P302+P352

Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

The product may react exothermically on contact with strong oxidising or reducing agents, strong acids or bases. - EmS: Emergency Schedule INDEX.

Environmental hazards

Make sure the leakage site is well aired. Evaluate the compatibility of the container to be used, by checking section 10. Contaminated material Does not meet the classification criteria for this hazard class. CALCIUM SULFOALUMINATE CEMENT - GHS: Globally Harmonized System of classification and labeling of chemicals should be disposed of in compliance with the provisions set forth in point 13.

2.1 Classification of the substance or mixture

10.2. Chemical stability. During the risk assessment process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate not - IATA DGR: International Air Transport Association Dangerous Goods Regulation CAS. 65997-15-1 14 ≤ x < 19 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317 Not applicable. otherwise classified (PNOC respirable fraction 3 mg/m3; PNOC inhalable fraction 10 mg/m3). For values above these limits, use a P type STOT - SINGLE EXPOSURE. - IC50: Immobilization Concentration 50% EC. 266-043-4 6.4. Reference to other sections. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment. May cause respiratory irritation. - IMDG: International Maritime Code for dangerous goods The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments 14.6. Special precautions for user. Excessively high temperatures can cause thermal decomposition. Any information on personal protection and disposal is given in sections 8 and 13. INDEX. and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and PORTLAND CEMENT [Cr(VI) < 2 ppm] - IMO: International Maritime Organization and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and 8.2. Exposure controls. subsequent amendments. STOT - REPEATED EXPOSURE. - INDEX NUMBER: Identifier in Annex VI of CLP subsequent amendments. CAS. 65997-15-1 14 ≤ x < 19 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317, Note 1 10.3. Possibility of hazardous reactions. Does not meet the classification criteria for this hazard class. Not applicable. SECTION 7. Handling and storage. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. - LC50: Lethal Concentration 50% Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC. 266-043-4 As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is - LD50: Lethal dose 50% INDEX. 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code. See paragraph 10.1.

Aspiration hazard

7.1. Precautions for safe handling. Hazard classification and indication: well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable - OEL: Occupational Exposure Level Hazard classification and indication: Reg. no. 02-2119682167-31 CALCIUM SULPHATE HEMIHYDRATE Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the standards. Does not meet the classification criteria for this hazard class.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Serious eye damage, category 1 H318 Causes serious eye damage. PORTLAND CEMENT [Cr(VI) < 2 ppm] Information not relevant. environment. Do not eat, drink or smoke during use. Provide an emergency shower with face and eye wash station. - PEC: Predicted environmental Concentration CAS. Skin irritation, category 2 10034-76-1 4 ≤ x < 5 H315 Causes skin irritation. Si decompone a contatto con: acido idrofluoridrico HAND PROTECTION - PEL: Predicted exposure level EC. Specific target organ toxicity - single exposure, category 3 H335 231-900-3

ECOLOGICAL INFORMATION

May cause respiratory irritation. 7.2. Conditions for safe storage, including any incompatibilities. SECTION 15. Regulatory information. In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). - PNEC: Predicted no effect concentration INDEX. Skin sensitization, category 1B H317 May cause an allergic skin reaction. 10.4. Conditions to avoid. Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or - REACH: EC Regulation 1907/2006 Reg. no. 01-2119444918-26-0198

2.2 Label elements

reactions. contaminate soil or vegetation. - RID: Regulation concerning the international transport of dangerous goods by train Avoid overheating. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. The full wording of hazard (H) phrases is given in section 16 of the sheet. PORTLAND CEMENT [Cr(VI) < 2 ppm] SKIN PROTECTION - TLV: Threshold Limit Value Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Effectiveness of the Chrome VI reducing agent Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. PORTLAND CEMENT [Cr(VI) < 2 ppm] 12.1. Toxicity. Intact packaging and compliance with the appropriate storage conditions as indicated above are the essential conditions to keep the with soap and water after removing protective clothing. Seveso Category - Directive 2012/18/EC: - TWA STEL: Short-term exposure limit Avoid exposure to: moisture. None.