1-10

Hazard statements (CLP)

H225, H319, H335, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP In certain cases, the symptoms of poisoning may only appear after an extended period / after several hours. If solvent components are inhaled above the air threshold-value: Irritation of the respiratory tract

2.1 Classification of the substance or mixture

Coughing

CLP CLASSIFICATION

Headaches Dizziness

Hazard statements

Effects/damages the central nervous system Flam. Liq. 2 H225-Highly flammable liquid and vapour. Coordination disorders Eye Irrit. 2 H319-Causes serious eye irritation. Unconsciousness STOT SE 3 H335-May cause respiratory irritation. 4.3 Indication of any immediate medical attention and special treatment needed Carc. n.c. 2 H351-Suspected of causing cancer. SECTION 5: Firefighting measures

2.2 Label elements

Labeling according to Regulation (EC) 1272/2008 (CLP) 5.1 Extinguishing media Suitable extinguishing media CO2 Extinction powder Water jet spray Alcohol resistant foam Unsuitable extinguishing media High volume water jet 5.2 Special hazards arising from the substance or mixture In case of fire the following can develop: Danger Oxides of carbon Toxic gases Explosive vapour/air mixture Dangerous vapours heavier than air. H225-Highly flammable liquid and vapour. H319-Causes serious eye irritation. H335-May cause In case of spreading near the ground, flashback to distance sources of ignition is possible. respiratory irritation. H351-Suspected of causing cancer. 5.3 Advice for firefighters P201-Obtain special instructions before use. P210-Keep away from heat, hot surfaces, sparks, In case of fire and/or explosion do not breathe fumes. open flames and other ignition sources. No smoking. P261-Avoid breathing vapours or spray. P280-Wear protective gloves and eye protection/face protection. Protective respirator with independent air supply. According to size of fire P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse Full protection, if necessary skin with water/shower. P305+P351+P338-IF IN EYES: Rinse cautiously with water for several Cool container at risk with water. minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313-IF Dispose of contaminated extinction water according to official regulations. exposed or concerned: Get medical advice/attention. P403+P233-Store in a well-ventilated place. Keep container tightly closed. SECTION 6: Accidental release measures EUH019-May form explosive peroxides. 6.1 Personal precautions, protective equipment and emergency procedures Keep non-essential personnel away. Tetrahydrofuran Remove possible causes of ignition - do not smoke. Ensure sufficient supply of air.

2.3 Other hazards

Avoid inhalation, and contact with eyes or skin. The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not If applicable, caution - risk of slipping included under XIII of the regulation (EC) 1907/2006. 6.2 Environmental precautions The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included If leakage occurs, dam up. under XIII of the regulation (EC) 1907/2006. Resolve leaks if this possible without risk. Prevent surface and ground-water infiltration, as well as ground penetration. Prevent from entering drainage system. If accidental entry into drainage system occurs, inform responsible authorities.