W.R.Grace & Co.-Conn

W.R.Grace & Co

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

105-76-0

Name of the chemical

DBM, Dibutyl-maleate

Concentration

N/A

Listed in

General Information

Product name

W.R.Grace & Co.-Conn

Emergency telephone

In USA: (617) 876-1400

Icons in SDS

Company Information

company name

W.R.Grace & Co

Section 2

SECTION 2: Hazards identification

OSHA EMERGENCY OVERVIEW:

Appearance/Odor

dark brown liquid with a slightly musty odor REACTIVE: Product will polymerize when exposed to water.

Potential health effects

EYES: Causes irritation with symptoms of reddening, tearing, stinging, and swelling. May cause temporary corneal injury. Vapor or aerosol may cause irritation with symptoms of burning and tearing. Product may polymerize in eye. CHRONIC EYE: Prolonged vapor contact may cause conjunctivitis SKIN: Causes irritation with symptoms of reddening, itching, and swelling. Persons previously sensitized can experience allergic skin reaction with symptoms of reddening, itching, swelling, and rash. Contact with skin can cause product to polymerize. Cured material is difficult to remove. Contact with MDI can cause discoloration. CHRONIC SKIN: Prolonged contact can cause reddening, swelling, rash, and, in some cases, skin sensitization. Animal tests on MDI indicate skin contact alone may lead to an allergic respiratory reaction. INGESTION: May cause irritation; Symptoms may include abdominal pain, nausea, vomiting, and diarrhea. Carcinogenicity: No Carcinogenic substances as defined by IARC, NTP and/or OSHA (Continued) INHALATION: Diisocyanate vapors or mist can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). CHRONIC INHALATION As a result of previous repeated overexposures or a single large dose, certain individuals may develop sensitization to diisocyanates (asthma or asthma-like symptoms).

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