Extinguish Professional Fire Ant Bait

SECTION 2: Hazards identification

(29 CFR 1910.1200) 21. Classification of the substance or mixture GHS US classification Combustible Dust May form combustible dust concentrations in air 22

2.2 Label elements

GHS US labeling

Signal word

Waming

Hazard statements

May form combustible dust concentrations in air 23.

Other hazards which do not result in classification

Other hazards which do not result in

2.1 Classification of the substance or mixture

GHS US classification Combustible Dust May form combustible dust concentrations in air 22.

Ingredient(s) with unknown acute toxicity

Not applicable 31. Substances Not applicable 32. Mixtures Name

Product definition

% (s)-Methoprene Technical (CAS-No) 65733-16-6 05 Defatted Grits (CAS-No.) 68525-86-0 85-90 Non-hazardous and/or does not meet criteria for classification (CAS-No.) VA Balance 41. Description of first aid measures First-aid measures after inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctoriphysician if you feel unwell First-aid measures after skin contact IF ON SKIN Wash with plenty of soap and water. If skin irftation or rash occurs Get medical advice/attention 05/26/2022 EN (English US) Page 1 First-aid measures after eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irfitation persists: Get medical advice and attention First-aid measures after ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth Do NOT induce vomiting unless directed to do so by medical personnel 42. Mostimportant symptoms and effects (acute and delayed) 43. Immediate medical attention and special treatment, if necessary Treat symptomatically. 51. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Use extinguishing agent suitable for surrounding fire. Unsuitable extinguishing media Avoid heavy hose streams. 52. Specific hazards arising from the chemical Explosion hazard This material is friable and can create small dust particles during any handling, processing, and transfer operations. This material can form explosive dust/air suspensions that are ignitable under some conditions. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard 53. Special protective equipment and precautions for fire-fighters Firefighting instructions Combustible dust - use low-pressure medium fog streams to avoid dust clouds. Ventilate closed spaces before entering. Eliminate ignition sources. Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing SECTION 6: Accidental release measures 61. Personal precautions, protective equipment and emergency procedures. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. No flames, no sparks. Eliminate all sources of ignition. Contain spill and monitor for excessive dust accumulation. Tum off electric power to area. 6.1.2. For emergency responders Protective equipment Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection Emergency procedures Contain spill and monitor for excessive dust accumulation. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Turn off electric power to area. As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions. Evacuate area. 6.2. Environmental precautions Avoid release to the environment 63. Methods and material for containment and cleaning up Methods for cleaning up Use appropriate PPE. Sweep or scoop spills, dispose of any unusable material in approved landfill. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Non- sparking tools should be used SECTION 7: Handling and storage 74. Precautions for safe handling Precautions for safe handiing Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Avoid dust formation. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration Hygiene measures Do ot eat, drink or smoke when using this product. Always wash hands after handling the product 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep cool. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Incompatible materials Heat, sparks, open flame. 05/26/2022 EN (English US) 2% SECTION 8: Exposure controls/personal protectio 81. Control parameters No additional information available 82. Appropriate engineering controls Adequate ventilation systems as needed to control concentrations of airbome contaminants below applicable threshold limit values. It is recommended that dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion suppression system or an oxygen-deficient

Environmental hazards

Environmental exposure controls Avoid release to the environment. 83. Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear long-sleeved shirt, long pants, socks and shoes Respiratory protection: In case of insufficient ventilation, use NIOSH approved respiratory protection SECTION 9: Physical and chemical properties 91. Information on basic physical and chemical properties Physical state Solid Appearance Pale yellow granule Color Pale yellow Odor Earthy, com-like Odor threshold No data available pH No data available Metting point No data available Freezing point Not applicable Boiling point No data available Flash point Not applicable Relative evaporation rate (butyl acetate=1) No data available Flammability (solid, gas) Non-flammable Vapor pressure No data available Relative vapor density at 20 °C No data available Relative density Not applicable Bulk density 19 Ib(syftt Solubility No data available Partition coefficient n-octanol/water (Log Pow) ~ No data available Auto-ignition temperature Not applicable Decomposition temperature No data available Viscosity, kinematic Not applicable Viscosity, dynamic Not applicable 05/26/2022 EN (English US) 36 Explosion limits Not applicable Explosive properties Combustible Dust Oxidizing properties Not applicable

Further information

No additional information available SECTION 10: Stability and reactivit 101. Reactivity No additional information available 102. Chemical stability Stable under nomal conditions 10.3. Possibility of hazardous reactions Stable under nomal conditions of use. Hazardous polymerization will not occur. May form combustible dust concentrations in the air 104. Conditions to avoid Avoid dust formation. Heat. No flames, no sparks. Eliminate all sources of ignition 105. Incompatible materials Heat. Strong oxidizing agents. 106. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information A Information on toxicological effects (s)-Methoprene Technical ( 65733-16-6) LD50 oral rat > 34000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 Inhalation - Rat 5.19 mg/li4h GHS-US Properties Classification Acute toxicity (oral) Not classified Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified Skin corrosioniiritation Not classified Serious eye damagefirritation Not classified Respiratory or skin sensitization | Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity Not classified (single exposure) Specific target organ toxicity Not classified (repeated exposure) Aspiration hazard Not classified Potential health effects Inhalation Acute Exposure to dust may cause respiratory irritation skin Acute Exposure to dust may cause mechanical irritation Eye Acute Exposure to dust may cause mechanical irritation Ingestion Acute Under normal conditions of use, no health effects are expected 05/26/2022 EN (English US) /6 Mutagenicity (s)-Methoprene has been tested and found negative for mutagenicity potential Carcinogenicity (s)-Methoprene is not classified as a carcinogen by NTP, IARC or OSHA Reproductive Effects (s)-Methoprene is not a reproductive toxin and does not cause birth defects. SECTION 12: Ecological information 121, To (s)-Methoprene Technical (65733-16-6) LC50 Acute fish 1 0.76 mg/l (Exposure ime: 96hr Oncorhynchus mykiss) LC50 Acute fish 2 > 0.37 mg/l (Exposure time: 96h - Blue gill) LC50 Acute crustacea 1 0.11 mg/l (Exposure time: 96h - Mysid shrimp) LC50 Acute crustacea 2 0.36 mg/l (Exposure time: 48h Daphnia) NOEC Chronic fish 1 0.048 mg/l (Fathead minnow) NOEC Chronic crustacea 1 0.014 mg/I (Mysid shrimp) 122.