Acute Tox. 4, H332

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Carc. 2, H351 Skin Sens. 1, H317 STOT SE 3, H335

2.1 Classification of the substance or mixture

STOT RE 2, H373 (respiratory system) (as inhalation)

Hazard statements

2,2'-methylenediphenyl diisocyanate Eye Irrit. 2 H319-Causes serious eye irritation. Registration number (REACH) Index 01-2119927323-43-XXXX 615-005-00-9 STOT SE 3 H335-May cause respiratory irritation. EINECS, ELINCS, NLP 219-799-4 Skin Irrit. 2 H315-Causes skin irritation. CAS 2536-05-2 Resp. Sens. 1 H334-May cause allergy or asthma

Contains

0,1-<1

CLP CLASSIFICATION

symptoms or breathing difficulties if inhaled. Acute Tox. 4, H332 (CLP) Skin Irrit. 2, H315 Skin Sens. 1 H317-May cause an allergic skin reaction. Eye Irrit. 2, H319 Carc. 2 H351-Suspected of causing cancer. Resp. Sens. 1, H334 STOT RE 2 H373-May cause damage to organs through Skin Sens. 1, H317 prolonged or repeated exposure by Carc. 2, H351 STOT SE 3, H335 inhalation (respiratory system). STOT RE 2, H373 (respiratory system) (as inhalation) 2.2 Label elements Dibutyltin dilaurate Labeling according to Regulation (EC) 1272/2008 (CLP) Registration number (REACH) 01-2119496068-27-XXXX Index 050-030-00-3 EINECS, ELINCS, NLP 201-039-8 CAS 77-58-7 content % 0,1-<0,25 Classification according to Regulation (EC) 1272/2008 Muta. 2, H341 (CLP) Repr. 1B, H360FD Skin Corr. 1C, H314 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) Skin Sens. 1, H317 Danger STOT SE 1, H370 STOT RE 1, H372 (immune system) Eye Dam. 1, H318 H319-Causes serious eye irritation. H335-May cause respiratory irritation. H315-Causes skin Isophthaloyl dichloride irritation. H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317- Registration number (REACH) 01-2119493993-19-XXXX May cause an allergic skin reaction. H351-Suspected of causing cancer. H373-May cause Index --- damage to organs through prolonged or repeated exposure by inhalation (respiratory system). EINECS, ELINCS, NLP 202-774-7 CAS P201-Obtain special instructions before use. P260-Do not breathe vapours or spray. P280-Wear 99-63-8 content % <0,25 protective gloves / protective clothing / eye protection / face protection. P284-Wear respiratory Classification according to Regulation (EC) 1272/2008 Acute Tox. 4, H312 protection. (CLP) Acute Tox. 3, H331 P302+P352-IF ON SKIN Wash with plenty of water / soap. P304+P340-IF INHALED Remove Skin Corr. 1A, H314 person to fresh air and keep comfortable for breathing. P305+P351+P338-IF IN EYES: Rinse Eye Dam. 1, H318 cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313-IF exposed or concerned: Get medical advice / attention. For the text of the H-phrases and classification codes (GHS/CLP), see Section 16. The substances named in this section are given with their actual, appropriate classification! EUH204-Contains isocyanates. May produce an allergic reaction. For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may be given here for the named classification have been taken into account. Dibutyltin dilaurate SECTION 4: First aid measures Diphenylmethanediisocyanate, isomeres and homologues 4,4'-methylenediphenyl diisocyanate o-(p-isocyanatobenzyl)phenyl isocyanate 4.1 Description of first aid measures 2,2'-methylenediphenyl diisocyanate First-aiders should ensure they are protected! 2.3 Other hazards Never pour anything into the mouth of an unconscious person! Wash hands before breaks and at end of work. Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Keep away from food, drink and animal feedingstuffs. Revision date / version: 25.04.2019 / 0014 Remove contaminated clothing and protective equipment before entering areas in which food is consumed. Replacing version dated / version: 08.01.2019 / 0013