Slop

Hazard statements (CLP)

H224, H304, H315, H332, H336, H340, H350, H361, H373, H411

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Regulation (EC) No 1272/2008 as amended Physical hazards Flammable liquids Category 1 H224 - Extremely flammable liquid and vapour. Health hazards Acute toxicity, inhalation Category 4 H332 - Harmful if inhaled. Skin corrosion/irritation Category 2 H315 - Causes skin irritation. Germ cell mutagenicity Category 1B H340 - May cause genetic defects. Carcinogenicity Category 1B H350 - May cause cancer. Reproductive toxicity Category 2 H361 - Suspected of damaging fertility or the unborn child. Specific target organ toxicity - single Category 3 narcotic effects H336 - May cause drowsiness or exposure dizziness. Specific target organ toxicity - repeated Category 2 (bone marrow, liver, thymus) H373 - May cause damage to exposure organs (bone marrow, liver, thymus) through prolonged or repeated exposure. Aspiration hazard Category 1 H304 - May be fatal if swallowed and enters airways. Environmental hazards Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects. 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Contains: Fuels, diesel, Gasoline, Kerosine (petroleum) Hazard pictograms Signal word Danger Hazard statements H224 Extremely flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs (bone marrow, liver, thymus) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Precautionary statements Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/. Response P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor/. P331 Do NOT induce vomiting. Storage P403 + P235 Store in a well-ventilated place. Keep cool. Disposal Not assigned. Supplemental information on None. the label 2.3. Other hazards Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapour. May cause flash fire or explosion. This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII. SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes Fuels, diesel < 100 68334-30-5 01-2119484664-27-0052 649-224-00-6 269-822-7 Classification: Flam. Liq. 3;H226, Acute Tox. 4;H332, Skin Irrit. 2;H315, Carc. 2;H351, N STOT RE 2;H373, Asp. Tox. 1;H304, Aquatic Chronic 2;H411 Gasoline < 100 86290-81-5 - 649-378-00-4 289-220-8 Classification: Flam. Liq. 1;H224, Skin Irrit. 2;H315, Muta. 1B;H340, Carc. 1B;H350, P Repr. 2;H361, STOT SE 3;H336, Asp. Tox. 1;H304, Aquatic Chronic 2;H411 Kerosine (petroleum) < 100 8008-20-6 01-2119485517-27-0037 649-404-00-4 232-366-4 Classification: Flam. Liq. 3;H226, Skin Irrit. 2;H315, STOT SE 3;H336, Asp. Tox. 1;H304, Aquatic Chronic 2;H411 List of abbreviations and symbols that may be used above #: This substance has workplace exposure limit(s). M: M-factor vPvB: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. Note N - The harmonized classification as a carcinogen does not apply because the full refining history is known and the substance from which it is produced is not a carcinogen. Note P - The harmonized classification as a carcinogen or mutagen does not apply because the substance contains less than 0.1 % w/w of benzene (EINECS No 200-753-7). Composition comments The full text for all H-statements is displayed in section 16. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 4: First aid measures General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 4.1. Description of first aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a poison centre or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control centre immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness or dizziness. and effects, both acute and Headache. Nausea, vomiting. Diarrhoea. Direct contact with eyes may cause temporary irritation. delayed Skin irritation. May cause redness and pain. Jaundice. Prolonged exposure may cause chronic effects. 4.3. Indication of any Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediate medical attention immediately. While flushing, remove clothes which do not adhere to affected area. Call an and special treatment needed ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: Firefighting measures General fire hazards Extremely flammable liquid and vapour. 5.1. Extinguishing media Suitable extinguishing Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may media be used for small fires only. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media 5.2. Special hazards arising Vapours may form explosive mixtures with air. Vapours may travel considerable distance to a from the substance or mixture source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. 5.3. Advice for firefighters Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire. equipment for firefighters Special fire fighting In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective procedures equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. ALWAYS stay away from tanks engulfed in flame. Withdraw immediately in case of rising sound from venting safety device or any discolouration of tanks due to fire. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Remove all possible sources of ignition in the surrounding area. Do not breathe mist/vapours. Do personnel not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not touch or walk through spilled material. For emergency responders Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Remove all possible sources of ignition in the surrounding area. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Ventilate closed spaces before entering them. Avoid breathing mist/vapours. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS. 6.2. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 6.3. Methods and material for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep containment and cleaning up combustibles (wood, paper, oil etc) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. The product is immiscible with water and will spread on the water surface. Prevent entry into waterways, sewer, basements or confined areas. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Put material in suitable, covered, labelled containers. The product is insoluble in water. 6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. sections SECTION 7: Handling and storage 7.1. Precautions for safe Obtain special instructions before use. Do not handle until all safety precautions have been read handling and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist/vapours. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". 7.2. Conditions for safe Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge storage, including any build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid incompatibilities spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see section 10 of the SDS). Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended ANNEX 1, PART 1 Categories of dangerous substances Hazard categories in accordance with Regulation (EC) No 1272/2008 - P5a FLAMMABLE LIQUIDS (Lower-tier requirements = 10 tonnes; Upper-tier requirements = 50 tonnes) - E2 Hazardous to the Aquatic Environment Chronic (Lower-tier requirements = 200 tonnes; Upper-tier requirements = 500 tonnes) 7.3. Specific end use(s) Refinery feedstock. Observe industrial sector guidance on best practices. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring Follow standard monitoring procedures. procedures Derived no effect levels Not available. (DNELs) Predicted no effect Not available. concentrations (PNECs) 8.2. Exposure controls Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation should be used. controls Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower. Individual protection measures, such as personal protective equipment General information Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles. Eye protection should meet standard EN 166. Skin protection - Hand protection Wear appropriate chemical resistant gloves. Viton® or nitrile rubber gloves are recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Wear suitable gloves tested to EN374. - Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Full body suit and boots are recommended when handling large volumes or in emergency situations. Respiratory protection Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. Use respiratory equipment with combination filter, type A2/P2. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Observe any medical surveillance requirements. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental exposure Inform appropriate managerial or supervisory personnel of all environmental releases. Emissions controls from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Fume scrubbers, filters or engineering modifications to the process equipment may be necessary to reduce emissions to acceptable levels. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Liquid. Form Liquid. Colour Colourless. Odour Hydrocarbon. Odour threshold Not available. pH Not determined. Melting point/freezing point Not determined. Initial boiling point and boiling > 25 - < 385 °C (> 77 - < 725 °F) range Flash point -40 °C (-40 °F) (Minimum) Evaporation rate Not determined. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Explosive limit - lower ( %) 0.6 % v/v Explosive limit – upper 7.6 % v/v (%) Vapour pressure Not determined. Vapour density Not determined. Relative density > 0.75 Solubility(ies) Solubility (water) Insoluble. Partition coefficient Not determined. (n-octanol/water) Auto-ignition temperature Not determined. Decomposition temperature Not determined. Viscosity < 7 mm²/s (40°C) Explosive properties Not explosive. Oxidising properties Not oxidising. 9.2. Other information Kinematic viscosity Not determined. SECTION 10: Stability and reactivity 10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Material is stable under normal conditions. 10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions 10.4. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5. Incompatible materials Strong acids. Strong oxidizers such as nitrates, chlorates, peroxides. 10.6. Hazardous No hazardous decomposition products are known. decomposition products SECTION 11: Toxicological information General information Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure Inhalation Harmful if inhaled. May cause drowsiness or dizziness. Headache. Nausea, vomiting. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms Aspiration may cause pulmonary oedema and pneumonitis. May cause drowsiness or dizziness. Headache. Nausea, vomiting. Diarrhoea. Skin irritation. May cause redness and pain. Jaundice. 11.1. Information on toxicological effects Acute toxicity Harmful if inhaled. Components Species Test Results Fuels, diesel (CAS 68334-30-5) Acute Dermal LD50 Rabbit > 4300 mg/kg Inhalation vapour/aerosol LC50 Rat 4.1 mg/l, 4 Hours Oral LD50 Rat > 5000 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory sensitisation Based on available data, the classification criteria are not met. Skin sensitisation Based on available data, the classification criteria are not met. Germ cell mutagenicity May cause genetic defects. Carcinogenicity May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans. Reproductive toxicity Suspected of damaging fertility or the unborn child. Specific target organ toxicity - May cause drowsiness or dizziness. single exposure Specific target organ toxicity - May cause damage to organs (bone marrow, liver, thymus) through prolonged or repeated repeated exposure exposure. Aspiration hazard May be fatal if swallowed and enters airways. Mixture versus substance No information available. information Other information None known. SECTION 12: Ecological information 12.1. Toxicity Toxic to aquatic life with long lasting effects. Components Species Test Results Fuels, diesel (CAS 68334-30-5) Aquatic Acute Algae ErL50 Algae 22 mg/l Crustacea EL50 Daphnia 68 mg/l Fish LL50 Fish 21 mg/l 12.2. Persistence and No data is available on the degradability of this product. degradability 12.3. Bioaccumulative potential No data available. Partition coefficient Not available. n-octanol/water (log Kow) Bioconcentration factor (BCF) Not available. 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB This mixture does not contain substances assessed to be vPvB / PBT according to Regulation assessment

Physical hazards

Flammable liquids Category 1 H224 - Extremely flammable liquid and vapour.

Health hazards

Acute toxicity, inhalation Skin corrosion/irritation Germ cell mutagenicity Category 4 H332 - Harmful if inhaled. Category 2 H315 - Causes skin irritation. Category 1B H340 - May cause genetic defects. Carcinogenicity Category 1B H350 - May cause cancer. Reproductive toxicity Category 2 H361 - Suspected of damaging fertility or the unborn child. Specific target organ toxicity - single Category 3 narcotic effects H336 - May cause drowsiness or exposure dizziness. Specific target organ toxicity - repeated Category 2 (bone marrow, liver, thymus) H373 - May cause damage to exposure organs (bone marrow, liver, thymus) through prolonged or repeated exposure.

Aspiration hazard

Category 1 H304 - May be fatal if swallowed and enters airways Environmental hazards Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects

Contains

Fuels, diesel, Gasoline, Kerosine (petroleum)

Signal word

Danger

Hazard statements

H224 Extremely flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs (bone marrow, liver, thymus) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor/. P331 Do NOT induce vomiting.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool.

Disposal

Not assigned.

Additional information

None. the label

2.3 Other hazards

Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapour. May cause flash fire or explosion. This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No