Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
≤100%
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
≤50%
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
10%
General Information
Revision date
2020-01-15
Product name
CB-1128B
Emergency telephone
+1 (518) 344-7100, +1 800-262-8200, +1 (518) 793-7788
Icons in SDS
Company Information
company name
Von Roll USA, Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
NFPA Rating Classification of the substance or mixture GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Carc. 2 H351 Suspected of causing cancer STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure GHS07 Acute Tox. 4 H332 Harmful if inhaled Skin Irrit. 2 H315 Causes skin irritation Eye Irrit. 2A H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction STOT SE 3 H335 May cause respiratory irritation
2.2 Label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
diphenylmethanediisocyanate,isomeres and homologues 4,4'-methylenediphenyl diisocyanate methylenediphenyl diisocyanate
Hazard statements
H332 Harmful if inhaled. (Contd. on page 2) US (Contd. of page 1) H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 If on skin: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a poison center/doctor if you feel unwell. P321 Specific treatment (see on this label). P314 Get medical advice/attention if you feel unwell. P362+P364 Take off contaminated clothing and wash it before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system
· NFPA ratings (scale 0 - 4) Health = 3 1 Fire = 1 3 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH 3 Health = 3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0
PBT Substances
Not applicable
vPvB Substances
Not applicable US (Contd. on page 3) (Contd. of page 2) *
2.1 Classification of the substance or mixture
GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H332 Harmful if inhaled. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.