SILOMER 101

Hazard statements (CLP)

H336

Code

Statements

H336

May cause drowsiness or dizziness

SECTION 2: Hazards identification

1999/45/EC Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. Provide appointed staff with adequate training on how to use chemical products. H336 May cause drowsiness or dizziness. EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get EUH066 Repeated exposure may cause skin dryness or cracking.

2.1 Classification of the substance or mixture

SECTION 10. Stability and reactivity. SECTION 8. Exposure controls/personal protection. medical advice/attention. EUH210 Safety data sheet available on request. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. 10.1. Reactivity. SECTION 14. Transport information. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Text of risk (R) phrases mentioned in section 2-3 of the sheet: 8.1. Control parameters.

UN Number

There are no particular risks of reaction with other substances in normal conditions of use. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data authorised by a doctor. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments. INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments. R65 HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED. 10.2. Chemical stability. breathing, administer artificial respiration. Take suitable precautions for rescue workers. Information not available. Not applicable. The product is stable in normal conditions of use and storage. R66 REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING. 2.1.1. Regulation 1272/2008 (CLP) and following amendments and adjustments. R67 VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS. 4.2. Most important symptoms and effects, both acute and delayed. 8.2. Exposure controls. 14.2. UN proper shipping name. 10.3. Possibility of hazardous reactions. For symptoms and effects caused by the contained substances, see chap. 11. Hazard classification and indication: -- No hazardous reactions are foreseeable in normal conditions of use and storage. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well Not applicable. LEGEND: 4.3. Indication of any immediate medical attention and special treatment needed. aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. - ADR: European Agreement concerning the carriage of Dangerous goods by Road 10.4. Conditions to avoid. 14.3. Transport hazard class(es). Information not available. HAND PROTECTION 2.1.2. 67/548/EEC and 1999/45/EC Directives and following amendments and adjustments. - CAS NUMBER: Chemical Abstract Service Number None in particular. However the usual precautions used for chemical products should be respected. Protect hands with category III work gloves (see standard EN 374). Changes to previous review: - CE50: Effective concentration (required to induce a 50% effect)

Hazard pictograms

The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Not applicable. The following sections were modified: - CE NUMBER: Identifier in ESIS (European archive of existing substances) -- 10.5. Incompatible materials. SECTION 5. Firefighting measures. with soap and water after removing protective clothing. - IATA DGR: International Air Transport Association Dangerous Goods Regulation UNSUITABLE EXTINGUISHING EQUIPMENT --

R-phrase(s)

The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the 07 / 09. - CLP: EC Regulation 1272/2008 -- 14.4. Packing group. Information not available. duration and type of use. 5.1. Extinguishing media. - DNEL: Derived No Effect Level

2.2 Label elements

SKIN PROTECTION SUITABLE EXTINGUISHING EQUIPMENT - EmS: Emergency Schedule 10.6. Hazardous decomposition products. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Not applicable. The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. - GHS: Globally Harmonized System of classification and labeling of chemicals Information not available.

Environmental hazards

EYE PROTECTION - IC50: Immobilization Concentration 50% None in particular.

Signal word

Wear airtight protective goggles (see standard EN 166). - IMDG: International Maritime Code for dangerous goods -- RESPIRATORY PROTECTION Not applicable. - IMO: International Maritime Organization 5.2. Special hazards arising from the substance or mixture.

Hazard statements

If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type B Petroleum distillates hydrotreated middle LD50 > 2000 mg/kg (oral) - INDEX NUMBER: Identifier in Annex VI of CLP HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE 14.6. Special precautions for user. filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or LD50>2000 mg/kg (dermal). - LC50: Lethal Concentration 50% EUH210 Safety data sheet available on request. Do not breathe combustion products. vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. - LD50: Lethal dose 50% Contains: EUH208

Contains

4,5-dichloro-2-octyl-2H-isothiazol-3-one 11.1. Information on toxicological effects. 5.3. Advice for firefighters. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the Not applicable. - OEL: Occupational Exposure Level May produce an allergic reaction. threshold values considered. The protection provided by masks is in any case limited. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, GENERAL INFORMATION

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, using the criteria specified in the applicable regulation for classification. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. - PEC: Predicted environmental Concentration

Precautionary statements

wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated - PEL: Predicted exposure level -- compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. toxicological effects of exposure to the product. Information not relevant. water used for extinction and the remains of the fire according to applicable regulations. - PNEC: Predicted no effect concentration

2.3 Other hazards

ENVIRONMENTAL EXPOSURE CONTROLS. - REACH: EC Regulation 1907/2006 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure - RID: Regulation concerning the international transport of dangerous goods by train Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with SECTION 15. Regulatory information. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. compliance with environmental standards. - TLV: Threshold Limit Value On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Distillates (petroleum), hydrotreated middle - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. LD50 (Oral). - TWA STEL: Short-term exposure limit > 2000 mg/kg Rat LD50 (Dermal). - TWA: Time-weighted average exposure limit > 2000 mg/kg Rabbit Seveso category. - VOC: Volatile organic Compounds None. EPY 9.0.9 - SDS 1003