- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure

Hazard statements (CLP)

H226, H315, H319

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008 SECTION 8. Exposure controls/personal protection. CONTAMINATED PACKAGING No chemical safety assessment has been processed for the mixture and the substances it contains. This document must not be regarded as a guarantee on any specific product property. 10.1. Reactivity. Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

2.1 Classification of the substance or mixture

The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health There are no particular risks of reaction with other substances in normal conditions of use. SECTION 5. Firefighting measures. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. 8.1. Control parameters. 5.1. Extinguishing media. 10.2. Chemical stability.

Further information

SECTION 14. Transport information. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments Provide appointed staff with adequate training on how to use chemical products. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and SUITABLE EXTINGUISHING EQUIPMENT The product is stable in normal conditions of use and storage. Text of hazard (H) indications mentioned in section 2-3 of the sheet: and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and

UN Number

subsequent amendments. Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can Information not available. subsequent amendments. 10.3. Possibility of hazardous reactions. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. be used to disperse flammable vapours and protect those trying to stem the leak. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Flam. Liq. 3 Flammable liquid, category 3 8.2. Exposure controls. UNSUITABLE EXTINGUISHING EQUIPMENT The vapours may also form explosive mixtures with the air. Not applicable. Eye Irrit. 2 Eye irritation, category 2 Hazard classification and indication: Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent Hazard classification and indication: Skin Irrit. 2 Skin irritation, category 2 -- 14.2. UN proper shipping name. 10.4. Conditions to avoid. explosions. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is H226 Flammable liquid and vapour. well aired through effective local aspiration. Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. H319 Causes serious eye irritation.

2.2 Label elements

5.2. Special hazards arising from the substance or mixture. HAND PROTECTION Not applicable. H315 Causes skin irritation. 10.5. Incompatible materials. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Protect hands with category III work gloves (see standard EN 374). EUH210 Safety data sheet available on request. 14.3. Transport hazard class(es). Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Information not available. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 5.3. Advice for firefighters. 10.6. Hazardous decomposition products.

Hazard pictograms

the duration and type of use. Not applicable. -- GENERAL INFORMATION LEGEND: SKIN PROTECTION In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. 14.4. Packing group.

Signal word

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. - ADR: European Agreement concerning the carriage of Dangerous goods by Road Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body -- - CAS NUMBER: Chemical Abstract Service Number Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated with soap and water after removing protective clothing. - CE50: Effective concentration (required to induce a 50% effect)

Hazard statements

water used for extinction and the remains of the fire according to applicable regulations. EYE PROTECTION

TOXICOLOGICAL INFORMATION

Not applicable. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Wear airtight protective goggles (see standard EN 166). - CE NUMBER: Identifier in ESIS (European archive of existing substances) EUH210 Safety data sheet available on request. 11.1. Information on toxicological effects.

Environmental hazards

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with RESPIRATORY PROTECTION - CLP: EC Regulation 1272/2008 EUH208

Contains

CMIT/MIT Mixture of 5-chloro-2-methyl-2H- isothiazol-3-one and self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). - DNEL: Derived No Effect Level If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it 2-methyl-2H-isothiazol-3-one - EmS: Emergency Schedule A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases contains, using the criteria specified in the applicable regulation for classification. Not applicable. May produce an allergic reaction. - GHS: Globally Harmonized System of classification and labeling of chemicals or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the - IATA DGR: International Air Transport Association Dangerous Goods Regulation Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the toxicological effects of exposure to the product. 14.6. Special precautions for user. - IC50: Immobilization Concentration 50%

Precautionary statements

threshold values considered. The protection provided by masks is in any case limited. -- - IMDG: International Maritime Code for dangerous goods If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Not applicable. - IMO: International Maritime Organization

2.3 Other hazards

emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing - INDEX NUMBER: Identifier in Annex VI of CLP apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. 3-BUTOXY-2-PROPANOL - LC50: Lethal Concentration 50% EPY 9.1.7 - SDS 1003 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.