Mavrik Perimeter

Hazard statements (CLP)

H319, H331, H373

Code

Statements

H319

Causes serious eye irritation

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation Category 2A Acute toxicity (inhalation) Category 3 Specific target organ toxicity (repeated exposure) Causes serious eye irritation Toxic if inhaled May cause damage to organs through prolonged or repeated exposure Category 2

2.2 Label elements

GHS-US labeling

Hazard pictograms

GHS06 GHS07 GHS08

Signal word

Danger

Hazard statements

Causes serious eye irritation Toxic if inhaled May cause damage to organs (skin) through prolonged or repeated exposure

Precautionary statements

Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands, forearms and face thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Call a poison center or doctor Get medical advice/attention if you feel unwell. If eye irritation persists: Get medical advice/attention. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to in accordance with local/regional/national/international regulations 02/09/2018 EN (English US) Page 1

Other hazards which do not result in classification

This product is toxic to fish and aquatic organisms. Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous.

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS-US classification Serious eye damage/eye irritation Category 2A Causes serious eye irritation Acute toxicity (inhalation) Category 3 Toxic if inhaled Specific target organ toxicity (repeated exposure) May cause damage to organs through prolonged or repeated exposure Category 2 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : GHS06 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Causes serious eye irritation Toxic if inhaled May cause damage to organs (skin) through prolonged or repeated exposure Precautionary statements (GHS-US) : Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands, forearms and face thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Call a poison center or doctor Get medical advice/attention if you feel unwell. If eye irritation persists: Get medical advice/attention. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to in accordance with local/regional/national/international regulations 02/09/2018 EN (English US) Page 1 2.3. Other hazards which do not result in classification Other hazards not contributing to the : This product is toxic to fish and aquatic organisms. Under United States Regulations (29 CFR classification 1910.1200 - Hazard Communication Standard), this product is considered hazardous. 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Tau-fluvalinate (CAS-No.) 102851-06-9 22.3 Sodium alkylnaphthalenesulfonate, formaldehyde condensate (CAS-No.) 36290-04-7 2.2 Ethylene glycol (CAS-No.) 107-21-1 8 Other ingredients (CAS-No.) N/A Balance SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Get medical advice/attention if you feel unwell. First-aid measures after inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a doctor. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting unless directed to do so by medical personnel. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after skin contact : May cause damage to skin through prolonged or repeated exposure. Symptoms/effects after eye contact : Causes serious eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Avoid heavy hose streams. 5.2. Specific hazards arising from the chemical Reactivity : The product is non-reactive under normal conditions of use, storage and transport. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Do not allow fire fighting water to escape into waterways or sewers. Do not use direct stream of water. A direct stream of water may spread fire. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Move containers away from the fire area if this can be done without risk. Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection. 02/09/2018 EN (English US) 2/7 Emergency procedures : As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Do NOT wash away into sewer. Avoid release to the environment. Evacuate unnecessary personnel. Stop leak if safe to do so. Ventilate area. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Do not breathe fumes. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Wear personal protective equipment. Read label before use. Wash hands immediately after handling the product. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well- ventilated place. Keep cool. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethylene glycol (107-21-1) ACGIH ACGIH TWA (ppm) 25 ppm (Vapor fraction) ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (Inhalable fraction, Aerosol only) ACGIH ACGIH STEL (ppm) 50 ppm (Vapor fraction) ACGIH Remark (ACGIH) Kidney dam; URT & eye irr 8.2. Appropriate engineering controls Appropriate engineering controls : Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Hand protection: Wear chemically resistant protective gloves. Eye protection: Chemical goggles or safety glasses Skin and body protection: It is recommended for handlers to wear appropriate clothing to prevent skin contact including long sleeves, long pants, socks and shoes. Respiratory protection: Wear respiratory protection. In case of insufficient ventilation, use NIOSH approved respiratory protection. In case of insufficient ventilation, use NIOSH approved respiratory protection. Mixers loaders, applicators and other handlers: wear a NIOSH approved respirator with a dust/mist filter with MSHA/NIOSH approval number prefix TC-21C or R, P or HE filter. 02/09/2018 EN (English US) 3/7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Milky white liquid Color : Milky white Odor : Strong oil-like Odor threshold : No data available pH : 4.88 (25 °C)(77 °F) Melting point : Not applicable Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Not applicable Vapor pressure : No data available Relative vapor density at 20 °C : No data available Relative density : 1.09 Solubility : No data available Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 400 cP (20 °C)(68 °F) Explosion limits : No data available Explosive properties : Not explosive Oxidizing properties : Not applicable 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Excessive heat > 110° F. Direct sunlight. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Thermal decomposition may produce toxic fumes/vapors which may include hydrogen cyanide, hydrogen chloride and hydrogen fluoride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Mavrik Perimeter LD50 oral rat 5150 mg/kg LD50 dermal rabbit > 2100 mg/kg LC50 inhalation rat (mg/l) 0.52 - 1.65 mg/l/4h pH 4.88 (25 °C)(77 °F) 02/09/2018 EN (English US) 4/7 GHS-US Properties Classification Acute toxicity Inhalation: Toxic if inhaled. Skin corrosion/irritation Not classified Serious eye damage/irritation Causes serious eye irritation. Respiratory or skin sensitization Not classified Germ cells mutagen Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicant Not classified (single exposure) Specific target organ toxicant May cause damage to organs through prolonged or repeated exposure. (repeated exposure) Aspiration hazard Not classified Potential health effects Inhalation Acute : Toxic if inhaled. Skin Acute : Under normal conditions of use, no health effects are expected. Chronic : Repeated and prolonged exposure to tau-fluvalinate may cause skin lesions. Eye Acute : Causes serious eye irritation. Ingestion Acute : Under normal conditions of use, no health effects are expected. Mutagenicity : Tau-fluvalinate has been tested and found negative for mutagenicity potential. Carcinogenicity : Tau-fluvalinate is not listed as a carcinogen by OSHA, IARC, or NTP, No other component present at 0.1% or greater are listed by IARC, OSHA or NTP. Reproductive Effects : Tau-fluvalinate has been tested and is not a reproductive toxin. SECTION 12: Ecological information 12.1. Toxicity Tau-fluvalinate (102851-06-9) LC50 Acute fish 1 0.00091 mg/l (Exposure time: 96h - Rainbow trout) LC50 Acute fish 2 0.0012 mg/l (Exposure time: 96h - Blue gill) LC50 Acute fish 3 0.0015 mg/l (Exposure time: 96h - Sheepshead minnow) LC50 Acute crustacea 1 0.0000079 mg/l (Exposure time: 96h - Mysid shrimp) EC50 Daphnia 1 0.00094 mg/l (Exposure time: 48h - Daphnia magna) NOEC Chronic crustacea 1 0.0003 mg/l (Daphnia magna) NOEC Chronic crustacea 2 0.0000003 mg/l (Mysid shrimp) 12.2. Persistence and degradability Tau-fluvalinate (102851-06-9) Persistence and degradability Tau-fluvalinate is expected to degrade rapidly under aerobic conditions but be persistent under anaerobic conditions. 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil Tau-fluvalinate (102851-06-9) Mobility in soil Tau-fluvalinate is expected to be highly immobile. Soil half life: 14.9 day 12.5. Other adverse effects Mavrik Perimeter Ecological Fate This product is toxic to fish and aquatic organisms. 02/09/2018 EN (English US) 5/7 SECTION 13: Disposal considerations 13.1. Disposal methods Product/Packaging disposal recommendations : Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: Transport information UN number Proper Shipping Name Transport hazard Packing group Environmental hazards class(es) DOT Not regulated Ethylene glycol RQ = 5,000 lb Packaging 5 L or greater: IMDG UN3082 Environmentally Hazardous substance, 9 III Marine pollutant Liquid, N.O.S. (Tau-fluvalinate) Pesticide, liquid, toxic, n.o.s. (Tau- IATA Acute aquatic toxicity UN2902 Fluvalinate) 6.1 III Other Information : DOT: The calculated 1-hour acute toxicity for inhalation LC50 = 2.08 mg/L, however it has been determined a mist or aerosol cannot be formed if there is leakage during transport, therefore the 6.1 classification does not apply SECTION 15: Regulatory information 15.1. US Federal regulations Sodium alkylnaphthalenesulfonate, formaldehyde condensate (36290-04-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)). ethylene glycol (107-21-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory