None

Hazard statements (CLP)

H410

Code

Statements

H410

Very toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

1272/2008 None in particular. However the usual precautions used for chemical products should be respected. EUH210 HAND PROTECTION Not applicable. H410 Safety data sheet available on request. Very toxic to aquatic life with long lasting effects. Protect hands with category III work gloves (see standard EN 374).

2.1 Classification of the substance or mixture

14.4. Packing group. SECTION 5. Firefighting measures. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 10.5. Incompatible materials. 5.1. Extinguishing media. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Information not available. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). the duration and type of use. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Not applicable. SUITABLE EXTINGUISHING EQUIPMENT However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data LEGEND: SKIN PROTECTION However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data 10.6. Hazardous decomposition products. The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments. - ADR: European Agreement concerning the carriage of Dangerous goods by Road Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments.

Environmental hazards

UNSUITABLE EXTINGUISHING EQUIPMENT Information not available. - CAS NUMBER: Chemical Abstract Service Number with soap and water after removing protective clothing. None in particular. Hazard classification and indication: - CE50: Effective concentration (required to induce a 50% effect) EYE PROTECTION Hazard classification and indication: -- Not applicable. - CE NUMBER: Identifier in ESIS (European archive of existing substances) Wear airtight protective goggles (see standard EN 166). 5.2. Special hazards arising from the substance or mixture.

TOXICOLOGICAL INFORMATION

RESPIRATORY PROTECTION - CLP: EC Regulation 1272/2008 14.6. Special precautions for user. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type - DNEL: Derived No Effect Level 11.1. Information on toxicological effects. Do not breathe combustion products.

Hazard pictograms

EmS: Emergency Schedule B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it -- Not applicable. - GHS: Globally Harmonized System of classification and labeling of chemicals or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. contains, using the criteria specified in the applicable regulation for classification. 5.3. Advice for firefighters.

Signal word

IATA DGR: International Air Transport Association Dangerous Goods Regulation Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the -- 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. GENERAL INFORMATION - IC50: Immobilization Concentration 50% threshold values considered. The protection provided by masks is in any case limited. toxicological effects of exposure to the product.

Hazard statements

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. - IMDG: International Maritime Code for dangerous goods If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Information not relevant. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated - IMO: International Maritime Organization EUH210 emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing This product contains sensitizing substance/s and may cause allergic reactions. Safety data sheet available on request. water used for extinction and the remains of the fire according to applicable regulations. - INDEX NUMBER: Identifier in Annex VI of CLP apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. EUH208

Contains

CMIT/MIT Mixture of 5-chloro-2-methyl-2H- isothiazol-3-one and SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS - LC50: Lethal Concentration 50% ENVIRONMENTAL EXPOSURE CONTROLS. 2-methyl-2H-isothiazol-3-one SECTION 15. Regulatory information.

ECOLOGICAL INFORMATION

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with - LD50: Lethal dose 50% May produce an allergic reaction. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure May produce an allergic reaction. self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). - OEL: Occupational Exposure Level compliance with environmental standards. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil and

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation

Precautionary statements

waterways. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. Please take all the proper - PEC: Predicted environmental Concentration -- SECTION 6. Accidental release measures. SECTION 9. Physical and chemical properties. measures to reduce harmful effects on aquifers. Seveso category. - PEL: Predicted exposure level None.

2.3 Other hazards

6.1. Personal precautions, protective equipment and emergency procedures. - PNEC: Predicted no effect concentration 9.1. Information on basic physical and chemical properties. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. - REACH: EC Regulation 1907/2006 12.1. Toxicity. Block the leakage if there is no hazard. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Appearance None. - RID: Regulation concerning the international transport of dangerous goods by train On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. dense liquid Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent Colour Information not available. - TLV: Threshold Limit Value transparent white any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Odour Substances in Candidate List (Art. 59 REACH). - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. characteristic procedures. Odour threshold. None. - TWA STEL: Short-term exposure limit Not available. EPY 9.1.5 - SDS 1003