P304+P340

Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

CAS PORTLAND CEMENT [Cr(VI) < 2 ppm] Text of hazard (H) indications mentioned in section 2-3 of the sheet: 1305-62-0 10 ≤ x < 15 mg/m3 ppm Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 mg/m3 ppm The product must not penetrate into the sewer system or come into contact with surface water or ground water. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the WEL GBR 4 EC Incompatible with: acids,ammonium salts,aluminium. 215-137-3 REPRODUCTIVE TOXICITY (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. suitability and thoroughness of provided information according to each specific use of the product. MAC NLD 10

2.1 Classification of the substance or mixture

9.1. Information on basic physical and chemical properties INDEX Eye Dam. 1 Serious eye damage, category 1 6.3. Methods and material for containment and cleaning up This document must not be regarded as a guarantee on any specific product property. Reg. no. 01-2119475151-45-0041 10.6. Hazardous decomposition products

UN Number

Does not meet the classification criteria for this hazard class The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Skin Irrit. 2 Skin irritation, category 2 The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments PORTLAND CEMENT [Cr(VI) < 2 ppm] Appearance The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments STOT SE 3 Specific target organ toxicity - single exposure, category 3 powder Collect the leaked product and place it in containers for recovery or disposal. If there are no contraindications, use jets of water to eliminate and safety laws and regulations. The producer is relieved from any liability arising from improper uses. and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. CAS Colour and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. 65997-15-1 5 ≤ x < 7 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317, white CALCIUM HYDROXIDE In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. STOT - SINGLE EXPOSURE product residues. Not applicable Provide appointed staff with adequate training on how to use chemical products. Skin Sens. 1B Skin sensitization, category 1B Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Threshold Limit Value Odour Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. H318 Causes serious eye damage. Classification note according to Annex VI to the CLP Regulation: 1 characteristic Make sure the leakage site is well aired. Evaluate the compatibility of the container to be used, by checking section 10. Contaminated material EC Odour threshold Type 266-043-4 Country TWA/8h Not available STEL/15min CALCIUM CARBONATE should be disposed of in compliance with the provisions set forth in point 13. May cause respiratory irritation Changes to previous review: H315 Causes skin irritation. 14.2. UN proper shipping name Hazard classification and indication: INDEX pH Hazard classification and indication: May develop: calcium oxides,carbon oxides. H335 May cause respiratory irritation. mg/m3 ppm Not available mg/m3 ppm The following sections were modified: Reg. no. Melting point / freezing point Serious eye damage, category 1 MAK Serious eye damage, category 1 02-2119682167-31 DEU 1 Not available 2 H318 Causes serious eye damage. INHAL Causes serious eye damage. STOT - REPEATED EXPOSURE Not applicable 01 / 02 / 03 / 04 / 07 / 08 / 09 / 10 / 11 / 12 / 14 / 15. H317 May cause an allergic skin reaction. 6.4. Reference to other sections Initial boiling point Skin irritation, category 2 VLA Skin irritation, category 2 ESP 5 Not available H315 Causes skin irritation.

TOXICOLOGICAL INFORMATION

Changed TLVs in section 8.1 for following countries: The full wording of hazard (H) phrases is given in section 16 of the sheet. Boiling range Specific target organ toxicity - single exposure, VLEP Specific target organ toxicity - single exposure, FRA 5 Not available H335 May cause respiratory irritation. 14.3. Transport hazard class(es) Any information on personal protection and disposal is given in sections 8 and 13. Does not meet the classification criteria for this hazard class DEU, category 3 Flash point WEL category 3 GBR 5 Not available LEGEND: In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it QUARTZ Evaporation rate - ADR: European Agreement concerning the carriage of Dangerous goods by Road Skin sensitization, category 1B MAC Skin sensitization, category 1B NLD 5 Not available H317 May cause an allergic skin reaction. contains, using the criteria specified in the applicable regulation for classification.

Aspiration hazard

The product contains less than 1% w/w RCS (respirable crystalline silica). The product does not require classification and labelling as Flammability (solid, gas) Not applicable OEL EU 1 Not available 4 SECTION 7. Handling and storage - CAS NUMBER: Chemical Abstract Service Number RESP It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the

2.2 Label elements

hazardous according to Regulation (EC) No. 1272/2008, as amended. Lower inflammability limit - CE50: Effective concentration (required to induce a 50% effect) toxicological effects of exposure to the product. Does not meet the classification criteria for this hazard class TLV-ACGIH 5 Not available 7.1. Precautions for safe handling 14.4. Packing group Predicted no-effect concentration - PNEC Upper inflammability limit - CE NUMBER: Identifier in ESIS (European archive of existing substances) Not available Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Lower explosive limit - CLP: EC Regulation 1272/2008 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Normal value in fresh water Not available 11.1. Information on toxicological effects