UNSUITABLE EXTINGUISHING EQUIPMENT

Hazard statements (CLP)

H226, H304, H336, H372, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

and thoroughness of provided information according to each specific use of the product. H372 mg/kg/d Causes damage to organs through prolonged or repeated exposure. mg/kg/d 3.2. Mixtures. HYDROCARBONS, H304 May be fatal if swallowed and enters airways. C9-C11, n-ALKANES, ISOALKANES, CYCLICS, SECTION 10. Stability and reactivity. The product must not penetrate into the sewer system or come into contact with surface water or ground water. Legend: This document must not be regarded as a guarantee on any specific product property. <2% AROMATICS

2.1 Classification of the substance or mixture

Rapidly biodegradable. H336 May cause drowsiness or dizziness. ADR / RID: (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Environmentally Hazardous. 1272/2008 (CLP) 8.2. Exposure controls. remainder with inert absorbent material. amendments. Text of risk (R) phrases mentioned in section 2-3 of the sheet: amendments. IMDG: Marine Pollutant. 10.2. Chemical stability. Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of 12.3. Bioaccumulative potential. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. HYDROCARBONS, C9-C12, n-ALKANES, ISOALKANES, CYCLICS, AROMATICS (2-25%) Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. in compliance with the provisions set forth in point 13. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well The product is stable in normal conditions of use and storage. CAS. R10 64742-82-1 90 - 99 FLAMMABLE. R10, R66, R67, Xn R65, N R51/53, Note P Flam. Liq. 3 H226, STOT RE 1 H372, Asp. Tox. 1 H304, aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. R51/53 TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC 2.1.1. Regulation 1272/2008 (CLP) and following amendments and adjustments. HYDROCARBONS, EC. 919-446-0 STOT SE 3 H336, Aquatic Chronic 2 H411, EUH066, Note P C9-C11, n-ALKANES, ISOALKANES, CYCLICS, 6.4. Reference to other sections. 10.3. Possibility of hazardous reactions. Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to <2% AROMATICS IATA: Partition coefficient: n-octanol/water. INDEX. 649-330-00-2 NO ENVIRONMENT. 5 Any information on personal protection and disposal is given in sections 8 and 13. The vapours may also form explosive mixtures with the air. guarantee maximum protection (e.g. reduction in replacement times). R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED. Hazard classification and indication: Reg. no. 01-2119458049-XXXX HYDROCARBONS, C9-C11, n-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS HAND PROTECTION HYDROCARBONS, For Air transport, environmentally hazardous mark is only mandatory for UN 3077 and UN 3082. R66 Flammable liquid, category 3 REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING. C9-C12, n-ALKANES, H226 ISOALKANES, Flammable liquid and vapour. CYCLICS, 10.4. Conditions to avoid. Protect hands with category III work gloves (see standard EN 374). R67 AROMATICS VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS. (2-25%) R10, R66, R67, Xn R65, Note P Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H336, EUH066, Note P SECTION 7. Handling and storage. Partition coefficient: n-octanol/water. CAS. Specific target organ toxicity - repeated exposure, category 1 H372 64742-48-9 5 - 9 3,7 Causes damage to organs through prolonged or repeated Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 14.6. Special precautions for user. EC. 919-857-5 exposure. 7.1. Precautions for safe handling. 12.4. Mobility in soil. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the INDEX. 649-327-00-6 Aspiration hazard, category 1 H304 May be fatal if swallowed and enters airways. 10.5. Incompatible materials. Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may duration and type of use. LEGEND: Information not available. ADR / RID: Reg. no. 01-2119463258-XXXX Specific target organ toxicity - single exposure, category 3 H336 HIN - Kemler: 30 Limited Quantities: - May cause drowsiness or dizziness. Tunnel restriction code: - Information not available. accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Do SKIN PROTECTION - ADR: European Agreement concerning the carriage of Dangerous goods by Road Hazardous to the aquatic environment, chronic toxicity,

Contains

H411 Toxic to aquatic life with long lasting effects. 6.3. Methods and material for containment and cleaning up. 10.1. Reactivity. VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and HYDROCARBONS, The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and EUH066 Repeated exposure may cause skin dryness or cracking. C9-C12, n-ALKANES, ISOALKANES, CYCLICS, Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the There are no particular risks of reaction with other substances in normal conditions of use. Provide appointed staff with adequate training on how to use chemical products. AROMATICS (2-25%) supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent Identification. Rapidly biodegradable. supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent Conc. %.

Special Provisions

H411 Toxic to aquatic life with long lasting effects.

Results of PBT and vPvB assessment

Note: Upper limit is not included into the range. not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people Wear category III professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body - CAS NUMBER: Chemical Abstract Service Number Changes to previous review: IMDG: category 2 EMS: - Limited Quantities: - 10.6. Hazardous decomposition products. - CE50: Effective concentration (required to induce a 50% effect) The following sections were modified: The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. eat. Avoid leakage of the product into the environment. with soap and water after removing protective clothing. IATA: Cargo: Maximum quantity: - Packaging instructions: - 2.1.2. 67/548/EEC and 1999/45/EC Directives and following amendments and adjustments. Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. - CE NUMBER: Identifier in ESIS (European archive of existing substances) 02 / 07 / 08 / 09 / 11 / 14 / 15. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Pass.: Maximum quantity: - Packaging instructions: - 7.2. Conditions for safe storage, including any incompatibilities. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = EYE PROTECTION - CLP: EC Regulation 1272/2008 Dangerous for the Environment(N) Special Instructions: -

Hazard pictograms

Store only in the original container. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other Wear airtight protective goggles (see standard EN 166). - DNEL: Derived No Effect Level Xn-N 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. sources of ignition. Keep containers away from any incompatible materials, see section 10 for details. In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent - EmS: Emergency Schedule 11.1. Information on toxicological effects.