CLP) does

Hazard statements (CLP)

H226, H302, H315, H317, H318, H332, H335

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008 European TORGGLER including Parliament is proposed, those S.R.L. generated based on by the ventilation negative conclusive equipment, data. should 6.2. REACH It may Environmental be checked however to cause Reg. 01-2119513215-52-xxxx ensure

Precautionary statements

10.6. Full 13.1. N-[3-(dimethoxymethylsilyl)propyl]ethylenediamine compliance sensitisation Healthcare 10. Hazardous Waste treatment methods Regulation address controls with in decomposition (EU) susceptible environmental 2015/1221 individuals. standards. (VII products Atp. CLP) of N-(3-(trimethoxysilyl)propyl)ethylenediamine the European Via Prati Nuovi Parliament 9 SECTION District Predicted Method: Information 11. Regulation and OECD no-effect use(s) Small Acute local for user amounts of methanol (CAS 67-56-1) are formed by hydrolysis and released upon curing. archive data of sheet Acute existing available Chronic substances) Chronic Information Chemical Information NOT - CLP: rapidly EUH208 and not physical Regulation not degradable available hazards: available

ECOLOGICAL INFORMATION

Country not (EU) 406 available Skin 2016/918 concentration sensitisation, (VIII Atp. - PNEC Buehler CLP) of test the European 39020 Parliament Marlengo (BZ) CAS The product must 3069-29-2 not penetrate into the 0,809 sewer ≤ x < system 0,909 or come Acute into Tox. contact 4 H302, with surface Eye Dam. water 1 H318, or ground Skin water. Irrit. 2 H315, Skin Sens. 1 H317 In CN 12. the Normal EC Reuse, when possible. Regulation code: event Guinea value of thermal (EU) 221-336-6 in Pig fresh 2016/1179 decomposition Neat product residues should be considered water (IX Atp. or CLP) fire, gases and vapours that STA Oral: Italy are potentially dangerous to health 0,062 special 500 non-hazardous mg/kg waste. may be released. mg/l 15.2. Exposure: 6.3. 12.1. INDEX 13. Chemical

Disposal

Methods Toxicity must and be material Normal Regulation dermal value safety (EU) in marine performed 2017/776 assessment for through water (X Atp. CLP) containment an authorised and cleaning waste up management firm, in compliance with national and local regulations. Tel. +39 0473 282400 SECTION 9. Physical and chemical properties Results: 14. Normal Regulation No value sensitisation 0,0062 (EU) for 2018/669 fresh reactions water (XI sediment mg/l Atp. were CLP) observed. Fax +39 0473 282501 0,22 mg/kg/d REACH CONTAMINATED Reg. 01-2119963926-21-xxxx PACKAGING e-mail None A 15. chemical Normal Regulation under address value safety normal (EU) of for the assessment use 2019/521 marine competent conditions. water (XII has person Atp. sediment not Small been CLP) amounts performed of methanol for the preparation/for (CAS 67-56-1) the are substances formed by hydrolysis indicated in 0,022 and section released N-(3-(trimethoxysilyl)propyl)ethylenediamine Collect Contaminated 3. mg/kg/d upon curing. the leaked packaging product must into a be suitable recovered container. or disposed Evaluate of in the compliance compatibility with of national the container waste management to be used, by regulations. checking section 10. Absorb the responsible 16. Normal Delegated value for Regulation the for Safety water, (UE) Data intermittent 2018/1480 Sheet release (XIII Atp. CLP) reach@torggler.com 0,62 9.1. CAS remainder N-(3-(trimethoxysilyl)propyl)ethylenediamine Information mg/l with on inert 1760-24-3 basic absorbent physical material. and 0,809 chemical ≤ x < 0,909 properties Acute Tox. 4 H332, Eye Dam. 1 H318, STOT SE 3 H335, Skin Sens. 1 H317 Respiratory 17. Normal Regulation value sensitization (EU) of STP 2019/1148 microorganisms 1.4. SECTION SECTION EC Make LC50 sure 18. Normal Emergency 11. Delegated - for Fish the leakage value 16. Toxicological 14. telephone Regulation 217-164-6 liquid, in and section category is characteristic other given 16 35 information 3 in of mg/l sections the Daphnia sheet. 8 and magna Chronic 13. Acute local Acute Chronic 22. Delegated Regulation (UE) Odour Chronic Acute threshold NOEC for 4 Algae / Aquatic local 2022/692 systemic Acute Plants toxicity, category (XVIII Atp. CLP) local

Further information

for Transport the terrestrial site is well aired. Contaminated material number (UE) 2020/217 information compartment 25 information (XIV Atp. CLP) mg/l 597 STA mg/l/96h should Inhalation Danio be disposed vapours: rerio of in 11 compliance mg/l with the provisions set forth in point 13. 0,0085 mg/kg/d INDEX Properties EC50 - for Crustacea Value 81 mg/l/48h Daphnia magna Information 6.4. 11.1. REACH Health Information 19. Delegated Appearance EC50 Text Reference Information of - for - Derived Reg. Algae not Regulation to (H) on available 01-2119970215-39-xxxx other / Aquatic no-effect (UE) indications sections Plants classes level 2020/1182 mentioned - DNEL / (XV DMEL as defined in section Atp. CLP) in Regulation 2-3 pasty of the 8,8 liquid sheet: mg/l/72h (EC) No Desmodesmus

UN Number

or ID number SECTION not 4 applicable Tox. 2. Hazards 1,6 mg/l Pseudokirchnerella subcapitata systemic identification systemic local systemic Information Melting Information Oral Eye point Dam. not not available / 1 freezing available point Serious eye damage, not category available 1 2,5 2.1. SECTION - The Initial Trimethoxyvinylsilane Classification Skin Merck 4. 7. Index boiling Irrit. point of - the First Handling 10th aid substance Edition measures and Skin or storage irritation, mixture category not 2 available mg/kg bw/d not applicable GERM Handling Inhalation CELL Chemical MUTAGENICITY Safety 8,7 35,5 7.1. Description Flammability Information LC50 STOT Precautions of for first for SE Fish on 3 likely routes of exposure safe aid handling measures Specific target organ not toxicity applicable 191 - mg/l/96h single exposure, Oncorhyncus category mykiss The INRS Lower EC50 Skin product explosive Fiche for Sens Crustacea is Toxicologique not limit classified as toxicological hazardous sheet) Skin sensitization, pursuant category to not the available 168,7 provisions mg/l/48h set mg/m3 Daphnia forth in EC magna

Hazard pictograms

TOXICITY NOEC for Algae / Aquatic Plants effects value must on for sexual water, not be function intermittent regarded and -- as release fertility a guarantee on any specific product property. not applicable 3,1 mg/l 0,62 Specific information on symptoms and effects caused by the product are unknown. The Normal mg/l use of value this product of STP is microorganisms not subject to our direct control; therefore, users must, under their own responsibility, 25 comply mg/l with the current health 14.5. Protect - ADR: European Agreement concerning the carriage of Dangerous goods by Road

Environmental hazards

against moisture. Store at a temperature between +10 and +35 °C. Store away from food or feed and beverages. 9.2. 12.2. ATE Signal Information and Normal - ATE: Other Persistence safety (Inhalation Acute words: information laws value not available Toxicity and - and for the vapours) regulations. Estimate degradability terrestrial The compartment of the mixture: -- producer is relieved from any liability arising from improper uses. > 20 mg/l 0,01 4.3. Indication of any immediate medical attention and special treatment needed Health Provide - appointed mg/kg/d Derived no-effect staff with level adequate - DNEL training / DMEL on how to use chemical products. ATE - CAS: (Oral) Storage class TRGS 510 (Germany): not applicable Chemical of the Abstract mixture: Service Number 10 Not classified (no significant component) Adverse

Hazard statements

effects on development Effects of on the consumers offspring 9.2.1. ATE - CE50: (Dermal) Information Effective of the concentration with mixture: Effects on workers regard to (required physical to hazard induce classes a 50% effect) Not classified (no significant component) CALCULATION information Maritime not available and -- reactivity Code for dangerous goods The Changes - IMO: International extinguishing LD50 (Oral): Maritime Organization to previous equipment review should be of the conventional kind carbon dioxide, foam, powder and water spray 2295 mg/kg bw Rat 10.1. Reactivity UNSUITABLE VND Does The following = not hazard meet sections EXTINGUISHING identified were but modified: no DNEL/PNEC criteria EQUIPMENT for this available

Principle Routes of Exposure

METHODS Acute FOR CLASSIFICATION Acute Chronic on request. 7.3. 14.6. Treat N-(3-(trimethoxysilyl)propyl)ethylenediamine - CE: EUH210 Specific Special Chronic Identifier in ESIS (European Safety symptomatically. end

2.1 Classification of the substance or mixture

Irrit. point 2 of - the First Handling 10th aid substance Edition measures and Skin or storage irritation, mixture category not 2 available mg/kg bw/d not applicable GERM - Handling Inhalation CELL Chemical MUTAGENICITY Safety 8,7 35,5 4.1. 7.1. Description Flammability Information LC50 STOT Precautions of for first - for SE Fish on 3 likely routes of exposure safe aid handling measures Specific target organ not toxicity applicable 191 - mg/l/96h single exposure, Oncorhyncus category mykiss 3 The - INRS Lower EC50 Skin product - explosive - Fiche for Sens. Crustacea is Toxicologique not 1 limit classified as (toxicological hazardous sheet) Skin sensitization, pursuant category to not the available 168,7 provisions 1 mg/l/48h set mg/m3 Daphnia forth in EC magna Regulation 1272/2008 (CLP). 14.2. UN proper shipping name Does - Patty Skin not - Industrial meet mg/m3 classification Toxicology for this hazard class 2,5 However, Upper Information EC50 H226 - explosive for Algae since the the Hygiene not available limit / Aquatic Plants Flammable liquid and not vapour. product and contains criteria hazardous substances available 957 in mg/l/72h concentrations Desmodesmus such as subspicatus to be declared in section no. 3, it requires a safety data EYES: Keep away - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition mg/kg bw/d Remove from heat, contact sparks lenses, and naked if present. flames; Wash do not immediately smoke or use with matches plenty of or lighters. water for Without at least adequate 30-60 minutes, ventilation, sheet Flash Chronic H302 opening with point NOEC vapours appropriate the may for Fish information, eyelids fully. Get Harmful compliant if swallowed. to > (EU) 60 Regulation 100 °C mg/l 2020/878. Oncorhynchus mykiss medical accumulate CARCINOGENICITY not - IFA applicable GESTIS advice/attention. at website ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Auto-ignition Delayed Chronic SKIN: Do H332 NOEC not Remove eat, and temperature drink contaminated immediate for Crustacea or smoke during effects as Harmful clothing. well as if chronic use. Rinse Remove inhaled. effects skin any with contaminated not available a shower immediately. from 1 mg/l short Daphnia clothes and Get personal and long-term magna exposure medical protective advice/attention. equipment before entering places in which - ECHA Hazard website 14.3. INGESTION: pH H318 classification and indication: people Transport eat. Avoid hazard Have leakage the class(es) subject of the product Causes serious -- eye not drink as into much the environment. water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly damage. applicable Reason for missing data:not soluble in water Does - Database Kinematic Information N-[3-(dimethoxymethylsilyl)propyl]ethylenediamine H315 not meet viscosity of SDS not available the classification models for chemicals Causes skin irritation. >20,5 mm2/sec (40°C) criteria for - this Ministry N-[3-(dimethoxymethylsilyl)propyl]ethylenediamine hazard of Health class and ISS (Istituto Superiore di Sanità) - Italy authorised by a doctor. Predicted no-effect concentration - PNEC 7.2. INHALATION: Solubility LC50 H335 not Conditions applicable for Get safe medical - for Fish storage, advice/attention May cause respiratory immiscible including any immediately. incompatibilities irritation. 597 mg/l/96h Remove victim to fresh air, away from the accident scene. If the subject stops with water Danio rerio (read-across from CAS 1760-24-3) 2.2. REPRODUCTIVE Partition Interactive EC50 H317 Label Normal - for coefficient: elements effects Crustacea n-octanol/water value in TOXICITY fresh water May cause an allergic not skin available > reaction. 100 mg/l/48h Daphnia magna 0,062 mg/l breathing, administer artificial respiration. Take suitable precautions for rescue workers. Note Normal for users: value in marine water 0,0062 mg/l 14.4. Store Vapour EC50 EUH210 Packing - for pressure only in group Algae / Aquatic Plants Safety data sheet available the original container. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks not available 8,8 on mg/l/72h request. Pseudokirchneriella subcapitata Hazard Does The Normal Density Information Chronic and/or information not labelling NOEC meet

Health hazards

on or via lactation not available Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section mg/kg bw/d SECTION 9.2.2. Trimethoxyvinylsilane - EmS: Other Emergency LD50 5. safety (Oral): Firefighting characteristics Schedule measures Trimethoxyvinylsilane 7120 mg/kg bw Rat 11. Inhalation NOT - GHS: rapidly Globally LD50 degradable (Dermal): Harmonized System of classification and labeling May produce an allergic reaction. 3540 of µg/kg chemicals 2,9 Otyctolagus cuniculus 14.7. Maritime transport in bulk according to IMO instruments 5.1. Information Environmental Extinguishing not hazards: available media Product classification is based on calculation methods mg/m3 as per Annex I of CLP, Part 4, unless determined otherwise in SECTION Kinematic - IATA DGR: LC50 viscosity 8. International (Inhalation Exposure (40 °C) vapours): Air Transport controls/personal Association Dangerous >0,5 protection m2/s 16,8 Goods mg/l/4h Regulation Rat Section - N-[3-(dimethoxymethylsilyl)propyl]ethylenediamine IC50: Immobilization Concentration 50% Skin 12. 0,83 8.1. SECTION Information not relevant SUITABLE STOT Control - SINGLE parameters EXTINGUISHING EXPOSURE Stability EQUIPMENT mg/kg bw/d Precautionary Degradability: - IMDG: N-(3-(trimethoxysilyl)propyl)ethylenediamine International

Hazard categories

; NEA = no exposure expected ; NPI = no hazard identified ; LOW = low hazard 12.3. SECTION - INDEX: Bioaccumulative LD50 Identifier 15. (Dermal): Regulatory in Annex potential VI of CLP information > 2000 mg/kg bw Rat None Small ; 07 MED - LC50: LC50 / 08 in amounts / = particular. Lethal (Inhalation 11 medium / 12 of / 15. Concentration methanol hazard ; (CAS vapours): 50% HIGH 67-56-1) = high hazard. are formed by hydrolysis and released upon curing 1,49 mg/l Rat (aerosol 4h) There are no particular risks of reaction with other substances in normal conditions of use. Target organs 2.3. Methanol - LD50: Other STA Lethal CAS 67-56-1) (EU) TWA 200 ppm (Inhalation dose 50% vapours): 11 mg/l estimate from table 3.1.2 of Annex I of the CLP 5.2. 8.2. 15.1. Special Trimethoxyvinylsilane - OEL: Occupational Exposure Level Exposure Safety, hazards health controls and arising environmental from the substance regulations/legislation or mixture (figure used for calculation of the acute toxicity estimate of the mixture) specific for the substance or mixture Information not available On basis of available product not contain Partition

PBT Substances

Product cures with moisture. the Persistent coefficient: in percentage bioaccumulative n-octanol/water ≥ than 0,1%. data, the and toxic does as REACH Regulation 1,1 any Log PBT Kow or 20 vPvB °C - pH 7 As Seveso - PEC: Predicted the use Category N-[3-(dimethoxymethylsilyl)propyl]ethylenediamine CAUSED of adequate environmental Concentration - Directive BY technical EXPOSURE 2012/18/EU: equipment IN THE must EVENT always OF FIRE take priority over None personal protective equipment, make sure that the workplace is 12.4. - PEL: The Do well Route Mobility not product aired of breathe Predicted LD50 in (Oral): exposure through does combustion soil exposure level not effective

Contains

local products. substances aspiration. with endocrine disrupting 200 mg/kg properties Rat in concentration ≥ 0.1%. 10.2. Chemical stability When Restrictions choosing relating personal to the protective product or equipment, contained ask substances your chemical pursuant substance to Annex supplier XVII to for EC advice.