TBHP-70-AQ (BULK)

United Initiators GmbH

Revision date : 2023-02-21

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GHS02 GHS06 GHS08 GHS05 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-915-7/75-91-2

Name of the chemical

tert-Butylhydroperoxid (2016/1179)

Concentration

>68-<=72

General Information

Version

2.5

Revision date

2023-02-21

Product name

TBHP-70-AQ (BULK)

Substance name

tert-butyl hydroperoxide

CAS No.

75-91-2

REACH No

01-2119446670-40-0001

1.2.1 Relevant identified uses

polymerisation initiators, Oxidizing agents

1.2.2. Uses advised against

Exposure Scenario is available as separate attachment., For on use further information see eSDS

Emergency telephone

+49 / 89 / 74422, +49 89 220 61012

Icons in SDS

GHS02 GHS05 GHS06 GHS08 GHS09 M004 M009 M010 M011 M013 M017

Company Information

company name

United Initiators GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

contact@united-in.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H242, H302, H311, H314, H317, H318, H330, H335, H341, H351, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H242 Heating may cause a fire. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P234 Keep only in original packaging. P260 Do not breathe mist or vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi- ately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immedi- ately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rins- ing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use water spray, alcohol- resistant foam, dry chemical or carbon dioxide to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regu- lation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Organic peroxides, Type F H242: Heating may cause a fire. Acute toxicity, Category 4 H302: Harmful if swallowed. Acute toxicity, Category 2 H330: Fatal if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Skin corrosion, Sub-category 1C H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Carcinogenicity, Category 2 H351: Suspected of causing cancer. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Long-term (chronic) aquatic hazard, Cat- H411: Toxic to aquatic life with long lasting effects. egory 2

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