DIAXYL SOLVENTBASED

Hazard statements (CLP)

H302, H304, H317, H318, H331, H372, H400, H410, H412

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

The product must not penetrate into the sewer system or come into contact with surface water or ground water. Not applicable. CAS. OEL 34590-94-8 SKIN. EU 4 - 6 308 Substance with a community workplace exposure limit. 50 SKIN. PROPICONAZOLE

2.1 Classification of the substance or mixture

SECTION 10. Stability and reactivity. EC. TLV-ACGIH 252-104-2 606 100 909 150 SKIN. 6.3. Methods and material for containment and cleaning up. 14.6. Special precautions for user. LC50 - for Fish. INDEX. 4,3 mg/l/96h LEGEND: EC50 - for Crustacea. 10,2 mg/l/48h Daphnia magna 10.1. Reactivity. Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and Legend: - ADR: European Agreement concerning the carriage of Dangerous goods by Road The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and Reg. no. 01-2119450011-60 EC50 - for Algae / Aquatic Plants. 3-IODO-2-PROPYNYLBUTYLCARBAMATE remainder with inert absorbent material. There are no particular risks of reaction with other substances in normal conditions of use. Not applicable. 0,76 mg/l/72h Scenedesmus subspicatus supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. - CAS NUMBER: Chemical Abstract Service Number supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of amendments. - CE50: Effective concentration (required to induce a 50% effect) amendments. CAS. 55406-53-6 0,74 - 0,76 Acute Tox. 3 H331, Acute Tox. 4 H302, STOT RE 1 H372, Eye Dam. 1 H318, Skin Sens. 1 H317, 12.2. Persistence and degradability. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. in compliance with the provisions set forth in point 13. DIPROPYLENE GLYCOL MONOMETHYL ETHER: may react with oxidising agents. When heated to decomposition it releases harsh and Aquatic Acute 1 H400 M=10, Aquatic Chronic 1 H410 8.2. Exposure controls. - CE NUMBER: Identifier in ESIS (European archive of existing substances) Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. irritating fumes and vapours. - CLP: EC Regulation 1272/2008 EC. 259-627-5 6.4. Reference to other sections. HYDROCARBONS, Information not relevant. C10-C13, n-ALKANES, ISOALKANES, CYCLICS, As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well - DNEL: Derived No Effect Level INDEX. 616-212-00-7 <2% AROMATICS Hazard classification and indication: Rapidly biodegradable. Hazard classification and indication: 10.2. Chemical stability. PROPICONAZOLE Any information on personal protection and disposal is given in sections 8 and 13. aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. - EmS: Emergency Schedule Aspiration hazard, category 1 H304 May be fatal if swallowed and enters airways. The product is stable in normal conditions of use and storage. HAND PROTECTION - GHS: Globally Harmonized System of classification and labeling of chemicals CAS. Hazardous to the aquatic environment, chronic toxicity, 60207-90-1 0,23 - 0,25 Acute Tox. 4 H302, Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1, Aquatic Chronic 1 H410 H412 Harmful to aquatic life with long lasting effects. SECTION 15. Regulatory information. 3-IODO-2-PROPYNYLBUTYLCARBAMATE Protect hands with category III work gloves (see standard EN 374). - IATA DGR: International Air Transport Association Dangerous Goods Regulation EC. category 3 262-104-4 10.3. Possibility of hazardous reactions. SECTION 7. Handling and storage. Rapidly biodegradable. INDEX. 613-205-00-0 The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. - IC50: Immobilization Concentration 50% 7.1. Precautions for safe handling. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. No hazardous reactions are foreseeable in normal conditions of use and storage. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the - IMDG: International Maritime Code for dangerous goods

2.2 Label elements

PROPICONAZOLE Note: Upper limit is not included into the range. Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. duration and type of use. - IMO: International Maritime Organization 10.4. Conditions to avoid. NOT rapidly biodegradable. The full wording of hazard (H) phrases is given in section 16 of the sheet. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which SKIN PROTECTION Seveso category. - INDEX NUMBER: Identifier in Annex VI of CLP Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. None. None in particular. However the usual precautions used for chemical products should be respected. people eat. Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body - LC50: Lethal Concentration 50% 12.3. Bioaccumulative potential. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.

Hazard pictograms

with soap and water after removing protective clothing. - LD50: Lethal dose 50% 10.5. Incompatible materials.