TIN ALLOY

SECTION 2: Hazards identification

WARNING! Exposure to dust or fumes can cause eye, skin and respiratory tract irritation. Exposure to dust or fumes can cause respiratory system damage. May cause an allergic skin reaction. Contains a material which may cause blood, kidney, reproductive and neurological effects. Contains materials which may cause cancer. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing . Wash thoroughly after handling.

Hazard statements

for dust or fume) Degree of hazard (0 = low, 4 = extreme) Hazardous Materials Identification Health: 2* Flammability: 0

Physical hazards

System (HMIS) None National Fire Protection Association Mixture. Not rated. (NFPA) HUMAN THRESHOLD RESPONSE DATA Odor Threshold: Unknown Irritation Threshold: Unknown Immediately Dangerous to Life or Health The IDLH for this product is not known. The IDLH for arsenic is 5 (IDLH) Value(s): mg/m3. The IDLH for nickel is 10 mg/m3. The IDLH for copper and lead is 100 mg/m3.

Potential health effects

ACCUTE EFFCTS Eye: Dust or fume can cause irritation consisting of redness, swelling, and pain. May cause conjunctivitis with repeated exposures. Skin: Material not expected to be absorbed through the skin. Contact with dust may cause mild irritation consisting of redness and/or swelling. Inhalation: Harmful if inhaled. Inhalation of high concentrations of powder, dus, or fume may cause respiratory and nasal irritation, coughing, and difficulty breathing. Inhalation of high concentrations of metallic copper dusts or fumes may cause nasal irritation and/or nausea, vomiting and stomach pain. The metal fume may also produce influenza-like symptoms, known as metal fume fever. Symptoms of this reaction may include metallic taste, runny nose, nausea, fever and chills. These effects ususally disappear within 24 hours. Ingestion: Ingestion of large amounts of dust may cause neausea, vomiting, constipation, cramps, and or stomach pain.

Potential chronic health

Prolonged or repeated inhalation of dust or fume may cause more severe irritation and possibly lung damage. Repeated exposure may cause an allergic skin reaction consisting of itching, redness, swelling, and rash or urticaria(hives) in sensitized individuals. Prolonged or repeated inhalation of dust or fume may cause an allergic type of asthma reaction characterized by wheezing, coughing, and extreme breathing difficulty in sensitized individuals. Chronic exposure to lead can cause kidney damage, anemia, reproductive effects, developmental effects and permanent nervous system damage in humans including changes in cognitive function. Epidemiological studies in humans have shown an association between lung and nasal cancers and prolonged occupational exposures to high concentrations of nickel. Epidemiological studies in humans have shown an association between increased incidences of lung and skin cancer and prolonged exposures to high concentrations of arsenic. Arsenic is classified as a known human carcinogen.

Medical Conditions Generally Aggravated by Exposure

Exposure to dust or fume may aggravate an existing dermatitis, asthma, emphysema, or other respiratory disease. POTENTIAL ENVIORNMENATAL EFFECTS: None known. Product has not been tested for environmental properties.