AGW

Hazard statements (CLP)

H226, H302, H304, H312, H315, H317, H318, H319, H331, H332, H335, H336, H351, H361d, H372, H373, H400, H410, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Solubility LD50 (Dermal).

Principle Routes of Exposure

Acute local Acute > 5000 mg/kg Rabbit insoluble in water Chronic local Chronic Acute local Acute systemicChronic Chronic SECTION 6. Accidental release measures. HYDROCARBONS, The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability EC. H331 918-481-9 Toxic if inhaled. C9-C11, n-ALKANES, ISOALKANES, CYCLICS, Partition coefficient: n-octanol/water LC50 (Inhalation). ADR / RID: <2% AROMATICS HIN - Kemler: 30 > 20 mg/l/4h Rat systemic Not available. Limited Quantities: 5 L systemic Tunnel restriction code: (D/E) Flammable liquid, category 3 May cause respiratory irritation. Acute local Acute Chronic local Chronic H226 Flammable liquid and vapour. Acute local Acute systemicChronic LD50 (Dermal). Information not relevant. Chronic HYDROCARBONS, C10-C13, n-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS > 2000 mg/kg Rabbit SECTION 10. Stability and reactivity. CAS. H317 Aspiration hazard, category 1 407-000-3 0,5 - 1,5 May cause an allergic skin reaction. systemic Aquatic Chronic 2 H411 H304 systemic May be fatal if swallowed and enters airways. local systemic 6.3. Methods and material for containment and cleaning up. Threshold Limit Value. EC. 127519-17-9 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. H336 Oral. Type Specific target organ toxicity - single exposure, category 3 H336 Country May cause drowsiness or dizziness. TWA/8h VND STEL/15min 2,83 May cause drowsiness or dizziness. 10.1. Reactivity. SECTION 15. Regulatory information.

2.1 Classification of the substance or mixture

Partition coefficient: n-octanol/water. and thoroughness of provided information according to each specific use of the product. INDEX. 649-327-00-6 H302 local systemic Harmful if swallowed. 5 6.1. Personal precautions, protective equipment and emergency procedures. Auto-ignition temperature. H312 Oral. Harmful in contact with skin.

Special Provisions

640E Not available. VND 300 This document must not be regarded as a guarantee on any specific product property. Reg. no. 01-2119457273-XXXX CALCIUM BIS (2-ETHYLHEXANOATE) Decomposition temperature. HYDROCARBONS, IMDG: Block the leakage if there is no hazard. H332 Harmful if inhaled. EMS: F-E, S-E C10-C13, n-ALKANES, Not available. Limited Quantities: 5 L mg/kg/d ISOALKANES, CYCLICS, XYLENE (MIXTURE OF ISOMERS) The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and Threshold Limit Value. 3-IODO-2-PROPYNYLBUTYLCARBAMATE The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and <2% AROMATICS Viscosity LD50 (Oral). IATA: Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any H372 Inhalation. Causes damage to organs through prolonged or repeated exposure. Cargo: > 5000 mg/kg 20-40 sec VND Maximum quantity: 220 L 900 VND 1500 Packaging instructions: 366 supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent Partition coefficient: n-octanol/water. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent CAS. Type 1330-20-7 Country 1 - 3 TWA/8h Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373, 2,81 STEL/15min Explosive properties LD50 (Dermal). contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency H304 May be fatal if swallowed and enters airways. Pass.: > 5000 mg/kg not applicable Maximum quantity: 60 L mg/m3 Packaging instructions: 355 amendments. Provide appointed staff with adequate training on how to use chemical products. amendments. mg/m3 Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Note C ppm mg/m3 ppm Oxidising properties LC50 (Inhalation). procedures. H373 Skin. May cause damage to organs through prolonged or repeated exposure. Special Instructions: > 20 mg/l/4h Rat not applicable VND A3, A72, A192 300 12.4. Mobility in soil. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC. VND TLV 215-535-7 300 GRC 5000

Further information

H318 Causes serious eye damage. mg/kg/d Health - Derived no-effect level - DNEL / DMEL Information not available. INDEX. 601-022-00-9 mg/kg/d 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. 6.2. Environmental precautions. Information not available. 3-IODO-2-PROPYNYLBUTYLCARBAMATE H319 Causes serious eye irritation. Hazard classification and indication: Reg. no. 01-2119488216-XXXX Causes skin irritation. Effects on consumers. Effects on workers LD50 (Oral). The product must not penetrate into the sewer system or come into contact with surface water or ground water. H315 1056 mg/kg Rat

Results of PBT and vPvB assessment

Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]propionates H335

ECOLOGICAL INFORMATION

Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the INDEX. 607-281-00-4 H400 Very toxic to aquatic life. mg/m3 ppm mg/m3 ppm

2.2 Label elements

remainder with inert absorbent material. There are no particular risks of reaction with other substances in normal conditions of use. Reg. no. 01-0000015648-61 H410 Inhalation. Very toxic to aquatic life with long lasting effects. VND 9,86 Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of VND MAK 39,98 DEU 300 50 600 100 ETHYL METHYL KETOXIME H411 Toxic to aquatic life with long lasting effects. mg/m3 12.1. Toxicity. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. in compliance with the provisions set forth in point 13. 2-BUTANONE OXIME: decomposes under the effect of heat. EUH066 OEL mg/m3 EU Repeated exposure may cause skin dryness or cracking. 1200 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Information not available. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. CAS. Skin. 96-29-7 0,1 - 0,3 Carc. 2 H351, Acute Tox. 4 H312, Eye Dam. 1 H318, Skin Sens. 1 H317 VND 2,83 VND 5,67 EC. 202-496-6 mg/m3 mg/kg/d 6.4. Reference to other sections. 10.2. Chemical stability. XYLENE (MIXTURE OF ISOMERS) Seveso category.

Hazard pictograms

INDEX. 616-014-00-0 6 SECTION 13. Disposal considerations. 3-IODO-2-PROPYNYLBUTYLCARBAMATE Any information on personal protection and disposal is given in sections 8 and 13. The product is stable in normal conditions of use and storage. LC50 - for Fish. Legend: > 1 mg/l/96h (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. EC50 - for Crustacea. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. LEGEND: CAS. 55406-53-6 0,1 - 0,25 Acute Tox. 3 H331, Acute Tox. 4 H302, STOT RE 1 H372, Eye Dam. 1 H318, Skin Sens. 1 H317, > 1 mg/l/48h 10.3. Possibility of hazardous reactions. EC50 - for Algae / Aquatic Plants. - ADR: European Agreement concerning the carriage of Dangerous goods by Road Product. > 1 mg/l/72h VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. Aquatic Acute 1 H400 M=10, Aquatic Chronic 1 H410 13.1. Waste treatment methods. SECTION 7. Handling and storage. The vapours may also form explosive mixtures with the air. Chronic NOEC for Fish. - CAS NUMBER: Chemical Abstract Service Number EC. Point. 259-627-5 3 - 40 > 1 mg/l based on test data Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product Chronic NOEC for Crustacea. > 0,1 mg/l 7.1. Precautions for safe handling. 8.2. Exposure controls. - CE50: Effective concentration (required to induce a 50% effect) INDEX. 616-212-00-7 should be evaluated according to applicable regulations. Substances in Candidate List (Art. 59 REACH). 2-BUTANONE OXIME: thermal decomposition can have an explosive course. It reacts violently with strong oxidising agents and acids. Above CALCIUM BIS (2-ETHYLHEXANOATE) Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may - CE NUMBER: Identifier in ESIS (European archive of existing substances) Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. None. the flash point (69°C), explosive mixtures can form with air. HYDROCARBONS, - CLP: EC Regulation 1272/2008 0,1 - 0,3 C9-C11, Repr. 2 H361d, Eye Dam. 1 H318 n-ALKANES, ISOALKANES, CYCLICS, accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Do As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well CAS. <2% 136-51-6 AROMATICS Waste transportation may be subject to ADR restrictions. Substances subject to authorisarion (Annex XIV REACH). XYLENE (MIXTURE OF ISOMERS): stable, but may develop violent reactions in the presence of strong oxidising agents such as sulphuric and LC50 - for Fish. > 100 mg/l/96h

Signal word

not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. - DNEL: Derived No Effect Level CONTAMINATED PACKAGING None. EC. 205-249-0 Danger nitric acids and perchlorates. May form explosive mixtures with the air. EC50 - for Crustacea. eat. Avoid leakage of the product into the environment. HAND PROTECTION - EmS: Emergency Schedule Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: INDEX. > 100 mg/l/48h Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. EC50 - for Algae / Aquatic Plants. - GHS: Globally Harmonized System of classification and labeling of chemicals > 100 mg/l/72h

Hazard statements

Protect hands with category III work gloves (see standard EN 374). None. Reg. no. 01-2119978297-19-XXXX 10.4. Conditions to avoid. Chronic NOEC for Fish. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. - IATA DGR: International Air Transport Association Dangerous Goods Regulation H226 > 0,1 mg/l based on modeled data 7.2. Conditions for safe storage, including any incompatibilities. Flammable liquid and vapour. SECTION 14. Transport information. Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. Chronic NOEC for Crustacea. Note: Upper limit is not included into the range. Store only in the original container. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and other The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the - IC50: Immobilization Concentration 50% H304 May be fatal if swallowed and enters airways. > 0,1 mg/l based on modeled data Substances subject to the Rotterdam Convention: The full wording of hazard (H) phrases is given in section 16 of the sheet. sources of ignition. Keep containers away from any incompatible materials, see section 10 for details. duration and type of use. - IMDG: International Maritime Code for dangerous goods None. H336 May cause drowsiness or dizziness. 10.5. Incompatible materials.

UN Number

SKIN PROTECTION HYDROCARBONS, - IMO: International Maritime Organization EUH066 Repeated exposure may cause skin dryness or cracking. C10-C13, n-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS 7.3. Specific end use(s). Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body 2-BUTANONE OXIME: oxidising substances and strong acids. LC50 - for Fish. - INDEX NUMBER: Identifier in Annex VI of CLP Substances subject to the Stockholm Convention: EUH208

Contains

3-IODO-2-PROPYNYLBUTYLCARBAMATE > 100 mg/l/96h 3-IODO-2-PROPYNYLBUTYLCARBAMATE