PIPELINE INTERFACE

Valero Energy Ltd

Revision date : 2013-10-09

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GHS02 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

68334-30-5

Name of the chemical

Fuels, diesel, except if the full refining history is known and it can be shown that the substance from which it is produced is not a carcinogen

Concentration

N/A

EC/CAS

86290-81-5

Name of the chemical

Gasoline

Concentration

N/A

EC/CAS

64742-81-0

Name of the chemical

Kerosine (petroleum), hydrodesulfurized

Concentration

N/A

Listed in

EC/CAS

269-822-7

Name of the chemical

Fuels, diesel, except if the full refining history is known and it can be shown that the substance from which it is produced is not a carcinogen

Concentration

N/A

EC/CAS

289-220-8

Name of the chemical

Gasoline

Concentration

N/A

General Information

Revision date

2013-10-09

Product name

PIPELINE INTERFACE

Product Synonyms

None

supplier name

Valero Energy Ltd

Emergency telephone

0044/(0)18 65 407333

Icons in SDS

Company Information

company name

Valero Energy Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

CorpHSE@valero.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H224, H304, H315, H319, H332, H336, H340, H350, H361, H372, H411

Hazard statements

Code

Statements

H224

Extremely flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. F+;R12, Carc. Cat. 1;R45, Muta. Cat. 2;R46, Repr. Cat. 3;R62-63, Xn;R20-65, Xi;R36/38, N;R51/53 The full text for all R-phrases is displayed in section 16.

EU Classification

Directive 67/548/EEC or 1999/45/EC as amended Regulation (EC) No 1272/2008 as amended

Physical hazards

Flammable liquids Category 1 H224 - Extremely flammable liquid and vapour. Extremely flammable.

Health hazards

Acute toxicity, inhalation Category 4 H332 - Harmful if inhaled. Skin corrosion/irritation Category 2 H315 - Causes skin irritation. Serious eye damage/eye irritation Category 2 H319 - Causes serious eye irritation. Germ cell mutagenicity Category 1B H340 - May cause genetic defects. Carcinogenicity Category 1A H350 - May cause cancer. Reproductive toxicity Category 2 H361 - Suspected of damaging fertility or the unborn child. Specific target organ toxicity - single Category 3 narcotic effects H336 - May cause drowsiness or exposure dizziness. Specific target organ toxicity - repeated Category 1 H372 - Causes damage to organs exposure (Blood) through prolonged or repeated exposure. May cause cancer. May cause heritable genetic damage. Also harmful by inhalation. Irritating to eyes and skin. Possible risk of impaired fertility. Possible risk of harm to the unborn child. Also harmful: may cause lung damage if swallowed.

Aspiration hazard

Category 1 H304 - May be fatal if swallowed and enters airways.

Environmental hazards

Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects. Hazard summary Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Specific hazards Breathing of high vapour concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chapping and oil acne. Prolonged and repeated contact with the product may cause skin cancer. Components of the product may be absorbed into the body through the skin. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Material will float and can be re-ignited on surface of water. Main symptoms Vapours have a narcotic effect and may cause headache, fatigue, dizziness and nausea.

2.2 Label elements

Label according to Regulation (EC) No. 1272/2008 as amended

Contains

Benzene, Fuels, diesel, Gasoline, Kerosine, (petroleum ), hydrosulfu rized

Signal word

Danger

Hazard statements

H224 - Extremely flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H336 - May cause drowsiness or dizziness. H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. H372 - Causes damage to organs (Blood) through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects.

Prevention

P201 - Obtain special instructions before use. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Response

P307 + P311 - If exposed: Call a poison center/doctor. P370 + P378 - In case of fire: Use alcohol-resistant foam, carbon dioxide, dry powder or water fog for extinction.

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental label elements

Not applicable

2.3 Other hazards

Static accumulator - Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire (or explosion).

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