Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
10 - 20
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
8-15
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
<5
EC/CAS
219-799-4/2536-05-2
Name of the chemical
2,2’-Methylenediphenyl diisocyanate
Concentration
<1
General Information
Version
4.0
Revision date
2020-12-04
Product name
PLAST X B - HARDENER
1.2.1 Relevant identified uses
Industrial use,Professional use
1.2.2. Uses advised against
Consumer uses: Private households (= general public = consumers)
Manufacturer Name
U-POL Limited
Emergency telephone
+44 (0) 870 8200418, +353 1 809 2566, +353 1 809 2166
Icons in SDS
Company Information
company name
U-POL Limited
e-mail address of the competent person responsible for the Safety Data Sheet
technicalsupport@u-pol.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture
Adverse physicochemical, human health and environmental effects
Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Contains
aromatic polyisocyanate; 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'- diisocyanate; o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate; 2,2'-methylenediphenyl diisocyanate; diphenylmethane-2,2'-diisocyanate; formaldehyde, homopolymer with aniline and carbonyl dichloride
Hazard statements
H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 - Obtain special instructions before use. P261 - Avoid breathing vapours, fume. P264 - Wash hands thoroughly after handling. P280 - Wear eye protection, protective clothing, protective gloves. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Supplemental label elements
EUH204 - Contains isocyanates. May produce an allergic reaction.
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
Component polymethylene polyphenyl isocyanate (9016-87-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate (101-68-8) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate (5873-54-1) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII 2,2'-methylenediphenyl diisocyanate; diphenylmethane-2,2'-diisocyanate (2536-05-2) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
2.1 Classification of the substance or mixture
Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity — Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity — Repeated exposure, Category 2 H373 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. 2.2. Label elements