Multiflame 453, gas lighter refill

Hazard statements (CLP)

H222, H229

Code

Statements

H222

Extremely flammable aerosol

2.1 Classification of the substance or mixture

F+ R12 Extremely flammable. Classification according to 1272/2008/EC Flam. Aerosol 1 H222, H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2 Label elements

Hazard symbols and signal words DANGER

Hazard statements

H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F. P102 Keep out of reach of children.

2.3 Other hazards

The mixture wasn’t tested. Rapid evaporation can cause frostbite. S e c t i o n 3 C o m p o s i t i o n / i n f o r m a t i o n o n i n g r e d i e n t s 3.1 Substances Not applicable. 3.2 Mixtures Isobutane CAS number: 75-28-5 EC number: 200-857-2 Classification acc. to 67/548/EC: F+ R12 Classification acc. to 1272/2008/EC: Flam. Gas 1 H220, Press. Gas H280 Butane CAS number: 106-97-8 EC number: 203-448-7 Classification acc. to 67/548/EC: F+ R12 Classification acc. to 1272/2008/EC: Flam. Gas 1 H220, Press. Gas H280 Isobutane & Butane Range of percentages: 50-90% Propane Range of percentages: 5-35% CAS number: 74-98-6 EC number: 200-827-9 Classification acc. to 67/548/EC: F+ R12 Classification acc. to 1272/2008/EC: Flam. Gas 1 H220, Press. Gas H280 Full text of each relevant H and R phrase is in chapter 16. S e c t i o n 4 F i r s t a i d m e a s u r e s 4.1 Description of first aid measures Skin contact: take off contaminated clothes. W ash frost-bitten areas with plenty of water. Remove contaminated clothing, if it is possible. Do not remove clothing if it adheres constantly to the skin. Get warm frost-bitten areas slowly. Cover wound with sterile dressing. Do not use ointments or powders. Eye contact: wash out with plenty of water with the eyelid hold wide open for 10-15 min. Remove any contact lenses. Use sterile dressing. Seek medical advice. Ingestion: not applicable. Inhalation: remove to fresh air. Keep warm and calm. Consult a doctor, if symptoms persist. 4.2 Most import ant symptoms and effects, both acute and delayed Skin contact: contact with liquid gas can cause frostbite. Eye contact: contact with liquid gas can cause frostbite, damage of cornea. Inhalation: low concentrate of gas in the air causes lacrimation, cough, narcosis, high concentrate of gas causes dizziness, nausea, vomiting, dyspnoea, clouding of consciousness, drowsiness. In concentration >70% it causes an obvious fall in blood pressure, loss of consciousness, tremors, breathing abnormalities and death. 4.3 Indication of any immediate medical attention and special treatment needed Physician makes a decision regarding further medical treatment after thoroughly examination of the injured. Section 5: F i r e f i g h t i n g m e a s u r e s 5.1 Extinguishing media Suitable extinguishing media: CO2, dry chemical, water spray, foam. Small fire: out of doors – let the gas burn out; indoor – use powder extinguisher. Large fire: isolate a source of gas and use water spray. Unsuitable extinguishing media: water jet – risk of the propagation of the flame. 5.2 Special hazards arising from the substance or mixture May produce toxic fumes of carbon monoxide if burning. Do not inhale combustion products. 5.3 Advice for firefighters Personal protection typical in case of fire. W ear suitable respiratory equipment and protected clothes. Product is extremely flammable. It forms explosive mixtures with air. Gas is heavier than air and can accumulate in the lower sections of enclosed spaces. It displaces oxygen from the air. Cool down containers with water to prevent bursting. S e c t i o n 6 A c c i d e n t a l r e l e a s e m e a s u r e s 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel: limit the access for the outsiders into the breakdown area, until the suitable cleaning operations are completed. Do not use any open flame. No smoking. Take precautionary measures against static discharges. Wear adequate personal protective equipment. Avoid contact with skin and eyes. For emergency responders: ensure that removing the problem and its results is conducted by a trained personnel only. W ear chemical resistant safety clothing. 6.2 Environmental precautions Do not empty into drains (danger of explosion). Notify relevant emergency services. 6.3 Methods and material for containment and cleaning up Small spillage: let the gas evaporate and ventilate well. Large spillage: eliminate a source of gas if it is possible. Disperse the gas by water mist or safety curtain. 6.4 Reference to other sections Appropriate conduct with waste product – see section 13. Personal protective equipment – see section 8. S e c t i o n 7 H a n d l i n g a n d s t o r a g e 7.1 Precautions for safe handling Handle in accordance with good occupational hygiene and safety practices. Avoid contact with skin and eyes. Do not pierce or burn, even after use. Ensure adequate ventilation of area, where the product is used. Protect from sources of ignition – do not smoke during filling. Gas can form explosive mixtures with air. 7.2 Conditions for safe storage, including any incompabilities Keep container tightly closed, in dry, cool and well-ventilated place. Keep away from sources of ignition. Protect from temperature above 50ºC. Avoid direct expose to sunlight. Keep away from food, beverages or feed for animals. Do not smoke, use open flame and sparking tools. 7.3 Specific end use(s) Gas lighter refill. S e c t i o n 8 E x p o s u r e c o n t r o l s / p e r s o n a l p r o t e c t i o n 8.1 Control parameters Country BUTANE PROPANE Germany MAK: 1900 mg/m3 MAK: 1800 mg/m3 Italy TW A: 1900 mg/m3 TW A: 4508 mg/m3 France VME: 1900 mg/m3 VME: 1800 mg/m3 Hungary AK 2350 mg/m3, CK 9400 mg/m3 - Spain TLV TW A: 1900 mg/m3 - UK WEL: 1450 mg/m3 - 8.2. Exposure controls Use the product in accordance with good occupational hygiene and safety practices. When handlings do not eat, drink or smoke. Before break and after work carefully wash hands. Ensure adequate ventilation. Avoid contact liquid gas with skin and eyes. Hand and body protection Use protective gloves from neoprene or nitryl rubber. Gloves should be flexible at a temperature below the atmospheric boiling point of the gas. It may be necessary to increase the frequency of change gloves if there is immersion or prolonged contact with the product. The material that the gloves are made of must be impenetrable and resistant to the product’s effects. The selection of material must be performed with consideration of breakthrough time, penetration speed and degradation. Moreover, the selection of proper gloves depends not only on the material, but also on other quality features and changes depending on the manufacturer. The producer should provide detailed information regarding the exact breakthrough time. This information should be followed. Eye/face protection Use protective google if there is a risk of spraying liquid gas. Respiratory protection Normall not required. If concentarion of oxygen is lower than 17% or max. concentartion of gas in air is more than 1% use self-contained breathing apparatus. Environmental exposure controls Gas evaporates very quickly. It doesn’t cause contamination of environment. S e c t i o n 9 P h y s i c a l a n d c h e m i c a l p r o p e r t i e s 9.1 Information on basic physical and chemical properties physical state: liquefied gas colour: colorless odour: characteristic, weak odour threshold: not determinated pH: not applicable melting point/freezing point: not determinated initial boiling point and boiling range: - 42 - 0°C flash point: evaporation ca. - 80°C rate: flammability (solid, not determinated gas): extremely flammable upper/lower flammability or explosive limits: 10,9 % vol./1,5% vol. vapour pressure (20°C): 1 200 – 7 500 hPa vapour density: not determinated relative density: 0,5 – 0,58 g/cm3 solubility(ies): < 0,1 g/l partition coefficient: n-octanol/water: not determinated auto-ignition temperature: not determinated decomposition temperature: not determinated explosive properties: it forms explosive mixture with air oxidising properties: not display viscosity: not determinated

Further information

No additional data. S e c t i o n 1 0 S t a b i l i t y a n d r e a c t i v i t y 10.1 Reactivity Product reacts with strong oxidizing agents. It nitrations and chlorinations. 10.2 Chemical stability The product is stable under normal conditions. 10.3 Possibility of hazardous reactions Gas forms explosive mixture with air. 10.4 Conditions to avoid Avoid direct sunlight, source of ignition, temperature above 50°C and static discharges. 10.5 Incompatible materials Strong oxidizing agents. 10.6 Hazardous decomposition products Not known. S e c t i o n 1 1 T o x i c o l o g i c a l i n f o r m a t i o n 11.1 Information on toxicological effects Information regarding acute and/or delayed results of the exposure was defined on the basis of the information on product’s classification and/or toxicological studies as well as the experience and knowledge of the manufacturer. Acute toxicity Based on available data, the classification criteria are not met. Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard. Based on available data, the classification criteria are not met. S e c t i o n 1 2 E c o l o g i c a l i n f o r m a t i o n 12.1 Toxicity Product is not classified as dangerous for environment. 12.2 Persistence and degradability It oxides very quickly in air (photochemical reaction). 12.3 Bioaccumulative potential Does not accumulate in environment. 12.4