Note: Ingredients listed on restricted chemical lists
EC/CAS
424-610-5/120068-37-3
Name of the chemical
Fipronil; 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile
Concentration
20-25
EC/CAS
203-473-3/107-21-1
Name of the chemical
Ethane-1,2-diol
Concentration
2.5-10
General Information
Revision date
2025-04-07
Product name
Citrunil 200 SC
1.2.1 Relevant identified uses
Insecticide Industrial/Professional use spec For agricultural, industrial and professional use only
Icons in SDS
Company Information
company name
UPL South Africa (Pty) Ltd
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H302+H312+H332, H312, H332, H370, H373, H400, H410
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture Classification according to UN GHS Purple Book (Rev. 9, 2021) Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhalation:dust,mist) Category 4 H332 Specific target organ toxicity- Single exposure, Category 1 H370 Specific target organ toxicity — Repeated exposure, Category 2 H373 Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 Hazardous to the aquatic environment — Chronic Hazard, Category 1 H410 Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
EU Classification
GHS Purple Book (Rev. 9, 2021)labelling to displayExtra classification(s) to display
Hazard pictograms
GHS07 GHS08 GHS09
Signal word
Danger
Hazardous Ingredients
Fipronil; Monoethylene glycol
Hazard statements
H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled. H370 – Causes damage to organs. H373 – May cause damage to organs (kidneys) through prolonged or repeated exposure. H400 – Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements
P101 – If medical advise is needed, have product container or label at hand. P102 – Keep out of reach of children. P103 – Read carefully and follow all instructions. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P301 + P317 - IF SWALLOWED: Get medical help. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P316 - IF exposed or concerned: Get emergency medical help immediately. P319 - Get medical help if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label). P330 - Rinse mouth. P362+P364 - Take off contaminated clothing and wash it before reuse. P391 - Collect spillage. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
2.3 Other hazards
No additional information available
2.1 Classification of the substance or mixture
Classification according to UN GHS Purple Book (Rev. 9, 2021) Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhalation:dust,mist) Category 4 H332 Specific target organ toxicity- Single exposure, Category 1 H370 Specific target organ toxicity — Repeated exposure, Category 2 H373 Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 Hazardous to the aquatic environment — Chronic Hazard, Category 1 H410 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available