P302+P352

Hazard statements (CLP)

H315, H317, H318, H335

Code

Statements

H315

Causes skin irritation

Further information

EC Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body CARCINOGENICITY 215-279-6 DOLOMITE 10.5. Incompatible materials SECTION 14. Transport information INDEX Threshold Limit Value

2.1 Classification of the substance or mixture

with soap and water after removing protective clothing. Note for users: SECTION 6. Accidental release measures DOLOMITE Text of hazard (H) indications mentioned in section 2-3 of the sheet: EYE PROTECTION Does not meet the classification criteria for this hazard class The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Type Country TWA/8h STEL/15min CAS NATURAL QUICK SETTING CEMENT 16389-88-1 30 ≤ x < 40 mg/m3 ppm Substance with a community workplace exposure limit. mg/m3 ppm 6.1. Personal precautions, protective equipment and emergency procedures Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166). (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. suitability and thoroughness of provided information according to each specific use of the product. The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments EC The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments OEL Incompatible with: acids,ammonium salts,aluminium. Eye Dam. 1 240-440-2 EU Serious eye damage, category 1 10 REPRODUCTIVE TOXICITY RESPIRATORY PROTECTION This document must not be regarded as a guarantee on any specific product property. and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. INDEX and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Skin Irrit. 2 Skin irritation, category 2

UN Number

Use a type P filtering facemask, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. If there are no contraindications, spray powder with water to prevent the formation of dust. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. 10.6. Hazardous decomposition products NATURAL HYDRAULIC LIME STOT SE 3 Specific target organ toxicity - single exposure, category 3 (see standard EN 149). Does not meet the classification criteria for this hazard class and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent CAS Skin Sens. 1B 85117-09-5 14 ≤ x < 19 Skin sensitization, category 1B Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 NATURAL HYDRAULIC LIME ENVIRONMENTAL EXPOSURE CONTROLS Not applicable Provide appointed staff with adequate training on how to use chemical products. any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Hazard classification and indication: EC Hazard classification and indication: Threshold Limit Value Information not available H318 285-561-1 Causes serious eye damage. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure STOT - SINGLE EXPOSURE procedures. INDEX Serious eye damage, category 1 Type H315 Country Causes skin irritation. TWA/8h STEL/15min H318 Causes serious eye damage. 14.2. UN proper shipping name compliance with environmental standards. Changes to previous review: Reg. no. Skin irritation, category 2 05-2116476756-0000 H315 Causes skin irritation. May cause respiratory irritation The following sections were modified: H335 May cause respiratory irritation. mg/m3 ppm mg/m3 ppm 6.2. Environmental precautions

TOXICOLOGICAL INFORMATION

NATURAL QUICK SETTING CEMENT Specific target organ toxicity - single exposure, H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. Not applicable 01 / 03. VLEP FRA 1 RESP CAS category 3 65997-15-1 7 ≤ x < 9 Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335, Skin Sens. 1B H317 Health - Derived no-effect level - DNEL / DMEL In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it STOT - REPEATED EXPOSURE SECTION 9. Physical and chemical properties EC The product must not penetrate into the sewer system or come into contact with surface water or ground water. Skin sensitization, category 1B 266-043-4 H317 May cause an allergic skin reaction. 14.3. Transport hazard class(es) contains, using the criteria specified in the applicable regulation for classification. Effects on consumers Effects on workers INDEX LEGEND:

Principle Routes of Exposure

Acute Chronic Acute local Acute Chronic It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Does not meet the classification criteria for this hazard class

2.2 Label elements

6.3. Methods and material for containment and cleaning up - ADR: European Agreement concerning the carriage of Dangerous goods by Road local systemic local systemic local systemic 9.1. Information on basic physical and chemical properties toxicological effects of exposure to the product. Not applicable The full wording of hazard (H) phrases is given in section 16 of the sheet. - CAS NUMBER: Chemical Abstract Service Number

Aspiration hazard

Inhalation 1 Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Collect the leaked product and place it in containers for recovery or disposal. If there are no contraindications, use jets of water to eliminate Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. - CE50: Effective concentration (required to induce a 50% effect) 11.1. Information on toxicological effects mg/m3 14.4. Packing group NATURAL QUICK SETTING CEMENT product residues. Appearance - CE NUMBER: Identifier in ESIS (European archive of existing substances) powder Does not meet the classification criteria for this hazard class Colour beige Hazard pictograms: Natural quick setting cement, that sets and hardens quickly, is produced exclusively by cooking argillaceous limestone of regular composition Make sure the leakage site is well aired. Evaluate the compatibility of the container to be used, by checking section 10. Contaminated material - CLP: EC Regulation 1272/2008 Hazard pictograms: Metabolism, toxicokinetics, mechanism of action and other information at moderate temperature (1000 to 1200 °C), extracted from homogenous beds and subject to very fine milling. It is composed mainly of should be disposed of in compliance with the provisions set forth in point 13. Odour Not applicable characteristic - DNEL: Derived No Effect Level SECTION 12. Ecological information tricalcium silicate (3CaO.SiO2 ) (CAS 12168-85- 3, EINECS 235-336-9), dicalcium silicate (2CaO.SiO2) (CAS 10034-77-2, EINECS Odour threshold - EmS: Emergency Schedule Not applicable 14.5. Environmental hazards Information not available 233-107-8), tricalcium aluminate (3CaO.Al2O3) (CAS 12042-78-3, EINECS 234-932-6) and calcium ferroaluminate (4CaO.Al2O3.Fe2O3) pH Not available 6.4. Reference to other sections - GHS: Globally Harmonized System of classification and labeling of chemicals CAS 12068-35-8, EINECS 235-094-4), calcite (CaCO3) (CAS 471-31-1, EINECS 207-439-9), de spurrite (Ca5(SiO4)2(CO3)) (CAS Melting point / freezing point Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or - IATA DGR: International Air Transport Association Dangerous Goods Regulation Not available