TBPND

Hazard statements (CLP)

H227, H242, H315, H317, H400, H411

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : colourless Odour : ester-like Combustible liquid. Heating may cause a fire. Causes skin irritation. May cause an allergic skin reaction. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 4 Organic peroxides Type D Skin corrosion/irritation Category 2 Skin sensitisation Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 2 hazard

Signal word

Danger

Hazard statements

H227 Combustible liquid. H242 Heating may cause a fire. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/ Store away from clothing/ combustible materials. P234 Keep only in original container. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of water. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish. P391 Collect spillage.

Storage

P410 Protect from sunlight. P411 + P235 Store at temperatures not exceeding < -10 °C/ < 14 °F. Keep cool. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Combustible liquid. Heating may cause a fire.

Health hazards

Causes skin irritation. May cause an allergic skin reaction

Environmental hazards

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 4 Organic peroxides : Type D Skin corrosion/irritation : Category 2 Skin sensitisation : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 2 hazard