TBPB

Hazard statements (CLP)

H242, H315+H320, H317, H332, H400, H412

Code

Statements

H242

Heating may cause a fire

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Colour : light yellow Odour : ester-like Heating may cause a fire. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. Very toxic to aquatic life. Harmful to aquatic life with long lasting effects. GHS Classification Organic peroxides Type C Acute toxicity (Inhalation) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 2B Skin sensitisation Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 3 hazard

Signal word

Danger

Hazard statements

H242 Heating may cause a fire. H315 + H320 Causes skin and eye irritation. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/ Store away from clothing/ combustible materials. P234 Keep only in original container. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ at- tention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P410 Protect from sunlight. P411 + P235 Store at temperatures not exceeding 40 °C/ 104 °F. Keep cool. P420 Store away from other materials.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Heating may cause a fire.

Health hazards

Harmful if inhaled. Causes skin tion irritation. Causes eye irritation. May cause an allergic skin reac-

Environmental hazards

Very toxic to aquatic life. Harmful to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Organic peroxides : Type C Acute toxicity (Inhalation) : Category 4 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 2B tation Skin sensitisation : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 3 hazard