T&l SPR MF RED 120Z 6UC

Hazard statements (CLP)

H317, H319, H336

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

OSHA Serious eye damage/eye irritation Category 2 Skin sensitization Category 1A Carcinogenicity Category 2 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Flammable aerosols Category 2 Gases under pressure Liquefied gas

2.2 Label elements

Product Code 018.5339-02.076 Page 1/9

Signal word

WARNING

Hazard statements

Flammable aerosol Contains gas under pressure; may explode if heated Causes serious eye irritation May cause an allergic skin reaction Suspected of causing cancer Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing should not be allowed out of the workplace. Use only outdoors or in a well-ventilated area. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.

Response

IF exposed or concerned: Get medical advice/attention. Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Storage

Store locked up. Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Protect from sunlight. Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Protect from sunlight. Store in a well-ventilated place. Incompatible materials Strong oxidizing agents. Control parameters Exposure Limits lf S* appears in the OEL table, it indicates this chemical contains a skin notation. Chemical Name ACGIH TLV

Disposal

Dispose of contents/containers in accordance with local regulations.

2.3 Other hazards

No information available.

Other hazards

Propellant is classified as a simple asphyxiant if released in large quantities: May displace oxygen and cause rapid suffocation. Not applicable. UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity. Chemical Name CAS No | weight-% g! Product Code 018.5339-02.076 Page 2/9 Acetone 67-64-1 25 - 50 Propane 74-98-6 10 - 25 n-Butyl acetate 123-86-4 5-10 Ethylene glycol monopropyl ether 2807-30-9 3-5 Titanium dioxide 13463-67-7 0.1-0.3 Zirconium ethyl hexoate 22464-99-9 0.1-0.3 Hexanoic acid, 2-ethyl-, cobalt(2+) salt (2:1) 136-52-7 0.1 - 0.3 *The exact percentage (concentration) of composition has been withheld as a trade secret. First Aid Measures General advice IF exposed or concerned: Get medical advice/attention. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Dry chemical, CO2, water spray or alcohol-resistant foam. Not to be used for safety reasons: Strong water jet Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes. May cause sensitization by skin contact. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid breathing vapors or mists. Remove all sources of ignition. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. For emergency responders Product Code 018.5339-02.076 Use personal protection recommended in Section 8. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Take up mechanically, placing in appropriate containers for disposal. Pick up and transfer to properly labeled containers. Precautions for safe handling Advice on safe handling Prevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the occupational exposure limits. Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. General Hygiene Considerations Avoid contact with skin, eyes or clothing. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities

Contains

TWA: 1800 mg/m? n-Butyl acetate STEL: 150 ppm TWA: 150 ppm IDLH: 1700 ppm 123-86-4 TWA: 50 ppm TWA: 710 mg/ms TWA: 150 ppm TWA: 710 mg/m STEL: 200 ppm STEL: 950 mg/m? Titanium dioxide TWA: 10 mg/m? TWA: 15 mg/m? total dust IDLH: 5000 mg/m? 13463-67-7 Zirconium ethyl hexoate STEL: 10 mg/m? Zr TWA: 5 mg/m Zr IDLH: 25 mg/m? Zr 22464-99-9 TWA: 5 mg/m5 Zr TWA: 5 mg/m? except Zirconium tetrachloride Zr Product Code 018.5339-02.076 Page 4/9 L STEL: 10 mg/m? Zr | Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Wear suitable protective clothing. Personnel should wear anti-static clothing made of natural fiber or of high temperature resistant synthetic fiber. Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Thermal Protection © No information available Information on basic physical and chemical properties Physical state Aerosol

Appearance/Odor

No information available Solvent Color red Odor Threshold No information available pH value No information available Melting point/freezing point No information available Boiling point / boiling range No information available °C / °F flash point -35 °C / -31 °F evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor Pressure No information available vapor density No information available Density (Ibs per US gallon) 6.33 specific gravity 16 Solubility(ies) Not Determined Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available

Further information

Product Code 018.5339-02.076 Reactivity No information available. Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Chlorine gas. Information on likely routes of exposure Eye contact Causes serious eye irritation Skin Contact May cause an allergic skin reaction Ingestion Not applicable Inhalation May cause drowsiness or dizziness Numerical measures of toxicity - Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Acetone = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m? ( Rat) 8h 67-64-1 Propane - = 658 mg/L (Rat) 4h 74-98-6 n-Butyl acetate = 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 390 ppm (Rat) 4h 123-86-4 Ethylene glycol monopropyl ether = 3089 mg/kg ( Rat ) = 870 mg/kg ( Rabbit ) = 960 uL/kg = 1530 ppm (Rat) 7h 2807-30-9 ( Rabbit ) Titanium dioxide > 10000 mg/kg ( Rat ) 13463-67-7 Zirconium ethyl hexoate - 22464-99-9 Hexanoic acid, 2-ethyl-, cobalt(2+) - > 5000 mg/kg ( Rabbit ) >10 mg/L (Rat) 1h alt (2:1) 136-52-7 Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (dermal) 29325 Mg/kg ATEmix (inhalation-dust/mist) 13.9 ATEmix (inhalation-vapor) 102 UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints since the pigment is bound to other materials. Chemical Name ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Product Code 01 8.5339-02.076 Page 6/9 AGHS - USA OSHA SDS 13463-67-7 Hexanoic acid, 2-ethyl-, Group 2B X cobalt(2+) salt (2:1) 136-52-7 IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present. Skin corrosion/irritation Not applicable Serious eye damage/eye irritation Causes serious eye irritation Skin sensitization May cause an allergic skin reaction Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Suspected of causing cancer Reproductive Toxicity Suspected of damaging fertility or the unborn child Specific target organ toxicity (single exposure) May cause drowsiness or dizziness Specific target organ toxicity (repeated exposure) Not applicable Aspiration hazard Not applicable Ecotoxicity Environmental precautions Prevent product from entering drains. Persistence and degradability No information available Bioaccumulation No information available Mobility No information available Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned. DOT IMDG IATA 14.1 UN/ID no ORM-D UN1950 14.2 Proper shipping name CONSUMER COMMODITY Aerosols, flammable 14.3 Hazard Class 2.1 14.4 Packing Group 14.5 Environmental hazard 14.6 Special Provisions Emergency Response Guide EmS-No Number F-D, S-U 126 14.7 Transport in bulk according to Annex Il of MARPOL 73/78 and the IBC Code No information available The supplier may apply one of the following exceptions: Combustible Liquid (49 CFR 173.150(f)); Consumer Commodity (49 CFR 173.1 50(c), Product Code 018.5339-02.076 Page 7/9 AGHS - USA OSHA SDS ICAONATA SP A112); Limited Quantity (49 CFR 173.150(b), ICAO Part 3 Chapter 4, IATA 2.7, IMDG Chapter 3.4); Viscous Liquid (49 CFR 173.121(b), IMDG 2.3.2.2, IATA 3.3.3.1.1, ICAO 3.2.2, ADR 2.2.3.1.5); Does Not Sustain Combustion (49 CFR 173.120(a), IATA 3.3.1.3, ICAO 3.1.3, IMDG 2.3.1.3, ADR 2.2.3.1.1 Note 1); or others as allowed under hazardous materials/dangerous goods regulations. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt from listing. DSL - Canadian Domestic Substances List All components are listed or exempt from listing US Federal Regulations Chemical Name SARA 313 - Threshold Values Metals Hazardous air pollutants % (HAPs) content Ethylene glycol monopropyl ether 1 Present 2807-30-9 3-5 Hexanoic acid, 2-ethyl-, cobalt(2+) salt (2:1) 1 Cobalt Present 136-52-7 0.1 -0.3 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard Yes Reactive Hazard No Chemical Name CWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA - Hazardous Quantities