the capacity to penetrate intact skin when they com e in contact with it, and be absorbed into the body Derived No Effect Level (DNEL ) according to Regulation (EC) No.

Potential health effects

Value Propan -2-ol W orkers Inhalation Long -term system ic 500 m g/m 3 effects W orkers Skin contact Long -term system ic 888 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 89 m g/m 3 effects Consum ers Skin contact Long -term system ic 319 m g/kg effects bw/day Consum ers Ingestion Long -term system ic 26 m g/kg effects bw/day (R) -p-m entha -1,8 - W orkers Inhalation Long -term system ic 6.7 m g/m 3 diene effects W orkers Skin contact Acute local effects 9.5 m g/kg bw/day Consum ers Inhalation Long -term system ic 16.6 m g/m 3 effects Consum ers Skin contact Acute local effects 4.8 m g/kg bw/day Consum ers Ingestion Long -term system ic 4.8 m g/kg effects bw/day Hydrocarbons, C6, W orkers Inhalation Long -term system ic 5306 m g/m 3 isoalkanes, <5% n - effects hexane W orkers Skin contact Long -term system ic 13964 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 131 m g/m 3 effects Consum ers Skin contact Long -term system ic 1377 m g/kg effects bw/day Consum ers Ingestion Long -term system ic 1301 m g/kg effects bw/day Hydrocarbons, C7, n - W orkers Inhalation Long -term system ic 2085 m g/m 3 alkanes, isoalkanes, effects cyclics W orkers Skin contact Long -term system ic 300 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 47 m g/m 3 effects Consum ers Skin contact Long -term system ic 149 m g/kg effects bw/day Consum ers Ingestion Long -term system ic 149 m g/kg effects bw/day n-Hexane W orkers Skin contact Long -term system ic 11 m g/kg effects bw/day W orkers Inhalation Long -term system ic 75 m g/m 3 effects Consum ers Skin contact Long -term system ic 5.3 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 16 m g/m 3 effects Consum ers Ingestion Long -term system ic 4 m g/kg effects bw/day Cyclohexane W orkers Inhalation Long -term system ic 700 m g/m 3 effects W orkers Inhalation Acute system ic ef- 140 m g/m 3 fects W orkers Inhalation Long -term local ef- 700 m g/m 3 fects W orkers Inhalation Acute local effects 140 m g/m 3 W orkers Skin contact Long -term system ic 2016 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 206 m g/m 3 effects Consum ers Inhalation Acute system ic ef- 412 m g/m 3 fects Consum ers Inhalation Long -term local ef- 206 m g/m 3 fects Consum ers Inhalation Acute local effects 412 m g/m 3 Consum ers Skin contact Long -term system ic 1186 m g/kg effects bw/day Consum ers Ingestion Long -term system ic 59.4 m g/kg effects bw/day Hydrocarbons, C6 - W orkers Inhalation Long -term system ic 2035 m g/m 3 C7, n -alkanes, isoal- effects kanes, cyclics, <5% n-hexane W orkers Skin contact Long -term system ic 773 m g/kg effects bw/day Consum ers Inhalation Long -term system ic 608 m g/m 3 effects Consum ers Skin contact Long -term system ic 699 m g/kg effects bw/day Consum ers Ingestion Long -term system ic 699 m g/kg effects bw/day Predicted No Effect Concentration (PNEC ) acording to Regulation (EC) No.