Denatured Alcohol

W. M. Barr

Revision date : 2013-05-12

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GHS02 GHS06 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

64-17-5

Name of the chemical

Ethanol

Concentration

40.0-50.0%

EC/CAS

67-56-1

Name of the chemical

Methanol

Concentration

50.0-55.0%

EC/CAS

108-10-1

Name of the chemical

4-methylpentan-2-one; isobutyl methyl ketone (MIBK)

Concentration

1.0-4.0%

EC/CAS

141-78-6

Name of the chemical

acetic acid, ethyl ester

Concentration

0.5-1.5%

General Information

Revision date

2013-05-12

Product name

Denatured Alcohol

1.2.1 Relevant identified uses

Cleans glass and is used as a fuel for marine stoves Synonyms CSL26, DSL26, GSL26, QSL26, QSL26W

Icons in SDS

GHS02 GHS06 GHS08

Company Information

company name

W. M. Barr

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H301, H304, H311, H319, H331, H370, H402, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Placard Key word

Hazard statements

Flammable Liquids, Category 2 Flame Danger Highly flammable liquid and vapor Acute Toxicity: Inhalation, Category 3 Skull and Danger Toxic if inhaled crossbones Acute Toxicity: Oral, Category 3 Skull and Danger Toxic if swallowed crossbones Acute Toxicity: Skin, Category 3 Skull and Danger Toxic in contact with skin crossbones Serious Eye Damage/Eye Irritation, Category Exclamation Warning Causes serious eye irritation 2A point Target Organ Systemic Toxicity (single H225: Highly flammable liquid and vapor. H331: Toxic if inhaled. H301: Toxic if swallowed. H311: Toxic in contact with skin. H319: Causes serious eye irritation. H370: Causes damage to organs. H304: May be fatal if swallowed and enters airways. H402: Harmful to aquatic life. H412: Harmful to aquatic life with long lasting effects.

Health hazards

Danger Causes damage to organs. exposure), Category 1 Aspiration Toxicity, Category 1 Danger May be fatal if swallowed and enters airways. Aquatic Toxicity (Acute), Category 3 none Harmful to aquatic life Aquatic Toxicity (Chronic), Category 3 none Harmful to aquatic life with long lasting effects

Precautionary statements

P233: Keep container tightly closed. P210: Keep away from {heat/sparks/open flames/hot surfaces}. - No smoking. P280: Wear protective gloves/clothing and eye/face protection as specified by the manufacturer/supplier or the competent authority. P240: Ground/bond container and receiving equipment - if the explosive is electrostatically sensitive. P241: Use explosion-proof electrical/ventilating/lighting/... equipment ... other specified by the manufacturer/supplier or the competent authority. - if dust clouds can occur. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P361+364: Take off immediately all contaminated clothing and wash it before reuse. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P273: Avoid release to the environment - if this is not the intended use.

Response

P370+378: In case of fire, use ... for extinction ... appropriate media specified by the manufacturer/supplier or the competent authority - if water increases risk. P303+361+353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P311: Call a POISON CENTER or doctor/physician. P322: Specific measures (see ... on this label) ... reference to supplemental first aid instruction - if immediate measures such as specific cleansing agent is advised. P301+310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P330: Rinse mouth. P321: Specific treatment (see ... on this label) ... reference to supplemental first aid instruction - if immediate administration of antidote is required. P302+352 IF ON SKIN Wash with plenty of soap and water P312: Call a POISON CENTER or doctor/physician if you feel unwell. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313: If eye irritation persists, get medical advice/attention. P307+311 IF exposed Call a POISON CENTER or doctor/physician P331: Do NOT induce vomiting.

Storage

P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container to ... (in accordance with local/regional/national/international regulation). P405: Store locked up. P403+233: Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere.

Potential health effects

(Acute and Chronic) Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, watering of eyes, irritation of respiratory tract, irritation to the eyes, drowsiness, nausea, other central nervous system effects, spotted or blurry vision, dilation of pupils, and convulsions. Skin Contact Acute Exposure Effects: May cause irritation, drying of skin, redness, and dermatitis. May cause symptoms listed under inhalation. May be absorbed through damaged skin. Eye Contact Acute Exposure Effects: May cause irritation. Ingestion Acute Exposure Effects: Poison. Cannot be made non-poisonous. May be fatal or cause blindness. May produce fluid in the lungs and pulmonary edema. May cause dizziness, headache, nausea, drowsiness, loss of coordination, stupor, reddening of face and or neck, liver, kidney and heart damage, coma, and death. May produce symptoms listed under inhalation. Chronic Exposure Effects: May cause symptoms listed under inhalation, dizziness, fatigue, tremors, permanent central nervous system changes, blindness, pancreatic damage, and death. Target Organs: Liver, kidneys, pancreas, heart, lungs, brain, central nervous system, eyes

Medical Conditions Generally Aggravated by Exposure

Diseases of the liver, skin, lung, kidney, central nervous system, pancreas, and heart; asthma; inflammatory or fibrotic pulmonary disease; any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease, or anemias

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