MethaSol

Hazard statements (CLP)

H225, H301, H301+H311+H331, H311, H331, H360D, H372, H373, H400, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

EC) No 1272/2008 Kommentiert [A16]: This section of the safety data sheet shall describe the hazards of the

2.1 Classification of the substance or mixture

substance or mixture and the appropriate warning information associated with those hazards. SCL, Classification procedure Kommentiert [A17]: The classification of the substance or the according to M-factor, mixture which results from the application of the classification criteria in ATE, Regulation (EC) No Regulation (EC) No 1272/2008 shall be given. Where the supplier has 1272/2008 [CLP] notified information regarding the substance to the classification and labelling inventory in accordance with Article 40 of Regulation (EC) No 1272/2008, or Flam. Liq. 2, H225 On basis of test data has provided that information as part of a registration pursuant to this Repr. 1A, H360D Regulation, the classification given in the safety data sheet shall be the same C ≥ 3 %: Repr. 1A, H360D Legal classification as the classification provided in that notification or registration. If the mixture Acute Tox. 3, H301 ATE oral: 250 mg/kg Practical experience / human evidence does not meet the criteria for classification in accordance with Regulation Acute Tox. 3, H311 (EC) No 1272/2008, this shall be clearly stated. Information on the ATE dermal: 300 mg/kg Practical experience / human evidence substances in the mixture is provided under subsection 3.2. If the Acute Tox. 3, H331 ATE inhal.: 2,5 mg/ml/4h Practical experience / human evidence classification, including the hazard statements, is not written out in full, reference shall be made to section 16 where the full text of each STOT RE 1, H372 C ≥ 1 %: STOT RE 1, H372 On basis of test data classification, including each hazard statement, shall be given. The most 0,1 ≤ C < 1 %: STOT RE 2, H373 important adverse physical, human health and environmental effects shall be listed in accordance with sections 9 to 12 of the safety data sheet, in such a Aquatic Acute 1, H400 M (acute) = 100 On basis of test data way as to allow non-experts to identify the hazards of the substance or Aquatic Chronic 1, H410 M (chronic) = 10 mixture. On basis of test data Note: according to REACH, Annex II, the specification of the SCL and / or

Additional information

the M-factors for substances at this point is not necessary, as only required in SECTION 3.1. However, the indication of this data coupled with the Kommentiert [A22]: e.g. REACH, Annex XVII and Detergents regulation etc.

Hazard statements

see SECTION 16 classification appears to be more sensible than being listed individually. Kommentiert [A18]: The classification of the substance or the mixture which results from the application of the classification criteria in Regulation (EC) No 1272/2008 shall be given. Where the supplier has notified information regarding the substance to the classification and labelling inventory in accordance with Article 40 of Regulation (EC) No 1272/2008, or has provided that information as part of a registration pursuant to this Regulation, the classification given in the safety data sheet shall be the same as the classification provided in that notification or registration. Note: according to REACH, Annex II, the specification of the SCL, M-factor and ATE for substances is not necessary at this point, as it is not required until SECTION 3.1 However, the indication of this data, coupled with the classification, also appears to be sensefully. Proposed standard phrases (see www.euphrac.eu) are for example: Calculation method. Bridging principle "Dilution". Bridging principle "Batching". Bridging principle "Concentration of highly hazardous mixtures". Bridging principle "Interpolation within one toxicity category". Bridging principle "Substantially similar mixtures". Bridging principle "Aerosols". For mixtures it may be possible to use also the „calculation method“ as classification procedure. According to REACH, Annex II this should be stated in SECTION 16 latest: in the case of mixtures, an indication of which of the methods of evaluating information referred to in Article 9 of Regulation (EC) No 1272/2008 was used for the purpose of classification. H225 Highly flammable liquid and vapour. H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. H372 Causes damage to organs through prolonged or repeated exposure (oral, kidneys). H360D May damage the unborn child. H410 Very toxic to aquatic life with long lasting effects.

2.2 Label elements

Kommentiert [A19]: Based on the classification, at least the following elements appearing on the label in accordance with Regulation Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] (EC) No 1272/2008 shall be provided: hazard pictogram(s), signal word(s), hazard statement(s) and precautionary statement(s). A graphical

Hazard pictograms

reproduction of the full hazard pictogram in black and white or a graphical reproduction of the symbol only may be substituted for the colour pictogram provided in Regulation (EC) No 1272/2008. The applicable label elements in accordance with Article 25(1) to (6) and Article 32(6) of Regulation (EC) No 1272/2008 shall be provided. Note: just specifying the coding of the pictograms alone is not sufficient.

Signal word

Danger

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P308+P311 IF exposed or concerned: Call a doctor. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Supplemental label elements

Kommentiert [A20]: if applicable. For example EUH071

Special rules for supplemental label elements for certain mixtures

Kommentiert [A21]: To be added if applicable for mixtures only. For example EUH202

2.3 Other hazards

Kommentiert [A23]: Information shall be provided on whether the

Other physicochemical hazards

substance meets the criteria for persistent, bioaccumulative and toxic or very

Potential health effects

persistent and very bioaccumulative in accordance with Annex XIII, whether the substance was included in the list established in accordance with Article

Environmental effects

59(1) for having endocrine disrupting properties, and whether the substance Other adverse hazards: is a substance identified as having endocrine disrupting properties in ___________________________________________________________________________________ accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100(3) or Commission Regulation (EU) 2018/605(4). For a mixture, information shall be provided for each such substance that is