915 HARDENER (TPOB)

U-POL LIMITED

Revision date : 2017-11-22

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

>=23 >=5

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

>=5

EC/CAS

219-799-4/2536-05-2

Name of the chemical

2,2’-Methylenediphenyl diisocyanate

Concentration

<100

General Information

Version

2.0

Revision date

2017-11-22

Product name

915 HARDENER (TPOB)

1.2.1 Relevant identified uses

Industrial/Professional use spec Industrial

Emergency telephone

+44 (0) 870 8200418

Icons in SDS

GHS07 GHS08 M004 M010 M017

Company Information

company name

U-POL LIMITED

e-mail address of the competent person responsible for the Safety Data Sheet

technical.department@u-pol.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373, H412

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Harmful to aquatic life with long lasting effects

Hazard pictograms

GHS07 GHS08

Signal word

Danger

Hazardous Ingredients

FORMALDEHYDE, OLIGOMERIC REACTION PRODUCTS WITH ANILINE & PHOSGENE (OLIGOMERIC MDI); 4,4'-methylenediphenyl diisocyanate, diphenylmethane-4,4'-diisocyanate; PREPOLYMER BASED ON AROMATIC POLYISOCYANATE; 2,2'-methylenediphenyl diisocyanate, diphenylmethane-2,2'-diisocyanate; o-(p-isocyanatobenzyl)phenyl isocyanate, diphenylmethane-2,4'-diisocyanate

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs (hearing organs) through prolonged or repeated exposure (inhalation). H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements

P260 - Do not breathe fume, vapours. P280 - Wear eye protection, protective clothing, protective gloves. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Supplemental label elements

EUH204 - Contains isocyanates. May produce an allergic reaction.

2.3 Other hazards

No additional information available

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity — Repeated exposure, Category 2 H373 Hazardous to the aquatic environment — Chronic Hazard, Category 3 H412 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Harmful to aquatic life with long lasting effects.

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