Sulfur 90%

SECTION 2: Hazards identification

OSHA HCS 2012 EMERGENCY OVERVIEW: A yellowish to pale green tablet shaped solid (pastille). Dusts, if generated, may irritate the nose and throat. Concentrated dusts may produce a dust explosion if confined and a source of ignition is present. Confined space and head space in bulk storage bins may contain lethal levels of hydrogen sulfide gas.

Potential health effects

Eyes: Exposure to dust may cause mechanical irritation of the eyes. Skin: Exposure to dust may cause skin irritation. Symptoms include reddening, itching and inflammation. Inhalation: Exposure to dust may cause irritation of the respiratory tract’s mucous membranes. May cause coughing, sore throat, and shortness of breath. Confined space and head space in bulk storage bins may contain lethal levels of hydrogen sulfide gas. Ingestion: Large doses can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Preexisting Conditions: Exposure to dust may aggravate existing respiratory and skin conditions.

Potential chronic health

This product contains trace amounts of crystalline silica, a fraction of which is in the respirable form and is known to cause lung cancer through repeated inhalation. The small quantities of crystalline silica (quartz) found in this material are, under normal conditions, naturally coated with an un-removable layer of amorphous silica and/or clay. Carcinogenicity NTP: Not listed IARC: Not listed

Signal word

DANGER

Hazard statements

Flammable solid. May cause respiratory irritation. May cause damage to lungs through prolonged or repeated inhalation. Percent of product with unknown toxicity: 0% Continued on next page

Prevention

Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Ground and/or bond container and receiving equipment. Use explosion-proof electrical, ventilating, and lighting equipment. Wear protective gloves, eye protection and face protection. Do not breathe dust. Use only outdoors in a well-ventilated area.

Response

If inhaled Remove person to fresh air and keep comfortable for breathing. Call a poison control center (1-877- 424-7452) or doctor for treatment advice if you feel unwell. In case of fire Use foam, carbon dioxide, sand or earth, water spray or fog for extinction. Get medical attention if you feel unwell.

Storage

Store in a secured and well-ventilated place. Keep container tightly closed.

Disposal

Dispose of contents/container in accordance with Federal, state and local regulations.