TBPB-HA-M3

Hazard statements (CLP)

H226, H242, H303+H313, H315+H320, H317, H331, H400, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : light yellow Odour : ester-like Flammable liquid and vapour. Heating may cause a fire. May be harmful if swallowed or in con- tact with skin. Causes skin and eye irritation. May cause an allergic skin reaction. Toxic if inhaled. Very toxic to aquatic life. Harmful to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 3 Organic peroxides Type C Acute toxicity (Oral) Category 5 Acute toxicity (Inhalation) Category 3 Acute toxicity (Dermal) Category 5 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 2B Skin sensitisation Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 3 hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H242 Heating may cause a fire. H303 + H313 May be harmful if swallowed or in contact with skin. H315 + H320 Causes skin and eye irritation. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible materials. P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate- ly all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/ doctor if you feel unwell. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ at- tention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P410 Protect from sunlight. P411 + P235 Store at temperatures not exceeding 30 °C/ 86 °F. Keep cool. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Flammable liquid and vapour. Heating may cause a fire.

Health hazards

May be harmful if swallowed. Toxic if inhaled. May be harmful in contact with skin. Causes skin ir- ritation. Causes eye irritation. May cause an allergic skin reaction

Environmental hazards

Very toxic to aquatic life. Harmful to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Organic peroxides : Type C Acute toxicity (Oral) : Category 5 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 5 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 2B tation Skin sensitisation : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 3 hazard