Note: Ingredients listed on restricted chemical lists
EC/CAS
108-88-3
Name of the chemical
Toluene
Concentration
30.0-60.0%
EC/CAS
123-86-4
Name of the chemical
acetic acid, butyl ester
Concentration
10.0-30.0%
EC/CAS
1321-74-0
Name of the chemical
divinylbenzene
Concentration
1.0-5.0%
EC/CAS
100-42-5
Name of the chemical
Styrene ( Vinyl benzene )
Concentration
1.0-5.0%
EC/CAS
97-63-2
Name of the chemical
methacrylic acid, ethyl ester
Concentration
1.0-5.0%
EC/CAS
111-76-2
Name of the chemical
Ethylene glycol monobutyl ether (EGBE)
Concentration
1.0-5.0%
General Information
Revision date
2022-09-26
Product name
Bulldog Paint Adhesion Resin Reduced Formula
1.2.1 Relevant identified uses
Paint adhesion
Icons in SDS
Company Information
company name
W. M. Barr
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
OSHA Flammable Liquids, Category 2 Acute Toxicity: Inhalation, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Skin Sensitization, Category 1 Germ Cell Mutagenicity, Category 2 Carcinogenicity, Category 2 Toxic To Reproduction, Category 2 Specific Target Organ Toxicity (single exposure), Category 3 Specific Target Organ Toxicity (repeated exposure), Category 1
Signal word
Danger
Hazard statements
H225: Highly flammable liquid and vapor. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H341: Suspected of causing genetic defects. H351: Suspected of causing cancer, inhalation. H361: Suspected of damaging fertility or the unborn child. H372: Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P235: Keep cool.
Response
P302+352 IF ON SKIN Wash with plenty of soap and water P303+361+353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313 IF exposed or concerned Get medical attention/advice P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical attention/advice if you feel unwell. P321: Specific treatment see label. P332+313: If skin irritation occurs, get medical advice/attention. P333+313: If skin irritation or rash occurs, seek medical advice/attention. P337+313: If eye irritation persists, get medical advice/attention. P362: Take off contaminated clothing and wash before re-use. P363: Wash contaminated clothing before reuse. P370+378: In case of fire, use dry chemical powder to extinguish.
Storage
P403+233: Store container tightly closed in well-ventilated place. P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations.
Potential health effects
INHALATION ACUTE EXPOSURE EFFECTS: (Acute and Chronic): Vapor Harmful. May cause dizziness, headache, irritation of the upper respiratory tract and lungs, irritation and injury to mucous membranes, watering of the eyes, weakness, drowsiness, nausea, loss of coordination, numbness in fingers, arms and legs, depression of the central nervous system, pulmonary edema, shortness of breath, loss of appetite, fatigue, stupor, anesthesia, narcosis, vomiting, lightheadedness, liver and kidney injury, insensibility and other central nervous system effects, blood disorders, nose tumors, brain damage, giddiness, olfactory changes, confusion, hearing impairment, slurred speech, coughing, hallucinations, irregular heartbeat, unconsciousness, coma, and death. Intentional misuse of this product by deliberately concentrating and inhaling vapors can be harmful or fatal. SKIN CONTACT ACUTE EXPOSURE EFFECTS: This product is a skin irritant. Product may be absorbed through the skin. May cause irritation, drying and cracking of the skin, defatting of the skin, dermatitis, itching, redness, swelling, tissue damage, inflammation, numbness in fingers and arms, discomfort or pain, erythema. May be absorbed readily to produce symptoms similar to those listed under ingestion. EYE CONTACT ACUTE EXPOSURE EFFECTS: This material is an eye irritant. May cause redness, tearing, corneal clouding, discomfort or pain with excessive blinking and tear production, excess redness and possible slight swelling of the conjunctiva, stinging, conjunctivitis, visual intolerance to light. If not promptly removed, will injure eye tissue, which may result in permanent damage. INGESTION ACUTE EXPOSURE EFFECTS: Harmful or fatal if swallowed. May cause dizziness, headache, drowsiness, nausea, weakness, loss of coordination, irritation to mouth, throat and stomach, vomiting, gastrointestinal irritation, diarrhea, loss of appetite, pain and discomfort, cough and hoarseness, salivation, changes in white blood cells, burning sensation in mouth and stomach, unconsciousness and coma. Ingestion of significant quantities may result in red blood cell hemolysis. Liquid aspirated into lungs can cause chemical pneumonitis, which can be fatal. CHRONIC EXPOSURE EFFECTS: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged skin contact may result in absorption of a harmful amount of this material. Prolonged or repeated contact may cause dermatitis. May cause dizziness, headaches, weakness, eye irritation, drying and cracking of the skin, dermatitis, fatigue, nausea, numbness in the hands and feet, permanent central nervous system changes, some loss of memory, liver and kidney damage, blood disorders, thyroid effects, enlarged liver, and irritation to the respiratory tract. Prolonged or repeated contact may cause skin irritation, even a burn. Prolonged exposure may cause slight swelling of the conjunctiva, blurring of vision may occur. Prolonged skin contact may cause mild to moderate redness and swelling. Medical Conditions Generally Diseases of the skin, liver, kidneys, and cardiovascular system. Aggravated By Exposure