TBPEH

Hazard statements (CLP)

H227, H242, H317, H360F, H400, H411

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : colourless Odour : ester-like Combustible liquid. Heating may cause a fire. May cause an allergic skin reaction. May damage fertility. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 4 Organic peroxides Type C Skin sensitisation Category 1 Reproductive toxicity Category 1B Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 2 hazard

Signal word

Danger

Hazard statements

H227 Combustible liquid. H242 Heating may cause a fire. H317 May cause an allergic skin reaction. H360F May damage fertility. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible materials. P234 Keep only in original container. P261 Avoid breathing mist or vapours. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish. P391 Collect spillage.

Storage

P405 Store locked up. P410 Protect from sunlight. P411 + P235 Store at temperatures not exceeding < 10 °C/ < 50 °F. Keep cool. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Combustible liquid. Heating may cause a fire.

Health hazards

May cause an allergic skin reaction. May damage fertility

Environmental hazards

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 4 Organic peroxides : Type C Skin sensitisation : Category 1 Reproductive toxicity : Category 1B Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 2 hazard