Diesel Fuels and Gas Oils - All Grades

Valero Energy Ltd

Revision date : 2014-05-09

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GHS08 GHS07 GHS09 GHS02
Health risk rating 4
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

269-822-7/68334-30-5

Name of the chemical

Fuels, diesel, except if the full refining history is known and it can be shown that the substance from which it is produced is not a carcinogen

Concentration

N/A

General Information

Version

06

Revision date

2014-05-09

Product name

Diesel Fuels and Gas Oils - All Grades

Substance name

Diesel Fuels and Gas Oils - All Grades (Refer to Synonyms for Product Name)

Product Synonyms

Ultra Low Sulfur Diesel, FAME Free * Ultra Low Sulfur Diesel, up to 7% FAME * Ultra Low Sulphur Gas Oil , Unmarked - FAME Free * High Sulfur Diesel * GTL Diesel * Unfinished Diesel

CAS No.

68334-30-5

REACH No

01-2119484664-27-0052

1.2.1 Relevant identified uses

Distribution of a substance. Formulation & (re) packaging of substances and mixtures Manufacture of substance. Use as a Fuel. Use as an intermediate

supplier name

Valero Energy Ltd

Emergency telephone

0044/(0)18 65 407333

Icons in SDS

GHS02 GHS07 GHS08 GHS09

Company Information

company name

Valero Energy Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

CorpHSE@valero.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H304, H315, H332, H351, H373, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies

Aspiration hazard

Category 1 H304 - May be fatal if swallowed and enters airways Environmental hazards Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects Hazard summary

Physical hazards

Not classified for physical hazards

Health hazards

Harmful by inhalation. Irritating to skin. Limited evidence of a carcinogenic effect. Harmful: may cause lung damage if swallowed

Environmental hazards

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Specific hazards Breathing of high vapour concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chapping and oil acne. Components of the product may be absorbed into the body through the skin. Prolonged and repeated contact with the product may cause skin cancer Main symptoms Irritation of eyes and mucous membranes. Skin irritation. Defatting of the skin. Dermatitis Ingestion may cause irritation and malaise

Contains

Fuels, diesel Identification number 649-224-00-6

Signal word

Danger

Hazard statements

H373 - May cause damage to organs () through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. H332 - Harmful if inhaled. H304 - May be fatal if swallowed and enters airways. H351 - Suspected of causing cancer. H226 - Flammable liquid and vapour. H315 - Causes skin irritation.

Prevention

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P260 - Do not breathe dust/fume/gas/mist/vapors/spray.

Response

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. P331 - Do NOT induce vomiting.

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental label elements

None known.

2.3 Other hazards

Static accumulator - Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire (or explosion). Not a PBT or vPvB substance or mixture.

2.1 Classification of the substance or mixture

The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended Classification Carc. Cat. 3;R40, Xn;R20-65, Xi;R38, N;R51/53 The full text for all R-phrases is displayed in section 16. Classification according to Regulation (EC) No 1272/2008 as amended Physical hazards Flammable liquids Category 3 H226 - Flammable liquid and vapour. Health hazards Acute toxicity, inhalation Category 4 H332 - Harmful if inhaled. Skin corrosion/irritation Category 2 H315 - Causes skin irritation. Carcinogenicity Category 2 H351 - Suspected of causing cancer. Specific target organ toxicity - repeated Category 2 H373 - May cause damage to exposure organs () through prolonged or repeated exposure. Aspiration hazard Category 1 H304 - May be fatal if swallowed and enters airways. Environmental hazards Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects. Hazard summary Physical hazards Not classified for physical hazards. Health hazards Harmful by inhalation. Irritating to skin. Limited evidence of a carcinogenic effect. Harmful: may cause lung damage if swallowed. Environmental hazards Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Specific hazards Breathing of high vapour concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chapping and oil acne. Components of the product may be absorbed into the body through the skin. Prolonged and repeated contact with the product may cause skin cancer. Main symptoms Irritation of eyes and mucous membranes. Skin irritation. Defatting of the skin. Dermatitis. Ingestion may cause irritation and malaise.

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