H319

Hazard statements (CLP)

H226, H304, H312, H315, H317, H319, H332, H335, H373

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Oxidising properties - TLV: Threshold Limit Value TLV-ACGIH 0,0015 434 100 mg/L Not available. 651 150 None. ISOPHORONDIISOCYANATE HOMOPOLYMER Normal value in marine water 0,00015 mg/L

Further information

Health - Derived no-effect level - DNEL / DMEL The product, if packaged in packages of less than 30 litres, is not subject to obligations relating to marking, labelling and package testing in - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. 3.1. Substances. in compliance with the provisions set forth in point 13. IMDG: 7. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Class: 3 Label: 3 XYLENE (MIXTURE OF ISOMERS) aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. 8. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament Eye irritation, category 2 H319 Causes serious eye irritation. 1-METHOXY-2-PROPANOL ACETATE: may react violently with oxidising agents and strong acids and alkaline metals. R10, Xn R20/21, Xi R38, Note C Provide an emergency shower with face and eye wash station. Text of hazard (H) indications mentioned in section 2-3 of the sheet: ISOPHORONDIISOCYANATE HOMOPOLYMER 9. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament CAS. Skin irritation, category 2 1330-20-7 30 - 50 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, H315 Causes skin irritation. Asp. Tox. 1 H304, STOT RE 2 H373, Eye Irrit. 2 H319, Skin Irrit. 2 H315, 6.4. Reference to other sections. XYLENE (MIXTURE OF ISOMERS): stable, but may develop violent reactions in the presence of strong oxidising agents such as sulphuric and Exposure levels must be kept as low as possible to avoid significant build-up in the organism. Manage personal protective equipment so as to EC. 215-535-7 LC50 - for Fish. Specific target organ toxicity - single exposure, category 3 H335 > 1,51 mg/l/96h CYPRINUS CAPRIO May cause respiratory irritation. STOT SE 3 H335, Note C Any information on personal protection and disposal is given in sections 8 and 13. guarantee maximum protection (e.g. reduction in replacement times). nitric acids and perchlorates. May form explosive mixtures with the air. 10. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament EC50 - for Crustacea. IATA: INDEX. 601-022-00-9 Flam. Liq. 3 Skin sensitization, category 1 Class: 3 Flammable liquid, category 3 Label: 3 > 3,36 mg/l/48h DAPHNIA MAGNA H317 May cause an allergic skin reaction. 11. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament Reg. no. 01-2119488216-XXXX Acute Tox. 4 Acute toxicity, category 4 HAND PROTECTION 10.4. Conditions to avoid. 2.1.2. 67/548/EEC and 1999/45/EC Directives and following amendments and adjustments. ISOPHORONDIISOCYANATE HOMOPOLYMER Protect hands with category III work gloves (see standard EN 374). XYLENE (MIXTURE OF ISOMERS) Asp. Tox. 1 Aspiration hazard, category 1 SECTION 7. Handling and storage. Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. - The Merck Index. - 10th Edition STOT RE 2 Specific target organ toxicity - repeated exposure, category 2 Xi R37, Xi R43 STOT SE 3 H335, Skin Sens. 1 H317 The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. LC50 - for Fish. CAS. 53880-05-0 10 - 20 > 1 mg/l/96h - Handling Chemical Safety EC. Eye Irrit. 2 500-125-5 Eye irritation, category 2 7.1. Precautions for safe handling.

2.1 Classification of the substance or mixture

SECTION 6. Accidental release measures. LD50 (Oral). Normal value of STP microorganisms > 14000 mg/kg RAT Information not available. accordance with 2.3.2.5 of the IMDG CODE. Substances subject to the Stockholm Convention: - TWA STEL: Short-term exposure limit 100 mg/L Effects on consumers. Effects on workers Health - Derived no-effect level - DNEL / DMEL LC50 (Inhalation). 1272/2008 (CLP) mg/kg/d 14.3. Transport hazard class(es). The product must not penetrate into the sewer system or come into contact with surface water or ground water. 1. Directive 1999/45/EC and following amendments (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. LC50 (Inhalation). > 10 mg/l/4h Rat Hazard classification and indication: 2. Directive 67/548/EEC and following amendments and adjustments 15.2. Chemical safety assessment. 10.2. Chemical stability. 1-METHOXY-2-PROPANOL ACETATE VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. 3. Regulation (EU) 1907/2006 (REACH) of the European Parliament Flammable liquid, category 3 H226 Flammable liquid and vapour. 6.3. Methods and material for containment and cleaning up. The product is stable in normal conditions of use and storage. ADR / RID: CAS. Acute toxicity, category 4 108-65-6 Class: 3 30 - 50 Label: 3 R10, Xi R36 H332 Harmful if inhaled. Flam. Liq. 3 H226 8.2. Exposure controls.

Principle Routes of Exposure

Acute local Acute > 5 mg/l/4h RAT Chronic local Chronic Acute local Acute systemicChronic Chronic 6.1. Personal precautions, protective equipment and emergency procedures. Information not relevant. None. - TWA: Time-weighted average exposure limit The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and Effects on consumers. Effects on workers 14.2. UN proper shipping name. Block the leakage if there is no hazard. - VOC: Volatile organic Compounds systemic local systemic SECTION 10. Stability and reactivity. supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent 1-METHOXY-2-PROPANOL ACETATE supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent Oral. Acute local Acute Chronic local Chronic VND 1,6 Acute local Acute systemicChronic 3.2. Mixtures. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any Healthcare controls. LD50 (Oral). Chronic 8530 mg/kg Rat systemic amendments. - WGK: Water hazard classes (German). local systemic mg/kg/d 10.1. Reactivity. contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency ADR / RID: Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks LD50 (Dermal). Inhalation. PAINT or PAINT RELATED MATERIAL > 5000 mg/kg Rat 0.58 NPI Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. 0.29 Inhalation. NPI 174 VND 14,8 289 VND 77

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation

Contains

procedures. There are no particular risks of reaction with other substances in normal conditions of use. IMDG: related to the workers' health and safety are modest and that the 98/24/EC directive is respected. PAINT or PAINT RELATED MATERIAL mg/m3 IATA: XYLENE (MIXTURE OF ISOMERS) PAINT or PAINT RELATED MATERIAL 2.1.1. Regulation 1272/2008 (CLP) and following amendments and adjustments. GENERAL BIBLIOGRAPHY Skin. VND 108 VND 180 6.2. Environmental precautions. Identification. 1-METHOXY-2-PROPANOL ACETATE: stable but with the air it may slowly develop peroxides that explode with an increase in temperature. Product not intended for uses provided for by Dir. 2004/42/CE. Legend: LD50 (Oral). Conc. %. > 2000 mg/kg Rat

67/548/EEC

mg/kg/d

ECOLOGICAL INFORMATION

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the No chemical safety assessment has been processed for the mixture and the substances it contains. 4. Regulation (EU) 1272/2008 (CLP) of the European Parliament EC. Aspiration hazard, category 1 203-603-9 H304 May be fatal if swallowed and enters airways. 10.3. Possibility of hazardous reactions. remainder with inert absorbent material. 5. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament INDEX. 607-195-00-7 Specific target organ toxicity - repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of The vapours may also form explosive mixtures with the air. 6. Regulation (EU) 453/2010 of the European Parliament As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well Reg. no. 01-2119475791-29 exposure. 12.1. Toxicity.

Hazard pictograms

The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the EC50 - for Crustacea. - Niosh - Registry of Toxic Effects of Chemical Substances Skin irritation, category 2 Xn > 1 mg/l/48h 14.4. Packing group. 1-METHOXY-2-PROPANOL ACETATE: store in an inert atmosphere, sheletered from moisture because it hydrolises easily. Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may duration and type of use. EC50 - for Algae / Aquatic Plants. INDEX. Skin Irrit. 2 > 1 mg/l/72h - INRS - Fiche Toxicologique (toxicological sheet) STOT SE 3 Specific target organ toxicity - single exposure, category 3

R-phrase(s)

accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Do SKIN PROTECTION Reg. no. 01-2119488734-24 10-20/21-36/38-43 Chronic NOEC for Fish. - Patty - Industrial Hygiene and Toxicology Skin Sens. 1 Skin sensitization, category 1 > 1 mg/l based on test data 10.5. Incompatible materials. not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body ADR / RID, IMDG, IATA: III Chronic NOEC for Crustacea. - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 1-METHOXY-2-PROPANOL ACETATE: oxidising agents, strong acids and alkaline metals. H226 Flammable liquid and vapour. > 0,1 mg/l Note: Upper limit is not included into the range. The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. eat. Avoid leakage of the product into the environment. with soap and water after removing protective clothing. The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. - ECHA website H312 Harmful in contact with skin.

Environmental hazards

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. H332 Harmful if inhaled. 12.2. Persistence and degradability. 10.6. Hazardous decomposition products.

2.2 Label elements

7.2. Conditions for safe storage, including any incompatibilities. EYE PROTECTION H304 May be fatal if swallowed and enters airways. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. Dangerous for the Environment(N) Store only in the original container. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other Wear airtight protective goggles (see standard EN 166). ADR / RID: ISOPHORONDIISOCYANATE HOMOPOLYMER H373 NO May cause damage to organs through prolonged or repeated exposure. Note for users: RESPIRATORY PROTECTION Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. sources of ignition. Keep containers away from any incompatible materials, see section 10 for details. IMDG: NOT rapidly biodegradable. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability H319 NO Causes serious eye irritation. If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A IATA: H315 NO Causes skin irritation.

TOXICOLOGICAL INFORMATION

and thoroughness of provided information according to each specific use of the product. H335 May cause respiratory irritation. 7.3. Specific end use(s).