DEU

Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Block the leakage if there is no hazard. Provide an emergency shower with face and eye wash station. Not applicable EC LIME - IMO: International Maritime Organization 238-878-4 mg/m3 ppm mg/m3 ppm Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent HAND PROTECTION LC50 - for Fish - INDEX NUMBER: Identifier in Annex VI of CLP WEL GBR 4 50,6 mg/l/96h

2.1 Classification of the substance or mixture

INDEX Interactive effects The product may react exothermically on contact with strong oxidising or reducing agents, strong acids or bases. 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Protect hands with category III work gloves (see standard EN 374). EC50 - for Crustacea - LC50: Lethal Concentration 50% 49,1 mg/l/48h PORTLAND CEMENT [Cr(VI) < 2 ppm] MAC NLD 10 procedures. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. EC50 - for Algae / Aquatic Plants - LD50: Lethal dose 50% 184,57 mg/l/72h The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments CAS Information not available The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments CALCIUM CARBONATE 65997-15-1 14 ≤ x < 19 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317, The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Chronic NOEC for Crustacea Information not relevant and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. - OEL: Occupational Exposure Level and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Classification note according to Annex VI to the CLP Regulation: 1 32 mg/l/14days 6.2. Environmental precautions the duration and type of use. Decomposes at temperatures above 800°C/1472°F. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC ACUTE TOXICITY Chronic NOEC for Algae / Aquatic Plants

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. 266-043-4 48 mg/l/72h QUARTZ SKIN PROTECTION INDEX Threshold Limit Value - PEC: Predicted environmental Concentration SECTION 15. Regulatory information LIME The product must not penetrate into the sewer system or come into contact with surface water or ground water. Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body 12.2. Persistence and degradability Hazard classification and indication: Reg. no. LC50 (Inhalation) of the mixture: - PEL: Predicted exposure level Hazard classification and indication: Type Scaldato a decomposizione emette: ossido di calcio ossido di magnesio acqua 02-2119682167-31 Country TWA/8h STEL/15min Not classified (no significant component) with soap and water after removing protective clothing. - PNEC: Predicted no effect concentration LIME LD50 (Oral) of the mixture: Serious eye damage, category 1 mg/m3 ppm mg/m3 Not classified (no significant component) H318 ppm H318 Causes serious eye damage. 6.3. Methods and material for containment and cleaning up EYE PROTECTION - REACH: EC Regulation 1907/2006 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture CAS LD50 (Dermal) of the mixture: Skin irritation, category 2 MAK Skin irritation, category 2 58398-71-3 2 ≤ x < 3 DEU 0,15 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 Not classified (no significant component) H315 Causes skin irritation. 10.2. Chemical stability Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166). EC CALCIUM CARBONATE - RID: Regulation concerning the international transport of dangerous goods by train Specific target organ toxicity - single exposure, VLA Specific target organ toxicity - single exposure, 261-235-4 ESP 0,05 H335 May cause respiratory irritation. Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the RESPIRATORY PROTECTION INDEX Solubility in water Seveso Category - Directive 2012/18/EC: - TLV: Threshold Limit Value category 3 VLEP category 3 FRA 0,1 0,1 - 100 mg/l None RESP remainder with inert absorbent material. If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type Excessively high temperatures can cause thermal decomposition. Reg. no. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Skin sensitization, category 1B WEL Skin sensitization, category 1B CALCIUM CARBONATE 01-2119474879-14-0001 GBR 0,3 H317 May cause an allergic skin reaction. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases - TWA STEL: Short-term exposure limit OEL LD50 (Oral) NLD 0,075 6450 mg/kg Rat 12.3. Bioaccumulative potential 10.3. Possibility of hazardous reactions Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 RESP or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. The full wording of hazard (H) phrases is given in section 16 of the sheet. - TWA: Time-weighted average exposure limit Product TLV-ACGIH 0,025

2.2 Label elements

6.4. Reference to other sections Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the Information not available - VOC: Volatile organic Compounds Point PORTLAND CEMENT [Cr(VI) < 2 ppm] 3 threshold values considered. The protection provided by masks is in any case limited. See paragraph 10.1. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. QUARTZ LD50 (Dermal)

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Contained substance > 2000 mg/kg RABBIT If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an The product contains less than 1% w/w RCS (respirable crystalline silica). The product does not require classification and labelling as Any information on personal protection and disposal is given in sections 8 and 13. - WGK: Water hazard classes (German). 47 PORTLAND CEMENT [Cr(VI) < 2 ppm] Point PORTLAND CEMENT [Cr(VI) < 2 ppm] emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing PORTLAND CEMENT [Cr(VI) < 2 ppm] hazardous according to Regulation (EC) No. 1272/2008, as amended. Threshold Limit Value LIME 12.4. Mobility in soil

Hazard pictograms

Si decompone a contatto con: acido idrofluoridrico Reg. no.: 02-2119682167-31 apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. Type LD50 (Oral) Country TWA/8h STEL/15min > 2000 mg/kg RAT SECTION 7. Handling and storage ENVIRONMENTAL EXPOSURE CONTROLS Information not available Substances in Candidate List (Art. 59 REACH) GENERAL BIBLIOGRAPHY LD50 (Dermal) mg/m3 ppm mg/m3 > 2500 mg/kg RABBIT 10.4. Conditions to avoid