WATTYL ULTRA CEILING HIGH OPACITY WHITE

Hazard statements (CLP)

H227, H373

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

HSNO Classification FLAMMABLE LIQUIDS - Category 4 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 This material is classified as hazardous according to criteria in the Hazardous Substances (Hazard Classification) Notice 2020 This material is not classified as DANGEROUS GOODS according to criteria in New Zealand Standard 5433:2012 Transport of Dangerous Goods on Land

Signal word

Warning

Hazard statements

Combustible liquid. May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not breathe vapor.

Response

Get medical advice or attention if you feel unwell.

Storage

Not applicable.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Please refer to the SDS for additional information. Keep out of reach of children.

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 4 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 This material is classified as hazardous according to criteria in the Hazardous Substances (Hazard Classification) Notice 2020. This material is not classified as DANGEROUS GOODS according to criteria in New Zealand Standard 5433:2012 Transport of Dangerous Goods on Land. GHS label elements Signal word : Warning Hazard statements : Combustible liquid. May cause damage to organs through prolonged or repeated exposure. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not breathe vapor. Response : Get medical advice or attention if you feel unwell. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Symbol : Other hazards which do not : Please refer to the SDS for additional information. Keep out of reach of children. result in classification Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : Not available. identification CAS number/other identifiers Product code : 43151109 Ingredient name % (w/w) CAS number Titanium Dioxide 15.3 13463-67-7 Calcium Carbonate 9.9 1317-65-3 Perlite 2.4 93763-70-3 Cristobalite, respirable powder 2.0 14464-46-1 Amorphous Silica 1.8 7631-86-9 Attapulgite Clay 0.7 12174-11-7 Crystalline Silica, respirable powder 0.1 14808-60-7 2-Methyl-4-isothiazolin-3-one 0.0 2682-20-4 5-Chloro-2-methylisothiazolinone 0.0 26172-55-4 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if feeling unwell. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse. Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Most important symptoms/effects, acute and delayed Potential acute health effects Inhalation : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Eye contact : No known significant effects or critical hazards. Over-exposure signs/symptoms Inhalation : No specific data. Section 4. First aid measures Ingestion : No specific data. Skin : No specific data. Eyes : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Specific treatments : No specific treatment. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable : Use dry chemical, CO₂, water spray (fog) or foam. Not suitable : Do not use water jet. Specific hazards arising : Combustible liquid. Runoff to sewer may create fire or explosion hazard. In a fire or from the chemical if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide metal oxide/oxides Hazchem code : Not available. Special precautions for fire- : Promptly isolate the scene by removing all persons from the vicinity of the incident if fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Section 6. Accidental release measures Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved including any area. Store in original container protected from direct sunlight in a dry, cool and well- incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Titanium Dioxide NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 10 mg/m³ 8 hours. Form: The value for inhalable dust containing no asbestos and less than 1% free silica. Calcium Carbonate NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 10 mg/m³ 8 hours. Perlite NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 10 mg/m³ 8 hours. Cristobalite, respirable powder NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 0.05 mg/m³ 8 hours. Form: The value for respirable dust. WES-TWA: 10 mg/m³ 8 hours. Section 8. Exposure controls/personal protection Amorphous Silica NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 10 mg/m³ 8 hours. Crystalline Silica, respirable powder NZ HSWA 2015 - GRWM 2016 (New Zealand, 11/2020). WES-TWA: 0.05 mg/m³ 8 hours. Form: The value for respirable dust. WES-TWA: 10 mg/m³ 8 hours. Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and chemical properties The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Appearance Physical state : Liquid. Color : Not available. Odor : Not available. Odor threshold : Not available. Section 9. Physical and chemical properties The pH conditions of measurement of : 8.4 all properties are at standard temperature and pressure unless otherwise indicated. Melting point/freezing point : Not available. Boiling point, initial boiling : 100°C (212°F) point, and boiling range Flash point : Closed cup: 84°C (183.2°F) [Pensky-Martens Closed Cup] Evaporation rate