Healthcare controls

Hazard statements (CLP)

H317, H332, H335, H336, H411, H412

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

water used for extinction and the remains of the fire according to applicable regulations. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. H335 Normal value for fresh water sediment May cause respiratory irritation. 266700 mg/kg 10.3. Possibility of hazardous reactions. Identification. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS OMOPOLIMERO DI ESAMETILENE - 1,6 - DIISOCIANATO The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 2-METHOXY-1-METHYLETHYL ACETATE H317 x = Conc. %. May cause an allergic skin reaction. Classification

2.1 Classification of the substance or mixture

14.6. Special precautions for user. Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with LD50 (Oral). Partition coefficient: n-octanol/water. Normal value for marine water sediment 1,2 > 2500 mg/kg Rat, female 26670 mg/kg the duration and type of use. H336 Normal value for the terrestrial compartment May cause drowsiness or dizziness. 53182 mg/kg OMOPOLIMERO DI ESAMETILENE - 1,6 - DIISOCIANATO self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). LD50 (Dermal). SKIN PROTECTION The vapours may also form explosive mixtures with the air. H411 Toxic to aquatic life with long lasting effects. > 2000 mg/kg Rat The product is classified as hazardous pursuant to the provisions set forth in EC Regulation

Special Provisions

640E 3,6 Effects on workers with soap and water after removing protective clothing. 2-METHOXY-1-METHYLETHYL ACETATE subsequent amendments. IMDG:

Principle Routes of Exposure

Acute local Acute EMS: F-E, S-E Chronic Limited Quantities: 5 L Chronic Acute local Acute Chronic SECTION 6. Accidental release measures. Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. SKIN CORROSION / IRRITATION. INDEX. May react violently with: oxidising substances,strong acids,alkaline metals. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. IATA: Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Does not meet the classification criteria for this hazard class. Reg. no. 01-2119485796-17-0000 Cargo: systemic local Maximum quantity: 220 L systemic Packaging instructions: 366 local systemic 6.1. Personal precautions, protective equipment and emergency procedures. 12.4. Mobility in soil. EYE PROTECTION LEGEND: Hydrocarbons, C9, Aromatics Inhalation. Pass.: 102,34 Maximum quantity: 60 L 102,34 Packaging instructions: 355 480 Wear airtight protective goggles (see standard EN 166). XYLENE (MIXTURE OF ISOMERS) - ADR: European Agreement concerning the carriage of Dangerous goods by Road Hazard classification and indication: Block the leakage if there is no hazard. Hazard classification and indication: Special Instructions: mg/m3 A3, A72, A192 mg/m3 RESPIRATORY PROTECTION SERIOUS EYE DAMAGE / IRRITATION. XYLENE (MIXTURE OF ISOMERS) - CAS NUMBER: Chemical Abstract Service Number CAS. Stable in normal conditions of use and storage.Reacts violently with: strong oxidants,strong acids,nitric acid,perchlorates.May form 20 ≤ x < 25 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Does not meet the classification criteria for this hazard class. Flammable liquid, category 3 Aquatic Chronic 2 H411 H226 Flammable liquid and vapour. If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type Partition coefficient: soil/water. - CE50: Effective concentration (required to induce a 50% effect) any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Changes to previous review: explosive mixtures with: air. 2,73 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code. EC. Acute toxicity, category 4 918-668-5 H332 Harmful if inhaled. A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases - CE NUMBER: Identifier in ESIS (European archive of existing substances) procedures. The following sections were modified: Aspiration hazard, category 1 H304 May be fatal if swallowed and enters airways. ETHYLBENZENE RESPIRATORY OR SKIN SENSITISATION. Hydrocarbons, C9, Aromatics - CLP: EC Regulation 1272/2008 02 / 03 / 11. INDEX. or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Specific target organ toxicity - single exposure, category 3 H335 May cause respiratory irritation. Sensitising for the skin. Information not relevant. Partition coefficient: soil/water. - DNEL: Derived No Effect Level Reg. no. 01-2119455851-35 Reacts violently with strong oxidants.Attacks various types of plastic materials.May form explosive mixtures with air 2-METHOXY-1-METHYLETHYL ACETATE 1,78 Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the Threshold Limit Value. 2-METHOXY-1-METHYLETHYL ACETATE Skin sensitization, category 1 H317 May cause an allergic skin reaction. - EmS: Emergency Schedule threshold values considered. The protection provided by masks is in any case limited. GERM CELL MUTAGENICITY. CAS. Type Specific target organ toxicity - single exposure, category 3 H336 108-65-6 Country 10 ≤ x < 20 TWA/8h Flam. Liq. 3 H226 STEL/15min May cause drowsiness or dizziness. 10.4. Conditions to avoid. 12.5. Results of PBT and vPvB assessment.