CLEAN FLOCCULATION CHEMICAL

Hazard statements (CLP)

H290, H318

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

May be corrosive to metals. (H290) Causes serious eye damage. (H318)

Precautionary statements

General If medical advice is needed, have product container or label at hand. (P101) Keep out of reach of children. (P102)

Prevention

Keep only in original packaging. (P234) Wear eye protection/protective gloves/protective clothing. (P280)

Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (P305+P351+P338) Immediately call a POISON CENTER/doctor. (P310) Absorb spillage to prevent material damage. (P390)

Storage

-

Disposal

Dispose of contents/container in accordance with national regulation / in accordance with local regulation (P501)

Hazardous Ingredients

Aluminium chloride, basic / Polyaluminium chloride

2.3 Other hazards

Additional warnings This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification. This product does not contain any substances considered to be endocrine disruptors in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

2.1 Classification of the substance or mixture

Met. Corr. 1; H290, May be corrosive to metals. Eye Dam. 1; H318, Causes serious eye damage. 2.2. Label elements Hazard pictogram(s) Signal word Danger Hazard statement(s) May be corrosive to metals. (H290) Causes serious eye damage. (H318) Precautionary statement(s) General If medical advice is needed, have product container or label at hand. (P101) Keep out of reach of children. (P102) Prevention Keep only in original packaging. (P234) Wear eye protection/protective gloves/protective clothing. (P280) Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (P305+P351+P338) Immediately call a POISON CENTER/doctor. (P310) Absorb spillage to prevent material damage. (P390) Storage - Disposal Dispose of contents/container in accordance with national regulation / in accordance with local regulation (P501) Hazardous substances Aluminium chloride, basic / Polyaluminium chloride Additional labelling UFI: YDDN-2VKH-5205-QV4S 2.3. Other hazards Additional warnings This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification. This product does not contain any substances considered to be endocrine disruptors in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable. This product is a mixture. 3.2. Mixtures Product/substance Identifiers % w/w Classification Note Aluminium chloride, basic / CAS No.: 1327-41-9 25 - 50% Met. Corr. 1, H290 Polyaluminium chloride EC No.: 215-477-2 Eye Dam. 1, H318 REACH: 01-2119531563-43 Index No.: See full text of H-phrases in section 16. Occupational exposure limits are listed in section 8, if these are available. Other information - SECTION 4: First aid measures 4.1. Description of first aid measures General information In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet. Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an unconscious person water or other drink. Inhalation Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with him/her. Skin contact Upon irritation: rinse with water. In the event of continued irritation, seek medical assistance. Eye contact If in eyes: Flush eyes with plenty of water or salt water (20-30 °C) for at least 30 minutes and continue until irritation stops. Remove contact lenses. Make sure you flush under the upper and lower eyelids. Seek medical assistance immediately and continue flushing during transport. Ingestion If the person is conscious, rinse the mouth with water and stay with the person. Never give the person anything to drink. In case of malaise, seek medical advice immediately and bring the safety data sheet or label from the product. Do not induce vomiting, unless recommended by the doctor. Have the person lean forward with head down to avoid inhalation of or choking on vomited material. Burns Not applicable. 4.2. Most important symptoms and effects, both acute and delayed The product contains substances that cause serious eye damage. Contact with these substances can cause irreversible effects on the eye / serious eye damage. 4.3. Indication of any immediate medical attention and special treatment needed IF exposed or concerned: Get immediate medical advice/attention. Information to medics Bring this safety data sheet or the label from this product. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Alcohol-resistant foam, carbon dioxide, powder, water mist. Unsuitable extinguishing media: Waterjets should not be used, since they can spread the fire. 5.2. Special hazards arising from the substance or mixture Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are exposed to fire, should be cooled with water. Do not allow fire-extinguishing water to enter the sewage system and nearby surface waters. 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective clothing to prevent contact. Upon direct exposure contact the National Poisons Information Centre (NPIC) on +353 (0) 1 809 256 (24 h service) in order to obtain further advice. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid direct contact with spilled substances. Contaminated areas may be slippery. 6.2. Environmental precautions Avoid discharge to lakes, streams, sewers, etc. Keep unauthorized persons away from the spill 6.3. Methods and material for containment and cleaning up Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents. 6.4. Reference to other sections See section 13 “Disposal considerations” on handling of waste. See section 8 "Exposure controls/personal protection" for protective measures. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid direct contact with the product. Smoking, drinking and consumption of food is not allowed in the work area. See section 8 "Exposure controls/personal protection" for information on personal protection. 7.2. Conditions for safe storage, including any incompatibilities Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Store in a container with a resistant inner liner. Recommended storage material Plastic Keep only in original packaging. Storage conditions 0 - 30°C Incompatible materials Bases 7.3. Specific end use(s) This product should only be used for applications quoted in section 1.2. SECTION 8: Exposure controls/personal protection 8.1. Control parameters No substances are listed in the "List of Chemical Agents and Occupational Exposure Limit Values" with an occupational exposure limit. DNEL Aluminium chloride, basic / Polyaluminium chloride Duration: Route of exposure: DNEL: Long term – Systemic effects - General population Dermal 2.32 mg/kg bw/day Long term – Systemic effects - Workers Dermal 4.6 mg/kg bw/day Long term – Systemic effects - General population Inhalation 4 mg/m³ Long term – Systemic effects - Workers Inhalation 16.4 mg/m³ Long term – Systemic effects - General population Oral 2.3 mg/kg bw/day PNEC No data available. 8.2. Exposure controls Apply general control to prevent unnecessary exposure General recommendations Smoking, drinking and consumption of food is not allowed in the work area. Exposure scenarios There are no exposure scenarios implemented for this product. Exposure limits Occupational exposure limits have not been defined for the substances in this product. Appropriate technical measures Ensure that eyewash stations and safety showers are located within easy reach. Apply standard precautions during use of the product. Avoid inhalation of vapours. Hygiene measures In between use of the product and at the end of the working day all exposed areas of the body must be washed thoroughly. Pay special attention to hands, forearms and face. Measures to avoid environmental exposure No specific requirements. Individual protection measures, such as personal protective equipment Generally Use only CE marked protective equipment. Respiratory Equipment Type Class Colour Standards NR P2 White EN143 Skin protection Recommended Type/Category Standards Dedicated work - clothing should be worn. Wear a protective suit in the event of prolonged periods of work with the product. Hand protection Material Glove thickness (mm) Breakthrough time Standards (min.) Vinyl/PVC 0,5 > 480 EN374-3, EN388 Neoprene (Neoprene) 0,6 > 480 EN374-2, EN374-3, EN388 Eye protection Type Standards Safety glasses EN166 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Yellowish Odour / Odour threshold Mild pH ~ 1,5 Density (g/cm³) 1,28 - 1,34 Kinematic viscosity No data available Dynamic viscosity 10 - 30 mPa.s (23 °C) Particle characteristics Not applicable - product is a liquid Phase changes Melting point/Freezing point (°C) ~ 30 Softening point/range (waxes and pastes) (°C) Does not apply to liquids. Boiling point (°C) 100 - 120 Vapour pressure Not applicable Relative vapour density Not applicable Decomposition temperature (°C) > 200 Data on fire and explosion hazards Flash point (°C) Not applicable Flammability (°C) Not applicable Auto-ignition temperature (°C) Not applicable Lower and upper explosion limit (% v/v) Testing not relevant or not possible due to the nature of the product. Solubility Solubility in water Completely soluble n-octanol/water coefficient (LogKow) Not applicable - inorganic material Solubility in fat (g/L) Not applicable 9.2. Other information Evaporation rate (n-butylacetate = 100) No data available Other physical and chemical parameters No data available. Oxidizing properties Not applicable SECTION 10: Stability and reactivity 10.1. Reactivity No data available. 10.2. Chemical stability The product is stable under the conditions, noted in section 7 “Handling and storage”. 10.3. Possibility of hazardous reactions None known. 10.4. Conditions to avoid Frost Extremes of temperature 10.5. Incompatible materials Bases 10.6. Hazardous decomposition products The product is not degraded when used as specified in section 1. SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 401 Species: Rat Route of exposure: Oral Result: > 2000 mg/kg Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 403 Species: Rat Route of exposure: Inhalation Test: LC50 Result: > 5 mg/L Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 402 Species: Rat Route of exposure: Dermal Test: LC50 Result: > 2000 mg/kg Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Causes serious eye damage. Respiratory sensitisation Based on available data, the classification criteria are not met. Skin sensitisation Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. 11.2. Information on other hazards Long term effects The product contains substances that cause serious eye damage. Contact with these substances can cause irreversible effects on the eye / serious eye damage. Endocrine disrupting properties This mixture/product does not contain any substances known to have hormone-disrupting properties in relation to health. Other information None known. SECTION 12: Ecological information 12.1. Toxicity Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 203 Species: Fish, Danio rerio Duration: 96 hours Result: > 1000 mg/L Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 202 Species: Daphnia, Daphnia magna Test: EC50 Result: 98 mg/L Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 201 Species: Algae, Pseudokirchneriella subcapitata Duration: 72 hours Test: EC50 Result: 14 mg/L Other information: Read-accross (Analogy) Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 202 Species: Algae, Pseudokirchneriella subcapitata Duration: 72 hours Test: EC50 Result: 0.24 mg/L Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 201 Species: Algae, Pseudokirchneriella subcapitata Duration: 72 hours Test: NOEC Result: 1 mg/L Product/substance Aluminium chloride, basic / Polyaluminium chloride Test method: OECD 201 Species: Algae, Pseudokirchneriella subcapitata Duration: 72 hours Test: NOEC Result: < 0.02 mg/L 12.2. Persistence and degradability Based on available data, the classification criteria are not met. 12.3. Bioaccumulative potential Product/substance Aluminium chloride, basic / Polyaluminium chloride Conclusion: No potential for bioaccumulation 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification. 12.6. Endocrine disrupting properties This mixture/product does not contain any substances considered to have endocrine-disrupting properties in relation to the environment. 12.7. Other adverse effects None known. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product is covered by the regulations on hazardous waste. HP 4 - Irritant (skin irritation and eye damage) EWC code Not applicable. Contaminated packing Packaging containing residues of the product must be disposed of similarly to the product. SECTION 14: Transport information 14.1 14.2 14.3 14.4 14.5 Other UN / ID UN proper shipping name Hazard class(es) PG* Env** information: ADR UN3264 CORROSIVE LIQUID, ACIDIC, Transport hazard class: 8 III No Limited INORGANIC, N.O.S. (Polyaluminium Label: 8 quantities: 5 L chloride) Classification code: C1 Tunnel restriction code: (E) See below for additional information. IMDG UN3264 CORROSIVE LIQUID, ACIDIC, Transport hazard class: 8 III No Limited INORGANIC, N.O.S. (Polyaluminium Label: 8 quantities: 5 L chloride) Classification code: C1 EmS: F-A S-B See below for additional information. IATA UN3264 CORROSIVE LIQUID, ACIDIC, Transport hazard class: 8 III No See below for INORGANIC, N.O.S. (Polyaluminium Label: 8 additional chloride) Classification code: C1 information. * Packing group ** Environmental hazards Additional information ADR / See Table A, section 3.2.1 for any information on special provisions, requirements, or warnings in connection with transport. See section 5.4.3, for instructions in writing regarding mitigation of damages in relation to incidents or accidents during transport. IMDG / See section 3.2.1, for any information on special provisions, requirements, or warnings in connection with transport. IATA / See Table 4.2 for any information on special provisions, requirements, or warnings in connection with transport. This product is within scope of the regulations of transport of dangerous goods. 14.6. Special precautions for user Not applicable. 14.7. Maritime transport in bulk according to IMO instruments No data available. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Restrictions for application No special. Demands for specific education No specific requirements. SEVESO - Categories / dangerous substances Not applicable. Additional information Not applicable. Sources Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (CLP). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). 15.2. Chemical safety assessment No SECTION 16: Other information Full text of H-phrases as mentioned in section 3 H290, May be corrosive to metals. H318, Causes serious eye damage. Abbreviations and acronyms ADN = European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterway ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS = Chemical Abstracts Service CE = Conformité Européenne (European conformity) CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] CSA = Chemical Safety Assessment CSR = Chemical Safety Report DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level EINECS = European Inventory of Existing Commercial chemical Substances ES = Exposure Scenario EUH statement = CLP-specific Hazard statement EuPCS = European Product Categorisation System EWC = European Waste Catalogue GHS = Globally Harmonized System of Classification and Labelling of Chemicals GWP = Global warming potential IARC = International Agency for Research on Cancer (IARC) IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OECD = Organisation for Economic Co-operation and Development PBT = Persistent, Bioaccumulative and Toxic PNEC = Predicted No Effect Concentration RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail RRN = REACH Registration Number SCL = A specific concentration limit SVHC = Substances of Very High Concern STOT-RE = Specific Target Organ Toxicity - Repeated Exposure STOT-SE = Specific Target Organ Toxicity - Single Exposure TWA = Time weighted average UN = United Nations UVBC = Unknown or variable composition, complex reaction products or of biological materials VOC = Volatile Organic Compound vPvB = Very Persistent and Very Bioaccumulative Additional information The classification of the mixture in regard of health hazards is in accordance with the calculation methods given by Regulation (EC) No. 1272/2008 (CLP). The safety data sheet is validated by Uponor Infra AB Other A change (in proportion to the last essential change (first cipher in SDS version, see section 1)) is marked with a triangle. The information in this safety data sheet applies only to this specific product (mentioned in section 1) and is not necessarily correct for use with other chemicals/products. It is recommended to hand over this safety data sheet to the actual user of the product. Information in this safety Date Performer Batch counter Service/Notes 38 Uponor Clean II Treatment Plant Installation and operation manual Date Performer Batch counter Service/Notes 39 Uponor Clean II Treatment Plant Installation and operation manual Uponor Infra Ltd Industrivägen 11 513 32 Fristad T +46 33 172 500 E kundtjanst.infra@uponor.com We reserve the right to make changes. 30716-EN-06-25_062025 www.uponor.com